Abstract: Disclosed are novel dry, non-tacky photopolymer precursors or isocyanate-free urethane oligomers which are the reaction products of heat reactive phenolic resins and unsaturated monoisocyanates, e.g. a methylol containing resole and isocyantoethyl methacrylate. The reaction product combined with a haloalkyl triazine photosensitizer and an inert organic solvent provides an excellent coating for a variety of substrates used in the printing and publishing industry, e.g. grained, anodized aluminum lithoplates. The presensitized lithographic plates can be used in aqueous alkaline based development processes and exhibit an increased resistance to solvent attack during the development and printing processes.

Abstract: Solubility inhibitors for phenolic resins are disclosed, which when used in phenolic resin/iodonium salt positive printing plate constructions result in significantly increased sensitivity. The solubility inhibitors contain an alkoxyalkyl ester moiety. Also disclosed are presensitized lithogaphic plates containing the solubility inhibitors and a process for developing a photoimage.

Abstract: The invention relates to a pressure-sensitive thermosetting adhesive comprising from about 30% to about 80% by weight of a photopolymerizable prepolymeric or monomeric syrup containing an acrylic ester and a polar copolymerizable monomer, from about 20% to about 60% by weight of an epoxy resin or a mixture of epoxy resins containing no photopolymerizable groups, from about 0.5% to about 10% by weight of a heat-activatable hardener for the epoxy resin, from about 0.01% to about 5% of a photoinitiator, and from 0% to about 5% of a photocrosslinking agent. In a preferred embodiment, imidazoles and thermally expandable thermoplastic microspheres are utilized in the inventive adhesive formulation.

Abstract: Disclosed are siloxanyl-substituted diaromatic iodonium salts such as 4-[3-1,1,3,3,5,5,5-heptamethyl siloxanyl propoxy]phenyl-phenyliodonium hexafluoroantimonate. These diaryl iodonium salts are useful as photoinitiators for epoxy containing compounds, especially epoxypolysiloxanes. Also disclosed is a process for the preparation of a siloxanyl-substituted diaromatic iodonium salt.

Abstract: Disclosed are novel compounds which are useful as initiators for cationically polymerizable monomers. The novel compounds comprise a carbon containing cation (e.g., trimethyloxonium) which is capable of initiating cationic polymerization and a non-nucleophilic counterion which is an at least partially fluorinated hydrocarbylsulfonato metallate (e.g. perfluoroethylsulfonato-aluminate). The disclosed initiators are capable of initiating the cationic polymerization of a wide variety of monomers such as epoxides, tetrahydrofuans, oxazolines, vinyls, lactones, and the like.

Abstract: The current invention provides a photopolymerized pressure-sensitive adhesive which adheres well to all common surfaces and has an outstanding ability to bond to plasticized vinyl substrates and to remain firmly bonded thereto even after the in contact therewith for extended periods of time comprising the photopolymerization reaction product of a mixture containing about: 60-95 parts of alkyl acrylate; 5-40 parts monoethylenically unsaturated polar copolymerizable monomer; 10-30 parts ethylene vinylacetate copolymer containing about 40% to 70% vinylacetate; and 0.1-1 part photoinitiator.

Abstract: Disclosed are photothermographic constructions containing at least a plurality of light-sensitive layers which are separated by barrier layers composed of a polymer, e.g., ethyl cellulose and polyethylene terephthalate, having an energy activation of permeability (E.sub.p) of less than about 30 kJ/mole. The barrier layers must be substantially insoluble in the light sensitive layers and vice versa. Each light sensitive layer contains a nitrate salt, leuco dye, binder, and optionally, a photoinitiator. The photothermographic construction is capable of effectively reproducing full color images.

Abstract: Stable latices of polymer particles insoluble in non-polar organic solvents are prepared by the attachment of the insoluble polymer particles to a stabilizer soluble in the non-polar organic solvent. The stabilizer comprises the adduct of a polymer bearing pendant azlactone groups which is soluble in non-polar organic solvents and an ethylenically unsaturated nucleophile bearing an azlactone reactive nucleophilic moiety.

Abstract: Liquid toners for developing electrophotographic images contain dispersed toner particles which are based on a polymer with multiple characteristics. These particles comprise a thermoplastic resinous core with a T.sub.g below room temperature which is chemically anchored to an amphipathic copolymer steric stabilizer containing covalently attached groups of organic acid containing moieties having pKa's less than 4.5 which in turn are chemically bonded to metal soap containing compounds derived from organic acids having a pKa greater than 4.5. The toner particles so formed have advantageous properties of high charge/mass, and good charge and dispersion stability.

Abstract: A water-base endothermic fire protective material comprising a heat curable thermosetting resin, inorganic fibers, an endothermic inorganic filler, and thermoplastic binder resin is disclosed. The material can vary in viscosity from a putty that is moldable or trowelable into place to a thin paste that can be sprayed to form a flexible and stable fire stop seal or coating. The material with essentially no shrinkage retains strength and adhesion qualities before and after exposure to fire and retains superior resistance to the impact, erosion, and cooling effects of a hose stream used to combat a fire.

