Abstract: Radiation-crosslinkable elastomeric compositions containing:
(a) an elastomeric polymer containing abstractable hydrogen atoms in an amount sufficient to enable the elastomeric polymer to undergo crosslinking in the presence of a suitable radiation-activatable crosslinking agent; and
(b) a radiation-activatable crosslinking agent of the formula:
wherein:
X represents CH3—; phenyl; or substituted-phenyl; or substituted-phenyl with the proviso that any substituents on the substituted-phenyl do not interfere with the light-absorbing capacity of the radiation-activatable crosslinking agent and do not promote intramolecular hydrogen abstraction of the radiation activatable crosslinking agent;
W represents —O—, —NH—, or —S—;
Z represents an organic spacer selected from the group consisting of aliphatic, aromatic, aralkyl, heteroaromatic, and cycloaliphatic groups free of esters, amides, ketones, urethanes, and also free of ethers, thiols, allylic grou
Type:
Grant
Filed:
August 14, 1995
Date of Patent:
April 9, 2002
Assignee:
3M Innovative Properties Company
Inventors:
Peter A. Stark, Edward G. Stewart, Albert I. Everaerts
Abstract: A photographic fixer compositions comprising a silver halide solvent, an aluminum salt hardening agent, a buffering agent and ammonium ions in amount of at least 0.20 mol/l, wherein said fixer composition also contains at least an aminopolycarboxylic acid sequestering agent of formula (I-a) or (I-b) or a water-soluble salt thereof and d) at least a polyphosphonic acid sequestering agent of formula (II-a), (II-b), (II-c), (II-d') or (II-d"): ##STR1## wherein the substituents are defined in the specification. The present invention also provides a method of processing an exposed photographic silver halide element comprising the steps of developing by means of a developer comprising a silver halide developing agent and treating the developed element with a fixer composition, wherein the fixer composition is one described above.
Type:
Grant
Filed:
July 15, 1996
Date of Patent:
October 19, 1999
Assignee:
Imation Corp
Inventors:
Filippo Faranda, Franco Buriano, Carlo Marchesano
Abstract: An image-forming element comprising a substrate, and an image-forming medium comprising (a) a compound absorbing at a first wavelength in the UV/blue region and (b) a dye absorbing at a second wavelength which is longer than the first wavelength, irradiation at said second wavelength bleaching absorption of said compound at said first wavelength, said element being free of thermally unstable urea and/or carbamate molecules.
Abstract: Photochemical acid progenitors in combination with dihydroperimidine squarylium dyes have been found to be particularly effective at generating acid upon irradiation with near-infrared radiation. It has been found that dihydroperimidine squarylium dyes that are particularly useful in this invention have an oxidation potential greater than about 0.5 V relative to SCE as measured in dichloromethane.
Type:
Grant
Filed:
May 13, 1996
Date of Patent:
June 9, 1998
Assignee:
Imation Corp
Inventors:
Stanley C. Busman, Richard J. Ellis, Jeanne E. Haubrich, William D. Ramsden, Tran Van Thien, Gregory D. Cuny
Abstract: The invention relates to a method of increasing the sensitivity of laser induced thermal imaging by using certain sublimable compounds. The invention is useful in the field of thermal transfer imaging for the production of various graphic arts media.
Type:
Grant
Filed:
April 3, 1996
Date of Patent:
May 5, 1998
Assignee:
Minnesota Mining And Manufacturing Company
Inventors:
Krzysztof A. Zaklika, Stanley C. Busman, Gregory D. Cuny
Abstract: A series of novel pyrrolo?2,1-a!isoquinoline dyes has been prepared using readily available starting materials via a simple synthetic pathway. These dyes have narrow absorption bands in the range of 500-900 nm. Those that absorb in the near-infrared region (700-1400 nm) lack significant absorption in the 300-400 nm ultraviolet region of the spectrum; this is an advantage for use in an applications such as imaging setting film. In addition, the greater thermal and chemical stability of these dyes in comparison to their indolizine analogues should be valuable in many applications.
