Abstract: An asbestos-free insulating material suitable for use as a header in molten metal casting. The material is made from a dry mixture comprising lime, siliceous component, delaminated vermiculite or spodumene or lithium aluminate or mixtures thereof, and optionally, wollastonite and organic fiber. The dry mixture is mixed with water to form a slurry, shaped, heated in the presence of steam, and dried to remove free water.
Type:
Grant
Filed:
September 12, 1988
Date of Patent:
January 30, 1990
Assignee:
Aluminum Company of America
Inventors:
Stephen C. Libby, G. Edward Graddy, Jr.
Abstract: A process for making alpha alumina particles wherein a Bayer process caustic aluminate solution is treated with both alumina hydrate seed material and alpha alumina promoter particles to precipitate alumina hydrate particles. The precipitated particles are separated from the solution and then dried and calcined to produced alpha alumina particles. Addition of promoter particles in the precipitation step lowers the calcination temperture necessary to produce alpha alumina and results in smaller sized crystallites in the product.
Abstract: A metalworking lubricant composition comprising a propoxylated fatty alcohol; a carboxylic acid, carboxylic acid ester, or mixture of said acid and said ester; and water. The composition demonstrates a reduced tendency to form soap and sludge and to increase in viscosity compared with prior art lubricant compositions containing mineral oil.
Abstract: Alumina particles having average particle size of about 1-20 microns are converted to alpha alumina in a steam-fluidized bed maintained at about 380.degree.-600.degree. C. and a pressure greater than about 1000 psig. Acidifying the steam reduces average crystallite size of the product and lowers content of some impurities. A preferred product is alpha alumina having an average crystallite size of less than about 0.2 micron.
Abstract: A process for preparing a stabilized high cristobalite from a gel comprising ultramicroscopic particles of SiO.sub.2, Na.sub.2 O, and Al.sub.2 O.sub.3 where the ratio of moles of Na.sub.2 O to Al.sub.2 O.sub.3 is from about 0.95 to about 1.1, and the molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 is between about 10 and about 40. After the gel is formed, it is heated at 800-1400.degree. C. for a time sufficient to form stabilized high cristobalite.
Type:
Grant
Filed:
October 13, 1987
Date of Patent:
April 4, 1989
Assignee:
Aluminum Company of America
Inventors:
Anthony J. Perrotta, Donald K. Grubbs, Edward S. Martin
Abstract: A container body for foods and beverages having reduced gas and vapor permeability. The container body is preferably formed from a plastic resin and coated with a thin film of diamond-like carbon.
Type:
Grant
Filed:
August 27, 1987
Date of Patent:
March 7, 1989
Assignee:
Aluminum Company of America
Inventors:
Kathleen M. Tomaswick, Alfred F. LaCamera
Abstract: A method for reducing the acidity and moisture content of used organophosphate functional fluids. The used functional fluid is contacted with a solid composite adsorbent and then separated from the adsorbent. The composite adsorbent is preferably a powder having an average particle size of about 20-500 microns and total pore volume of at least about 0.40 cm.sup.3 /g and it comprises about 40-90 wt % alumina and about 10-60 wt % Y zeolite wherein the molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 is about 4.5-6.0. The adsorbent is produced by agglomerating particles of activated alumina and Y zeolite into a composite agglomerate, aging the agglomerate, activating at an elevated temperature, and then comminuting to form a powder.
Abstract: A stable gel is formed by reacting alumina hydrate sol and a vinyl alcohol-vinyl acetate copolymer in an aqueous solution having pH less than about 7 to form a polymeric sol and then transforming the sol to a gel. The copolymer preferably comprises polyvinyl acetate that is about 85-99% hydrolyzed. The gel is drawn into a thin layer and water is removed to form a thin, substantially crack-free film. The film makes a stable, generally transparent insulating material.
Abstract: Mineral particles are surface treated with an alkali metal silicate, hydrogen peroxide, an acid, or an organophosphorus compound. A preferred surface treating method utilizes sodium silicate in aqueous solution at pH greater than 9, followed by neutralization with acid to precipitate a silica coating onto surface portions of the particles. The mineral particles are preferably alumina particles. The surface-treated alumina particles may be incorporated into fluoride dentifrices or compounded with halogenated hydrocarbons and polymeric resins to form flame-retardant polymer compounds.
Type:
Grant
Filed:
November 27, 1987
Date of Patent:
November 1, 1988
Assignee:
Aluminum Company of America
Inventors:
Lawrence L. Musselman, Larry F. Wieserman
Abstract: A metalworking lubricant comprising an oil-in-water microemulsion and containing about 1-30 wt % natural or synthetic oil; about 0.5-30 wt % of a water-soluble surfactant, preferably a nonionic surfactant; about 1-20 wt % of an organic consurfactant, preferably 1,2-octanediol; and about 45-97.5 wt % water containing less than about 1 wt % dissolved inorganic salts. The lubricant is suitable for various metalworking methods, including hot rolling and cold rolling of aluminum and aluminum alloys.
