Abstract: A sulfuric acid catalyst is made by passing sulfur dioxide gas into an aqueous mixture of vanadium oxide, sulfuric acid, and a potassium salt compatible with the reducing reaction in situ, until a clear blue solution is obtained, wetting diatomaceous earth with this solution, drying and then calcining to provide an active supported catalyst. The process eliminates the necessity for activating the catalyst prior to use by exposure to a gas-stream containing sulfur dioxide and sulfur trioxide.