Abstract: Reduction of mottle and other surface anomalies in photothermographic and thermographic elements is reduced by the incorporation of a fluorinated polymer containing at least two different groups within the polymer chain derived from reactive monomers, the groups being: a fluorinated, ethylenically unsaturated monomer; and a polar, ethylenically unsaturated monomer.
Type:
Grant
Filed:
March 24, 1995
Date of Patent:
July 2, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: Ribonucleic acid (RNA) compounds have been found to function as antifoggants and post-processing print stabilizers in photothermographic elements.
Type:
Grant
Filed:
April 25, 1995
Date of Patent:
May 28, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Takuzo Ishida, Frank J. Manganiello, Kumars Sakizadeh
Abstract: A thermal transfer dye donor element containing at least one substrate coated with a layer containing binder and at least one .beta.-cyano-.beta.-trifluoromethanesulfonyl-p-N,N-dialkylaminostyrene yellow dye. Also disclosed is a process for the imagewise transfer of the yellow dye to a receiving element.
Type:
Grant
Filed:
September 14, 1995
Date of Patent:
May 28, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Kevin D. Landgrebe, Terrance P. Smith, Jeffrey C. Chang
Abstract: Sulfonyl hydrazides are used as developers in phothothermographic and thermographic elements. The sulfonyl hydrazides have the formula:R.sup.1 --CO--NHNH--SO.sub.2 --R.sup.2wherein R.sup.1 and R.sup.
Type:
Grant
Filed:
August 21, 1995
Date of Patent:
April 30, 1996
Assignee:
Minnesota Mining & Manufacturing Company
Inventors:
Doreen C. Lynch, Sharon M. Simpson, Paul G. Skoug
Abstract: Trityl hydrazides and formyl-phenyl hydrazines are useful as co-developers with hindered phenols in phothothermographic and thermographic elements. These co-developers have the formula:R.sup.1 --(C.dbd.O).sub.n --NHNH--R.sup.2R.sup.1 represents hydrogen and R.sup.2 represents an aryl or substituted aryl group; or,R.sup.1 represents hydrogen, alkyl and alkenyl groups of up to 20 carbon atoms; alkoxy, thioalkoxy, or amido groups of up to 20 carbon atoms; aryl, alkaryl, or aralkyl groups of up to 20 carbon atoms; aryloxy, thioaryloxy, or anilino groups of up to 20 carbon atoms; aliphatic or aromatic heterocyclic ring groups containing up to 6 ring atoms; carbocyclic ring groups comprising up to 6 ring carbon atoms; or fused ring or bridging groups comprising up to 14 ring atoms; and R.sup.2 represents a trityl group.
Type:
Grant
Filed:
January 6, 1995
Date of Patent:
March 5, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: A photothermographic element comprising a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a reducing agent for the non-photosensitive reducible silver source; and(d) a binder;wherein the reducing agent is a hydrazide redox-dye-releasing compound of the general formulae: ##STR1## wherein: D represents the chromophore of a thermally mobile dye; X represents a single bond or a divalent linking group; R.sup.1 and R.sup.2 independently represent an organic group; and n.gtoreq.1.
Type:
Grant
Filed:
January 6, 1995
Date of Patent:
February 20, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Kevin D. Landgrebe, Doreen C. Lynch, Sharon M. Simpson, Justine A. Mooney, Andrew W. Mott, Duncan M. A. Grieve, John H. A. Stibbard, Robert J. D. Nairne, Stephen S. C. Poon, David C. Bays
Abstract: A photothermographic element comprising a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a chromogenic leuco dye reducing agent; and(d) a binder;wherein the chromogenic leuco dye reducing agent is a chromogenic leuco redox-dye-releasing compound of the general formula: ##STR1## wherein: (i) Cp is a coupler group;(ii) N--D is a photographic developer group; and(iii) R.sup.1 is a --C(O)--NH--A--Dye group wherein Dye represents the chromophore of a thermally mobile dye; and A represents a single bond or a divalent linking group of the formula --X--R.sup.5 --L--, wherein R.sup.5 is a divalent hydrocarbon chain containing up to 12 carbon atoms, L is a single bond or a divalent group that binds the chromophore of the thermally mobile dye to R.sup.5, and X represents a single bond or an --SO.sub.2 -- group.
