Abstract: The present invention relates to a method of synthesizing 1-chloro-1-iodoethane by reacting hydrogen iodide with vinyl chloride monomer in the presence of an iodine containing catalyst under certain specified conditions. The resulting product of the reaction is a high yield, high purity 1-chloro-1-iodoethane which is useful as a chain transfer agent in the polymerization of vinyl chloride monomer. The 1-chloro-1-iodoethane formed by the instant invention can be made separately in a conventional synthesis apparatus or the compound can be synthesized in situ in the reaction vessel used for polymerization of vinyl chloride.
Type:
Grant
Filed:
May 19, 1994
Date of Patent:
July 4, 1995
Assignee:
The Geon Company
Inventors:
Philip I. Bak, Gregory P. Bidinger, Ross J. Cozens, Paul R. Klich
Abstract: The present invention relates to a method of synthesizing 1-chloro-1-iodoethane by reacting hydrogen iodide with vinyl chloride monomer in the presence of an iodine containing catalyst under certain specified conditions. The resulting product of the reaction is a high yield, high purity 1-chloro-1-iodoethane. This 1-chloro-1-iodoethane is useful as a chain transfer agent in the polymerization of vinyl chloride monomer in a process which mimics a pseudo-living radical polymerization.
Type:
Grant
Filed:
March 22, 1993
Date of Patent:
September 6, 1994
Assignee:
The Geon Company
Inventors:
Philip L. Bak, Gregory P. Bidinger, Ross J. Cozens, Paul R. Klich