Abstract: Bicyclic piperidine compounds of the general formula (I) ##STR1## in which R.sub.1 is hydrogen, O.cndot., OH, NO, CH.sub.2 CN, C.sub.1 -C.sub.8 -alkyl, allyl, benzyl, C.sub.1 -C.sub.8 -acyl, OH-monosubstituted C.sub.2 -C.sub.4 -alkyl, 2,3-epoxypropyl, C.sub.1 -C.sub.18 -alkyloxy, C.sub.5 -C.sub.12 -cycloalkyloxy or 2,3-dihydroxypropyl and R.sub.2 is a direct bond or --CH.sub.2 --, can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular, synthetic polymers.
Abstract: A new beta quinacridone polytype having a magenta color and a distinct X-ray diffraction pattern, said new form preferably having an average particle size of about 0.2-0.8 .mu.m and being prepared by various wet milling or reflux procedures in alcohol-base systems.
Abstract: Novel compositions are described which contain an elastomer or a tackifying resin and at least one compound of formula I ##STR1## The symbols R.sub.1 is alkyl or cycloalkyl, R.sub.2 is alkyl, hydroxyalkyl, phenyl or benzyl, and R.sub.3 is hydrogen or methyl with the proviso that, when R.sub.1 is other than methyl, R.sub.3 is methyl.
Abstract: The novel compounds of the formula (I) ##STR1## in which n is 1 or 2, R.sub.1 is hydrogen, 0.sup..multidot. NO, cyanomethyl, C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.6 alkenyl or C.sub.3 -C.sub.6 alkynyl subject to the proviso that the carbon atom attached to the nitrogen atom is a primary carbon atom, benzyl, C.sub.1 -C.sub.7 acyl or OH-monosubstituted C.sub.2 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or phenyl, R.sub.3 is a group of the formula (II) ##STR2## with R.sub.6 being as defined for R.sub.1, R.sub.4 is --COOR.sub.3 or --CN and, if n is 1, R.sub.5 is hydrogen, C.sub.1 -C.sub.18 alkyl, C.sub.2 -C.sub.4 alkyl substituted by C.sub.1 -C.sub.12 alkoxy or di(C.sub.1 -C.sub.6 alkyl)amino, or C.sub.5 -C.sub.12 cycloalkyl unsubstituted or substituted by 1, 2 or 3 C.sub.1 -C.sub.4 alkyl radicals, benzyl, benzyl substituted by 1, 2 or 3 C.sub.1 -C.sub.4 alkyl radicals, or a group of the formula (II), and, if n is 1 and R.sub.4 is --CN, R.sub.
Abstract: Optically active iridium complexes of the formula ##STR1## in which R is methyl and R.sup.1 is a hydrocarbon radical having at least one chiral C atom or a hydrocarbon radical containing at least one hetero atom and having at least one chiral C atom; or R is a hydrogen atom and R.sup.1 is 1,2-diphenylethyl or a 5-membered or 6-membered cycloaliphatic or cycloheteroaliphatic radical having at least two chiral C atoms and a phenyl group or alkyl group in the .alpha.-position, X.sup..crclbar. is an anion of a monobasic inorganic or organic acid and Y and Z are each ethylene, or Y and Z together represent an open-chain or cyclic diene which has 6 to 10 C atoms and whose diene groups are bonded via 1 or 2 C atoms.They are suitable as enantioselective, homogeneous catalysts for the transfer hydrogenation of, in particular, prochiral ketones with secondary alcohols.
Abstract: A container of hardened, fiber-reinforced synthetic resin and high stability is manufactured by forming a wound-up structure on a shaping core born on the shaft of a winding machine together with fittings for the two open container ends, of different size, and being clamped against the two core ends by means of fixing members held in position on the winding shaft during winding. One of the fittings is provided with an annular groove for anchoring the wound-up structure therein. The fixing members and fittings are of such shape that the winding affords a wound-up structure having end openings of equal size so that a geodetic depositing of the wrapped layers is possible. After the structure is hardened, the portion thereof extending beyond the fitting having an opening of larger diameter than that closed by the other fitting is cut off, so that a container closed by the first fitting and open through the second fitting is obtained.