Abstract: A method and article useful for preparing stable polysaccharide gels from aqueous solutions of water-soluble polysaccharides bearing pendant carboxylate groups. The gels produced may be of the foamed or nonfoamed variety.

Abstract: This invention relates to adhesives, surface modifying compositions, sealing compositions, and topical binder compositions comprising a copolymer having a vinyl polymeric backbone with grafted pendant siloxane polymeric moieties and especially to a method of topically applying such coating to animals.

Abstract: A photothermographic element comprising a support bearing an image forming system comprising:(a) a photosensitive silver halide(b) an organic silver compound(c) a polymer binder and(d) a reducing agent for the organic silver compound, characterized in that the reducing agent comprises a redox-dye-releasing compound of the general formula: ##STR1## in which: R represents an organic group which may be oxidatively cleaved to a thermally immobile form,A represents a bond or a divalent linking group having a chain consisting of up to 12 atoms, which is linked to the carbonyl group via a carbon atom or an oxygen atom, andD represents the chromophore of a thermally mobile dye.

Abstract: The adhesion of metal to a polyimide substrate is enhanced by depositing onto at least one surface of the polyimide a thin film of metal such as copper and heating in air to cause the deposited metal to texturize that surface by producing asperities that are at least 0.05 .mu.m in average height and average breadth. In doing so, metal oxide clusters are formed at the textured surface. When the textured surface is metallized, the resulting composite resists delamination even at soldering temperatures.

Abstract: A dimensionally stable alginate hydrogel foam wound dressing that absorbs wound exudate without any appreciable swelling. The wound dressing is formed-in-place in the wound cavity or on the wound surface from a reactive composition that foams as it gels. The water-insoluble alginate hydrogel foam based wound dressing is made by mixing together the ingredients of a two component system; applying the resulting composite liquid mixture to a wound site; and allowing the composite mixture to react. One component contains an aqueous suspension of certain di-or trivalent metal salts and an effervescent compound. The second component contains an aqueous solution of a biocompatible, water-soluble acid. At least one compound, and preferably both, contain a water soluble alginate.

Abstract: Zirconium based granules are produced by the steps of forming an aqueous solution of a zirconium compound such as zirconium acetate, combining the aqueous solution with a phase stabilizer, and then heating the solution to evaporation at a temperature below about 180.degree. C. preferably below thereby forming amorphous zirconium based granules.In an alternate embodiment, an alcohol solution of a zirconium compound such as zirconium propoxide in propanol is acidified and hydrolyzed with water. The partially or fully hydrolyzed zirconium complex is mixed with a phase stabilizer to form a homogeneous solution. The solution is then subjected to evaporation at a temperature below about 180.degree. C. or below to form amorphous zirconium based granules.Zirconia fibers are produced by making aqueous solution of the amorphous zirconium based granules containing the phase stabilizer to the desired viscosity, fiberizing the solution, and finally converting the fibers under appropriate conditions.

Abstract: A process for making a fibrous mat includes the steps of (a) combining (i) glass fibers, (ii) polyolefine fibers, (iii) fibers selected from the group consisting of polyamide fibers, polyester fibers, and mixtures thereof, and (iv) a cross-linked latex binder, (b) consolidating the fibers and binder into a loosely packed mat, (c) curing the consolidated mat at a temperature in the range of about 250-400 F., and (d) molding the cured mat into a desired shape at ambient temperature.

Abstract: An automotive headliner comprised of a laminate of double corrugated paperboard. Perforations in all the sheets of the laminate except the back paperboard sheet improve the acoustical performance of the liner. A vapor barrier on the back sheet prevents entry of moisture into the laminate from the roof, and a layer of sound dampening material on the front face of the laminate improves the sound absorption of the laminate. The front corrugation is larger than the back corrugation. When molding the laminate it is first moisturized, then heat molded. Heat is applied until the laminate has regained its rigidity.

Abstract: An expansion joint having a weather resistant cover and a fire barrier. The cover is a bellows attached to the upper surface of the adjacent joint structure by mounting flanges, and the barrier is a fire resistant inorganic fabric sheet mounted in the joint. The fabric supports resilient fire resistant inorganic fibrous insulation and is connected to the adjacent joint structure by mounting flanges. The flanges may be in the form of a bifurcated clamp, and one of the fabric-engaging clamp faces may be crimped and pierced to better grip the fabric.

Abstract: An electric furnace for melting batch material and mixing the molten material. Electrodes are used to create what is believed to be electromagnetically stirred active melting areas within the molten material. The molten material is stirred by moving the electrodes and furnace shell with respect to each other while the electrodes are positioned in a corona discharge relationship to the melt. This can be implemented by rotating the electrodes or the shell or by a compound movement caused by moving the electrode support arms toward and away from the center of the vessel in timed relationship to pivotal movement of electrode support arms so as to cause the electrode tips to traverse an arcuate path concentric with the center of the vessel. In a shallow immersion, simple pivoting of the electrode support arms is beneficial. To further decrease the dead area within a furnace vessel utilizing electrodes which are shallowly immersed, the vessel can be made polygonal as opposed to circular in lateral cross section.