Type:
Grant
Filed:
May 21, 1987
Date of Patent:
November 1, 1988
Assignee:
Aluminum Company of America
Inventors:
Girma Biresaw, Ronald A. Reich, John Bohaychick, Ronald P. Festa
Abstract: A metalworking lubricant comprising about 1-20 wt % natural or synthetic oil; about 0.5-30 wt % of a water-soluble surfactant, preferably a nonionic surfactant; about 1-20 wt % of an organic cosurfactant, preferably 1,2-octanediol; and about 50-97.5 wt % water containing less than about 1 wt % dissolved inorganic salts. The lubricant is preferably a lyotropic liquid crystal.
Abstract: A parting composition useful for continuously casting aluminum and aluminum alloys and comprising glycerol trioleate and a vegetable oil. Mixtures of glycerol trioleate with castor oil have superior properties compared with parting compositions previously used for continuous ingot casting.
Type:
Grant
Filed:
August 6, 1986
Date of Patent:
October 4, 1988
Assignee:
Aluminum Company of America
Inventors:
Joseph T. Laemmle, John Bohaychick, Willie Lansdale
Abstract: A process for continuous direct chill casting of aluminum alloys, particularly aluminum-lithium alloys. The molten alloy is cast in a mold containing a header comprising delaminated vermiculite or spodumene or lithium aluminate. The header preferably comprises delaminated vermiculite blended with wollastonite, lime, silica, and wood fiber. The mixture is slurried with water, molded into shape, compressed to expel water, steam cured, and dried. The header forms ingots of good quality and has excellent resistance to attack by molten aluminum-lithium alloys.
Type:
Grant
Filed:
November 19, 1987
Date of Patent:
September 27, 1988
Assignee:
Aluminum Company of America
Inventors:
Stephen C. Libby, G. Edward Graddy, Jr.
Abstract: A composite HCl adsorbent comprising about 50-95 wt % alumina and about 5-50 wt % Y zeolite wherein the molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 is about 4.5-6.0. The adsorbent is produced by admixing particles of alumina and acid-treated Y zeolite, agglomerating, aging and activating. The activated composite adsorbent has improved dynamic adsorption behavior for HCl compared with both the alumina and Y zeolite starting materials.
Type:
Grant
Filed:
June 2, 1987
Date of Patent:
August 9, 1988
Assignee:
Aluminum Company of America
Inventors:
Hubert L. Fleming, Kenneth P. Goodboy, Emmanuel K. Saforo
Abstract: A composite adsorbent useful for reducing the acidity and moisture content of used organophosphate functional fluids. The adsorbent is a powder having an average particle size of about 20-500 microns and total pore volume of at least about 0.40 cm.sup.3 /g and it comprises about 40-90 wt % alumina and about 10-60 wt % Y zeolite wherein the molar ratio of SiO.sub.2 to Al.sub.2 O.sub.3 is about 4.5-6.0. The adsorbent is preferably produced by agglomerating particles of activated alumina and Y zeolite into a composite agglomerate, aging the agglomerate and then comminuting to form a powder.
Abstract: Water contaminated with a trihalocarbon is passed through a first or second bed containing particles of an activated composite adsorbent comprising alumina and zeolite. The trihalocarbon is adsorbed onto the particles, thereby reducing trihalocarbon concentration in the water. The adsorbed trihalocarbon is reacted with air or steam at an elevated temperature in order to regenerate the adsorbent particles for reuse. Gaseous HCl produced in the reaction with air or steam may be adsorbed in a third bed containing adsorbent agglomerates.
Abstract: A stable monolithic gel produced by reacting an alumina hydrate sol with an organic reactant selected from the group consisting of polycarboxylic acids having esterified acid groups, anhydrides of polycarboxylic acids, and water-soluble cationic or neutral polyacrylamides. A particularly preferred gel is made by reacting an alumina monohydrate sol with dimethyl oxalate. The preferred monolithic gel remains transparent or slightly cloudy upon storage with little syneresis.
Abstract: A filler composition containing at least two surface modifiers and comprising a powdered inorganic filler, a carboxylic acid or mixture of carboxylic acids and an organosilane. A preferred filler composition comprises alumina trihydrate, isostearic acid and vinyl-tris (2-methoxyethoxy) silane. When filler compositions containing both the carboxylic acid and organosilane surface modifiers are blended with thermoplastic resins to form thermoplastic compounds, the resulting filled compounds display improved physical properties compared with controls.
Type:
Grant
Filed:
October 3, 1985
Date of Patent:
December 8, 1987
Assignee:
Aluminum Company of America
Inventors:
Lawrence L. Musselman, Thomas L. Levendusky
Abstract: A control system controlling the movements of a pneumatic percussion tool for breaking crust away from anode butts in an electrolysis cell. The system comprises a control arm extending through first and second plates connected to respective first and second valve stems. In a preferred embodiment, the first valve stem operates a hydraulic scissors jack for extending and retracting the tool, and the second valve stem operates a hydraulic rotator motor for radially rotating a mast supporting the tool. A preferred system also comprises a pneumatic control valve connected to the control arm for positioning and energizing the percussion tool.
Type:
Grant
Filed:
May 14, 1984
Date of Patent:
October 27, 1987
Assignee:
Aluminum Company of America
Inventors:
Dale R. Peinecke, Casimir B. Robak, Jr., Robert A. Dubs
Abstract: Metal articles are press-fitted together, using a lubricant dispersion comprising about 1-15 wt % colloidal graphite in isopropanol. The isopropanol is removed and the articles are then welded together at a joint to form a unitary weldment. The process is especially suitable for use on articles made from aluminum and aluminum alloys.