Patents Represented by Attorney, Agent or Law Firm Gerald D. Malpass
  • Patent number: 7121339
    Abstract: A solids-stabilized oil-in-water emulsion and a method for preparing the solids-stabilized oil-in-water emulsion. The oil-in-water emulsion is formed by combining oil, water, solid particles and a pH enhancing agent and mixing until the solid-stabilized oil-in-water emulsion is formed. The low viscosity oil-in-water emulsion can be used to enhance production of oil from subterranean reservoirs. The low viscosity oil-in-water emulsion can also be used to enhance the transportation of oil through a pipeline.
    Type: Grant
    Filed: November 8, 2005
    Date of Patent: October 17, 2006
    Assignee: ExxonMobil Upstream Research Company
    Inventors: James R. Bragg, Ramesh Varadaraj
  • Patent number: 6267143
    Abstract: A multi-port injection/selection valve utilizes a ferrule cluster to connect tubes or capillaries to a common port in the valve. The use of micro ferrule clusters, as opposed to conventional connectors such as nuts and/or bolts, permits the capillary ends to be positioned in extremely close proximity to the valve rotor and to each other, thus minimizing the volume between two capillaries when they are in brought into fluid communication with each other.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: July 31, 2001
    Assignee: Upchurch Scientific, Inc.
    Inventor: Hans Gunther Schick
  • Patent number: 6180736
    Abstract: The disclosed invention relates to a polymerization process comprising contacting ethylene, and optionally, one or more olefinically unsaturated comonomers, with an active supported Group 3, 4, 5, or 6 metallocene catalyst system having an unsubstituted or substituted fused-ring cyclopentadienyl ligand, preferably indenyl or fluorenyl, and a substituted or unsubstituted cyclopentadienyl ligand under gas-phase or slurry polymerization conditions. The process is suitable for the production of high-density polyethylene homopolymers and copolymers. The benefits to industrial practice are both the ease of preparation and low-cost of the precursor metallocene compound and the commercially feasible polymerization activity levels in stable, low fouling level reactor conditions surprisingly associated with it. Additionally, the polymers made under the invention process conditions have narrow molecular weight distributions, low MI, and low values for MIR.
    Type: Grant
    Filed: December 17, 1997
    Date of Patent: January 30, 2001
    Assignee: Exxon Chemical Patents Inc
    Inventors: Michael E. Muhle, George Alan Vaughan
  • Patent number: 6143682
    Abstract: This invention relates to single site catalyst systems comprising activated bimetallocyclic transition metal compounds, and the use of these catalyst systems for the polymerization of ethylenically and acetylenically unsaturated monomers. The bimetallocyclic compounds comprise two metal atoms, selected from the group consisting of Group 4 or Group 5 metal atoms, connected through two covalent bridging links so as to form a cyclic compound having delocalized bonding in the cyclic structure. The exemplary bimetallocyclic compound bis-M-(trimethylsilyl-methylidyne) tetrakis-(trimethylsilylmethyl) ditantalum activated with alumoxane and borate compounds is shown to be useful for preparing ethylene polymers having M.sub.n of at least 267,000 and MWD of about 2.3.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: November 7, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Richard Allen Fisher
  • Patent number: 5763532
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5723545
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: March 3, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5696213
    Abstract: This invention is a solution process for the preparation of ethylene-.alpha.-olefin/diolefin copolymers comprising contacting ethylene, one or more .alpha.-olefin monomer, and optionally one or more diene monomer, with a catalyst system containing a catalyst activator and a Group 4 metallocene compound, comprising a) conducting the polymerization reaction at a temperature of about 60.degree. to 150.degree. C.; b) selecting as the Group 4 metallocene compound one or more members of the group consisting of cyclic monocyclopentadienyl Group 4 metal and covalently bridged (bis)indenyl hafnium metallocene compounds; and c) maintaining the .alpha.-olefin concentration at a molar ratio to that of ethylene of between about 0.3 to 7.0 and a diolefin to ethylene molar ratio of between about 0.01 and 0.4. In a preferred embodiment the process comprises: 1) mixing with a reaction solvent the one or more .alpha.
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: December 9, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Rinaldo Soria Schiffino, Javier Mario Zamora