Type:
Grant
Filed:
December 21, 1995
Date of Patent:
March 3, 1998
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: A photothermographic element comprising a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a chromogenic leuco dye reducing agent; and(d) a binder;wherein the chromogenic leuco dye reducing agent is a chromogenic leuco redox-dye-releasing compound of the general formula: ##STR1## wherein: (i) Cp is a coupler group;(ii) N--D is a photographic developer group; and(iii) R.sup.1 is a --C(O)--NH--A--Dye group wherein Dye represents the chromophore of a thermally mobile dye; and A represents a single bond or a divalent linking group of the formula --X--R.sup.5 --L--, wherein R.sup.5 is a divalent hydrocarbon chain containing up to 12 carbon atoms, L is a single bond or a divalent group that binds the chromophore of the thermally mobile dye to R.sup.5, and X represents a single bond or an --SO.sub.2 -- group.
Type:
Grant
Filed:
November 16, 1995
Date of Patent:
January 6, 1998
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Raffaella Biavasco, Lori S. Harring, Larry R. Krepski, Daniel E. Mickus, Mark B. Mizen, Sharon M. Simpson, Cristina Soncini, Kim M. Vogel
Abstract: 4-Substituted isoxazole compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
Type:
Grant
Filed:
March 14, 1996
Date of Patent:
January 6, 1998
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The present invention relates to a photographic film base comprising a transparent support base and a binderless layer of magnetic material coated thereon.According to another aspect, the present invention relates to a color photographic material comprising a photographic film base and at least one light-sensitive layer coated thereon, wherein said photographic film base comprises a transparent support base and a binderless layer of magnetic material coated thereon.
Type:
Grant
Filed:
April 30, 1996
Date of Patent:
December 30, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Phillip A. Taylor, Jeffrey M. Florczak, Mark A. Peterson, Paul R. Iverson, Joseph Skorjanec, Robert D. Lorentz
Abstract: A photothermographic element containing a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer is provided. The emulsion layer comprises:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a leuco dye reducing agent; and(d) a binder;wherein the leuco dye reducing agent comprises a blocked leuco dye compound of the general formula L-R.sup.1, which is capable of being oxidized to a colored form, wherein:(i) L is a group remaining after removal of a hydrogen from a leuco dye; and(ii) R.sup.1 is a C(O)-NH-SO.sub.2 -R.sup.5 group wherein R.sup.5 is an aliphatic group or an aromatic group.
Type:
Grant
Filed:
November 16, 1995
Date of Patent:
December 9, 1997
Assignee:
Minnesota Mining And Manufacturing Company
Inventors:
Larry R. Krepski, Sharon M. Simpson, Kim M. Vogel
Abstract: A process for preparation of 4-mercapto-1-naphthol compounds which comprises the steps of:(i) obtaining a 4-heterocyclylthio-1-naphthol compound by reacting a 1-naphthol compound with a heterocyclylsulfur chloride or by reacting a 4-iodo-1-naphthol compound with an alkali metal or ammonium salt of a mercaptoheterocyclic compound,(ii) hydrolyzing the resulting 4-heterocyclylthio-1-naphthol compound in the presence of a base to form a reaction product, and(iii) acidifying said reaction product.The resulting compounds are useful as intermediates in the synthesis of bleach accelerator releasing couplers for use in silver halide color photographic materials.
Abstract: The invention relates to a method of increasing the sensitivity of laser induced thermal imaging by using certain diazo compounds. The diazo compounds contain functional groups adjacent the diazo substituent capable of stabilizing these compounds. The invention is useful in the field of thermal transfer imaging for the production of various graphic arts media.
Type:
Grant
Filed:
April 3, 1996
Date of Patent:
November 25, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Stanley C. Busman, Gregory D. Cuny, Krzysztof A. Zaklika, Richard J. Ellis
Abstract: The present invention relates to a light-sensitive silver halide photographic material comprising a support and silver halide emulsion layer or layers, wherein at least one of said silver halide emulsion layers comprises an alkylaminomercaptotetrazole antifoggant. According to a preferred embodiment of the present invention said silver halide emulsion layer comprises tabular silver halide grains having an average aspect ratio higher than 3:1 and a thickness lower than 0.4 .mu.m.