Type:
Grant
Filed:
June 30, 1994
Date of Patent:
February 20, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Raffaella Biavasco, Lori S. Harring, Larry R. Krepski, Daniel E. Mickus, Mark B. Mizen, Sharon M. Simpson, Cristina Soncini, Kim M. Vogel
Abstract: A photothermographic element containing a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer is provided. The emulsion layer comprises:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible source of silver;(c) a leuco dye reducing agent; and(d) a binder;wherein the leuco dye reducing agent comprises a blocked leuco dye compound of the general formula L-R.sup.1, which is capable of being oxidized to a colored form, wherein:(i) L is a group remaining after removal of a hydrogen from a leuco dye; and(ii) R.sup.1 is a C(O)--NH--SO.sub.2 --R.sup.5 group wherein R.sup.5 is an aliphatic group or an aromatic group.
Type:
Grant
Filed:
June 30, 1994
Date of Patent:
February 20, 1996
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Larry R. Krepski, Sharon M. Simpson, Kim M. Vogel
Abstract: A photothermographic or thermographic imaging element having uniform optical density is described which is useful in automated equipment. A polymeric fluorinated surfactant is present in a layer adjacent to the photothermographic or thermographic emulsion layer to provide uniform optical density. Optically transparent polymeric beads are present in at least one outermost layer of the imaging element to assist in the separation and sliding of the elements when subjected to a film feeding mechanism in automated equipment.
Type:
Grant
Filed:
November 16, 1994
Date of Patent:
November 21, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: Novel silver-carboxylate/1,2-diazine compounds having the formula: ##STR1## wherein: R.sup.1 represents either an alkyl, aralkyl, cycloalkyl, or alkenyl group of up to 29 carbon atoms; or an aryl group of up to 14 carbon atoms; andand R.sup.2 represents either hydrogen, an alkyl group, a cycloalkyl group fused to the 1,2-diazine ring, or the atoms necessary to complete a 5- or 6-membered aromatic ring fused to the 1,2-diazine ring.The novel silver-carboxylate/1,2-diazine compounds are coordination compounds of two silver-carboxylate molecules and two molecules comprising a 1,2-diazine nucleus. These compounds can serve as the silver source in a black-and-white thermographic or photothermographic element or as the oxidizing agent for a dye-based thermographic or photothermographic color-imaging construction.
Abstract: Sulfonyl hydrazides are used as developers in phothothermographic and thermographic elements. The sulfonyl hydrazides have the formula:R.sup.1 --CO--NHNH--SO.sub.2 --R.sup.2wherein R.sup.1 and R.sup.
Type:
Grant
Filed:
January 6, 1995
Date of Patent:
November 7, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Doreen C. Lynch, Sharon M. Simpson, Paul G. Skoug
Abstract: Post-processing stabilizers for photothermographic, silver imaging media are disclosed. The stabilizers are represented by the following general formulae: ##STR1## wherein: R.sup.1, R.sup.2, and R.sup.3 are independently H, halogen, an alkyl group, an alkoxy group, a thioalkyl group, a cycloalkyl group, a perhalogenated alkyl group, or taken together form a cycloaliphatic group.Compounds of formula (I) may be used as stabilizer precursors in photothermographic silver imaging media to provide post-processing stability without significantly adversely affecting desired properties of the photothermographic material.
Type:
Grant
Filed:
November 30, 1994
Date of Patent:
November 7, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Kumars Sakizadeh, John T. Blair, David T. Ask
Abstract: A fingerprinting system comprising means capable of releasably retaining a liquid and a liquid composition releasably retained in said means, said liquid composition comprising a leuco color-former coupound, a dialkyl phthalate wherein the alkyl group contains 1-3 carbon atoms, a substrate for receiving fingerprints associated therewith, said substrate being coated on at least a portion of one surface thereof with a color developing substance comprising a phenol/aldehyde condensation product produced by the reaction together of an alkyl-substituted salicylic acid, an alkyl-substituted phenol, and an aldehyde, said condensation product having been reacted with a metal source.
Abstract: Metal-Azomethine dyes with excellent solubility in organic media. The dyes have an arene nucleus and are substituted, in part, with a non-free-radically polymerizable alkyldiketonate or 8-hydroxyquinolate ligand. The dyes are useful in dye diffusion transfer processes.