Abstract: The novel UV-absorbers are compounds of the formula ##STR1## in which R.sup.1 is, for example, hydrogen, n is one of the numbers 1 or 2 and R.sup.2 is an appropriate monovalent or divalent radical, for example --OH or --O--CH.sub.2 CH.sub.2 --O--. The UV-absorbers are used in particular for stabilising and improving lacquers and photographic material.
Abstract: Optically active iridium complexes of the formula I and mixtures of the diastereomers ##STR1## in which R.sup.1 and R' are H and A is a radical of the formula II, IIa or IIb ##STR2## or R.sup.1 and R' represent a bond and A is a radical of the formula IIc ##STR3## in which R.sup.2 is --H or --CH.sub.3, X.sup..crclbar. is an anion of an inorganic or organic acid, Y and Z are each ethylene, or Y and Z together represent an open-chain or cyclic diene having 6-10 C atoms, whose double bonds are separated by one or two C atoms, and R is a hydrocarbon radical having at least one chiral C atom or a hydrocarbon radical having at least one hetero atom and at least one chiral C atom, or A is a radical of the formula II, IIa or IIb and R is phenyl, naphthyl, 2-methylphen-1-yl or 2,6-dimethylphen-1-yl. The complexes are suitable as enantioselective catalysts.
Abstract: A conveying apparatus for panels is equipped with two revolving endless conveyor belt members such as chains etc. The chains are connected with each other with successively arranged transverse organs such as cross bars. On each cross bar there are mounted displaceably with braking two panel-engaging devices comprising clamping springs for gripping and transferring panels from a charging to a discharging station past a random number of intermediate processing stations. Two pneumatically operable pusher members push the panel-engaging devices into contact with the lateral edges of an arriving panel and cause the clamping springs to grip the panel. At the discharging station, two separating pusher members of similar construction open the clamping springs and push the panel-engaging devices apart toward their terminal positions at opposite ends of their cross bar, thus setting the panel free to be discharged from the apparatus.
Type:
Grant
Filed:
September 14, 1988
Date of Patent:
July 18, 1989
Assignee:
Ciba-Geigy Corporation
Inventors:
Peter Martin, Hansjorg Singenberger, Viktor Lechleitner
Abstract: Photosensitive compositions of matter which are capable of undergoing condensation or addition reactions and may or may not be crosslinkable, and which contain an anthraquinone of the formula I ##STR1## in which X, X', R' and R" are as defined in Patent Claim 1 and X or X' is, for example, --OH or --NH.sub.2, at least one monomeric, oligomeric or polymeric compound which can be reacted with this antraquinone, for example, if X is --OH, a polymer with terminal glycidyl groups, and, where relevant, a crosslinking agent and/or a salt of a metal of group Ib or VIII of the periodic table, are suitable for image formation by means of electroless metal deposition.
Type:
Grant
Filed:
April 20, 1988
Date of Patent:
July 18, 1989
Assignee:
Ciba-Geigy Corporation
Inventors:
Jurgen Finter, Walter Fischer, Friedrich Lohse
Abstract: An anode for aqueous electrolyses, consisting of a frame or support and a porous substrate which is connected to the frame and in which electrochemically active substances are dispersed. The substrate consists of titanium which is doped with chromium or nickel.
Abstract: Chlorine-containing polymer containing (a) at least one compound of the formula I ##STR1## in which R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl, phenyl or phenyl which is substituted by C.sub.1 -C.sub.4 -alkyl or halogen, n is 1 or 2 and, if n is 1, R is C.sub.1 -C.sub.20 -alkyl, C.sub.1 -C.sub.20 -alkyl which is substituted by --OH or --SH, C.sub.2 -C.sub.20 -alkyl which is interrupted by ##STR2## phenyl, phenyl which is substituted by C.sub.1 -C.sub.4 -alkyl, benzyl, benzyl which is substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.5 -C.sub.6 -cycloalkyl or --NR.sup.2 R.sup.3 in which R.sup.2 and R.sup.3 are identical or different and are as defined for R.sup.1, and, if n is 2, R is a direct bond, C.sub.1 -C.sub.10 -alkylene, C.sub.1 -C.sub.10 -alkylene which is substituted by phenyl, benzyl, --OH, C.sub.1 14 C.sub.4 -alkoxy, C.sub.1 -C.sub.20 -acyloxy, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl or C.sub.2 -C.sub.10 -alkylene which is interrupted by ##STR3## in which R.sup.