Type:
Grant
Filed:
August 3, 1995
Date of Patent:
September 16, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: Positive-acting no-process printing plates are disclosed in which a stable visual or print-out image is obtained upon exposure of the plate to actinic radiation. The visual image is obtained by incorporation into the photosensitive layer, a dye which is irreversibly bleached upon exposure of the printing plate. For example, an acid which is generated upon exposure of a photopolymer to radiation may be used to bleach a dye of this invention. The visual or print-out images produced are useful in the production cycle and are stable to basic environments that may be encountered in the production setting.
Type:
Grant
Filed:
May 2, 1995
Date of Patent:
September 9, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Dennis E. Vogel, Robert J. Balchunis, James P. Gardner, George V.D. Tiers, Kim M. Vogel
Abstract: 2-Substituted malondialdehyde compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
Type:
Grant
Filed:
March 14, 1996
Date of Patent:
August 5, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: A process for preparation of 2-equivalent 4-arylthio-5-pyrazolone magenta couplers comprises the steps of:(i) reacting a 4-equivalent 5-pyrazolone magenta coupler and a diaryldisulfide compound in the presence of 1,8-diazabicyclo-[5,4,0]-undecen-7-ene and an organic solvent to obtain a reaction product between 4-arylthio-5-pyrazolone magenta coupler and 1,8-diazabicyclo-[5,4,0]-undecen-7-ene, and(ii) converting the reaction product with an inorganic acid into the 4-arylthio-5-pyrazolone magenta coupler.The reaction product between the 4-arylthio-5-pyrazolone magenta coupler and the 1,8-diazabicyclo-[5,4,0]-undecen-7-ene is easily formed in high yield and purity. This reaction product, which is insoluble in the reaction solvent, can be easily isolated from the reaction mixture and converted by acidification into the 2-equivalent 4-arylthio-5-pyrazolone magenta coupler in high yield and purity.
Abstract: Hydrogen atom donor compounds are useful as contrast enhancers when used in combination with (i) hindered phenol developers, and (ii) trityl hydrazide and/or formyl-phenyl hydrazine co-developers, to produce ultra-high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
Type:
Grant
Filed:
September 19, 1995
Date of Patent:
June 10, 1997
Assignee:
Imation Corp
Inventors:
Lori S. Harring, Sharon M. Simpson, Francis H. Sansbury
Abstract: Nitrogen containing 3-heteroaromatic substituted acrylonitrile compounds are useful as co-developers in combination with hindered phenol developers to produce high contrast black-and-white photothermographic and thermographic elements.The photothermographic and thermographic elements may be used as a photomask in a process where there is a subsequent exposure of an ultraviolet or short wavelength visible radiation-sensitive imageable medium.
Type:
Grant
Filed:
May 16, 1996
Date of Patent:
June 3, 1997
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The present invention provides a fixer composition and a method of processing an exposed photographic silver halide element comprising the steps of developing by means of a developer comprising a silver halide developing agent and treating the developed element with a fixer composition, wherein the fixer composition comprises a silver halide solvent, a sulfite ion source, an aluminum salt hardening agent, a buffering agent, a sequestering agent and an .alpha.-ketocarboxylic acid compound in an amount of more than 2 grams per liter corresponding to the formula:R--CO--COOHwherein R represents a hydrogen atom or an organic group.
Type:
Grant
Filed:
December 29, 1995
Date of Patent:
May 13, 1997
Assignee:
Imation Corp
Inventors:
Filippo Faranda, Elda Moizo, Carlo Marchesano
Abstract: The present invention relates to a method for the preparation of a tabular silver halide grain emulsion, wherein said silver halide emulsion comprises tabular grains having a thickness lower than 0.5 .mu.