Type:
Grant
Filed:
April 19, 1995
Date of Patent:
October 24, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: The growth of a phosphor layer deposited on a patterned substrate containing a multiplicity of recessed ridges of triangular cross section can be controlled by tailoring the geometry of the recessed ridge structures. During the deposition process, little or no phosphor deposition occurs on the recessed ridge structures, and cracks are formed which separate the otherwise uniformly growing phosphor which is present in other regions of the patterned substrate where more substantial phosphor deposition occurs.
Type:
Grant
Filed:
October 17, 1994
Date of Patent:
October 24, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Nang T. Tran, Kenneth R. Paulson, Bruce A. Sventek
Abstract: Photothermographic elements of the photothermographic type may be sensitized to the infrared with sensitizing dyes of the formula: ##STR1## wherein: R.sup.1 represents a (CH.sub.2).sub.n --COO.sup.- group of from 1-20 carbon atoms, or an alkyl group of from 1 to 20 carbon atoms; andn is an integer from 1 to 20.
Type:
Grant
Filed:
January 26, 1995
Date of Patent:
August 15, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
James R. Miller, Sam Kalousdian, Brian C. Willett, John M. Winslow, Pu Zhou, Chaofeng Zou
Abstract: Photothermographic elements having improved post-processing stabilty are described. These elements comprise a support bearing at least one photosensitive, image-forming photothermographic-emulsion layer comprising:(a) a photosensitive silver halide;(b) a non-photosensitive, reducible silver source;(c) a reducing agent for said non-photosensitive, reducible silver source,(d) a binder; and(e) a compound capable of releasing a post-processing stabilizer having a nucleus of the formula: ##STR1## wherein: A represents any monovalent group for which the corresponding compound AH functions as a post-processing stabilizer.
Type:
Grant
Filed:
June 24, 1994
Date of Patent:
August 8, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Ramaiah Muthyala, Raymond J. Kenney, Frank J. Manganiello, Kumars Sakizadeh, Sharon M. Simpson
Abstract: This invention relates to improved imaging systems based on the formation of yellow colored coordination compounds of transition metals with certain ligands. These coordination compounds have been found to provide excellent yellow colors when used in pressure sensitive carbonless copy-papers wherein the image is formed by the reaction of a color-forming compound with transition metal salts such as those of nickel, cobalt, iron, copper, and similar materials. These yellow color-formers have the advantage of high solubility in encapsulation solvents and have less color on Zn.sup.2+ containing CB sheets. Use of these yellow color-formers with other metal complex color-formers such as N-(monosubstituted)dithiooxamide color-formers and N,N'-(disubstituted)dithiooxamides results in the formation of black images.
Type:
Grant
Filed:
September 6, 1994
Date of Patent:
June 20, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Loren D. Albin, Martha Jacobson, David B. Olson
Abstract: A pixelized phosphor screen having an array of pixelized phosphors on a support which are separated a width of from greater than 0.0 to 5.0 microns. In order to produce the phosphor screen, phosphor is deposited on a support and then exposed to radiation to create an array of pixelized phosphors separated by slots. The resulting slots between the pixelized phosphors are then filled in with additional phosphor material such that the width between the pixelized phosphors is from greater than 0.0 to 5.0 microns.
Type:
Grant
Filed:
February 10, 1994
Date of Patent:
May 23, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Abstract: A photographic emulsion containing: a photosensitive silver halide; a light-insensitive, reducible silver source; a reducing agent for the light-insensitive, reducible silver source; and a binder consisting essentially of poly(vinyl butyral) having a poly(vinyl alcohol) content of about 17.5 to 21.0 wt. % and at least one solvent selected from the group consisting of: toluene, methyl ethyl ketone, acetone, tetrahydrofuran, and 1,4-dioxane. Additionally, a process for coating a substrate involving applying at least one layer of a molten thermoreversible organogel layer; causing it to gel; and removing residual solvent.
Type:
Grant
Filed:
February 17, 1994
Date of Patent:
May 16, 1995
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Kenneth L. Hanzalik, George H. Crawford, Jr., Sharon M. Rozzi, David J. Scanlan