Abstract: The invention relates to complexes of formula I ##STR1## wherein R.sup.1 is fluorine and R.sup.2 is hydrogen, or R.sup.2 is fluorine and R.sup.1 is hydrogen, and Y is bromine, or Y is also chlorine if R.sup.1 is hydrogen. These complexes are organic compounds which exhibit high electrical conductivity.
Abstract: Compounds containing at least 5 mol % of structural units of the formulae I and/or II ##STR1## in which Q is an unsubstituted or substituted tetravalent aromatic radical to which in each case two carbonyl groups are bonded in the ortho- or peri-position, R.sup.1 is selected from the radicals of the formulae III, IV and V ##STR2## R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are hydrogen, alkyl, cycloalkyl or substituted or unsubstituted aryl or aralkyl, R.sup.6 and R.sup.7 are aryl or halogen, m and n are 0, 1 or 2 and o is 0, 1, 2, 3 or 4, are described.The compounds are distinguished by an increased resistance to oxidation by heat. They can be used to produce coatings and relief structures.
Abstract: Novel salts of methylphosphonic acid with primary amines are described. These compounds are preferably used as extreme pressure additives in lubricant compositions.
Abstract: Co-advanced epoxy resins prepared by the reaction of polyethers of polyhydric phenols, diglycidyl ethers of di-secondary alcohols and dihydric phenols, said co-advanced resins being heat curable with suitable curing agents to afford cured coating compositions exhibiting a variety of excellent physical properties and performance characteristics.The diglycidyl ethers have the following formula: ##STR1## as defined in the specification.
Abstract: Surface modification of a variety of pigments, particularly quinacridone pigments, and the pigments resulting therefrom whereby the pigment is treated with a solvent-free, basic, nitrogen-containing copolymer of the polyurethane series and with a dispersion-improving derivative of the primary pigment resulting in compositions exhibiting enhanced performance in automative and other finish systems.
Abstract: A compound of formula (I) ##STR1## in which R.sub.1 and R.sub.2 are e.g. hydrogen or methyl, R.sub.3 is e.g. a group ##STR2## or a group R.sub.5 X-- with R.sub.5 being e.g. hydrogen, C.sub.1 -C.sub.18 -alkyl or C.sub.3 -C.sub.18 -alkenyl and X being e.g. --O--, --S-- or ##STR3## and R.sub.6 is as defined for R.sub.5, or R.sub.3 represents a 5-membered to 7-membered nitrogen containing heterocyclic group with the free valency on the nitrogen, n is an integer from 2 to 6, and R.sub.4 is a nitrogen containing organic radical of a valency equal to n.The compounds of formula (I) are particularly effective in stabilizing organic material against oxidative, thermal and/or light induced degradation.
Abstract: Benzoin esters of aromatic sulfonic acids can be obtained in high yield from benzoin and the respective sulfonyl halide in molar amounts of a base by carrying out the reaction at low temperature in an organic solvent with the addition of water. Aqueous NaOh or KOH can be used as base in this process.
Abstract: In a process for measuring the variations in volume, especially shrinkage measurements in duroplastics during the hardening, the material to be measured is acted upon by such a pressure that a fully homogeneous test piece is obtained without any fractures or blisters. Simultaneously and independently from one another, the impinging pressure, the pressure exerted through the test piece on the floor, the temperature in the test piece and in its environs and the volume of the test piece are measured under non-isothermal conditions and fed into a digital unit.