Patents Represented by Attorney Henry E. Millson
  • Patent number: 5712235
    Abstract: New toilet soaps contain: (a1) 4 to 7% by weight alkyl and/or alkenyl oligoglycosides and/or (a2) 2 to 7% by weight fatty acid N-allcylpolyhydroxyalkylamide; (b) 45 to 95% by weight soap and (c) 0 to 10% by weight anionic surfactants selected from the group of alkyl sulphates, isethionates, taurides, sarcosinates, mono- and dialkylsulfosuccinates, ether carboxylic acids, sulphotriglycerides and alkyloligoglucoside sulphates. These new soaps are characterized among others by an improved creaminess, a high foaming power, remarkable cosmetic compatibility with the skin and mechanical firmness.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: January 27, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Claus Nieendick, Gerhard Wollmann, Bernd Richter, Karl-Heinz Schmid, Andreas Syldath, Bernd Fabry
  • Patent number: 5705462
    Abstract: A bar soap comprising:A) from about 70 to about 85% by weight of at least one fatty acid salt,B) from about 0.5 to about 10% by weight of at least one fatty acid,C) from about 1 to about 10% by weight of at least one alkyl ether sulfate, andD) from about 0.1 to about 1% by weight of at least one of an alkyl oligoglycoside and an alkenyl oligoglycoside.
    Type: Grant
    Filed: April 26, 1996
    Date of Patent: January 6, 1998
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Marlene Hormes, Werner Schneider, Wolfhard Scholz, Udo Hennen
  • Patent number: 5696074
    Abstract: Liquid crystalline aqueous surfactant compositions containing alkyl glycosides, long-chain alcohols, and, optionally, anionic surfactants; and to finished products containing them.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: December 9, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Dieter Nickel, Rainer Hofmann, Manfred Weuthen
  • Patent number: 5688976
    Abstract: The invention relates to a process for producing 8.alpha.,12-oxido-13,14,15,16-tetranorlabdane through the cyclizing dehydration of 8.alpha.,12 -dihydroxy-13,14,15,16-tetranorlabdane in the presence of aluminophyllosilicates.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: November 18, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Andreas Bomhard, Ulf-Armin Schaper, Theo Stalberg, Thomas Markert
  • Patent number: 5688759
    Abstract: Nitrogen-free anionic conditioning formulations containing sulfated polyol fatty acid esters corresponding to formula (I): ##STR1## in which R.sup.1 CO is a linear or branched, saturated or unsaturated acyl radical containing 6 to 22 carbon atoms, R.sup.2 represents hydrogen, an OCR.sup.1 group or an SO.sub.3 X group, R.sup.3 is hydrogen or an (OCH.sub.2 CH.sub.2).sub.m OR.sup.2 group, n is 0 or a number of 1 to 5, m is 0 or a number of 1 to 10, and X is an alkali metal, alkaline earth metal, ammonium, alkylammonium, alkanolammonium or glucammonium ion.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: November 18, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Ansgar Behler, Gunther Uphues, Bernd Wahle
  • Patent number: 5686400
    Abstract: Liquid manual dishwashing detergent compositions which exhibit superior foaming and detergency properties in laboratory tests are comprised of alkyl sulfates, .alpha.-olefin sulfonates alkyl betaines, and alkyl polyglycosides.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: November 11, 1997
    Assignee: Henkel Corporation
    Inventors: Allen D. Urfer, Virginia L. Lazarowitz
  • Patent number: 5683612
    Abstract: Spin finishes for synthetic filament fibers which contain a water-soluble polyether carbonate of the formula I:R.sup.1 --O--((R.sup.2 --O--).sub.n COO--).sub.m R.sup.3 (I)in which R.sup.1 represents R.sup.4 (O--CH.sub.2 --CH.sub.2 --).sub.x O--CO--, CH.sub.3 --O--CO, CH.sub.3 --CH.sub.2 --O--CO, or hydrogen; R.sup.2 is a difunctional hydrocarbon radical containing 1 to 22 carbon atoms which may be saturated or unsaturated, linear or branched; R.sup.3 represents R.sup.4 (O--CH.sub.2 --CH.sub.2 --).sub.y ; R.sup.4 is a monofunctional hydrocarbon radical containing 1 to 22 carbon atoms which may be saturated or unsaturated, linear or branched; n is an integer of 1 to 100; m is an integer of 1 to 50; x is an integer or 11 to 100; and y is an integer of 11 to 100.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: November 4, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Paul Birnbrich, Norbert Bialas, Ulrich Eicken, Raymond Mathis
  • Patent number: 5684089
    Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: November 4, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Thierry Lanoye, Anne-Marie Garnault
  • Patent number: 5677160
    Abstract: An improved fat splitting process which eliminates the induction period encountered during pressure splitting. A partial hydrolysis is conducted prior to pressure splitting by combining a lipase in the presence of water with the fat or oil to be hydrolyzed with added agitation. Pressure splitting of this partially split triglyceride eliminates or reduces the induction period.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: October 14, 1997
    Assignee: Henkel Corporation
    Inventors: Dean A. Oester, Allen L. Hall, Karl T. Zilch, Kevin W. Anderson
  • Patent number: 5676955
    Abstract: This invention relates to a mixture of homologous narrow range lauryl polyglycol ethers, to its use as a local anaesthetic agent.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: October 14, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Achim Ansmann, Ansgar Behler, Rolf Franke, Peter Schmersahl
  • Patent number: 5670677
    Abstract: A process for the production of color- and odor-stable quaternized fatty acid triethanolamine ester salts comprising the steps ofA) partially or fully esterifying triethanolamine with at least one fatty acid in the presence of hypophosphorous acid;B) adding a peroxide compound and an alkali metal boranate to the esterification product from step A); andC) quaternizing the esterification product with an alkyl halide, a (di)alkyl sulfate or an alkylene oxide in the presence of a phenol derivative and a hydroxycarboxylic acid.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: September 23, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Oriol Ponsati Obiols, Joaquim Bigorra Llosas
  • Patent number: 5670670
    Abstract: In a process for the production of 8.alpha.,12-oxido-13,14,15,16-tetranorlabdane by dehydration of 8.alpha.,12-dihydroxy-13,14,15,16-tetranorlabdane (diol), wherein the diol is subjected to cyclizing dehydration in the presence of 5 to 80% by weight, based on the diol, of at least one alumino layer silicate selected from K catalysts which have an acid charge of less than 100 mval/100 g.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: September 23, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Andreas Bomhard, Ulf-Armin Schaper, Theo Stalberg, Thomas Markert
  • Patent number: 5663137
    Abstract: An ultramild surfactant mixture consisting ofa) from about 48 to about 52% by weight of at least one alkyl oligoglucoside corresponding to formula (I):R.sup.1 --O--(G).sub.p (I)in which R.sup.1 is an alkyl radical containing 8 to 10 carbon atoms, G is a glucose unit and p is a number of 1.3 to 1.8; andb) from about 48 to about 52% by weight of at least one alkyl oligoglucoside corresponding to formula (II):R.sup.2 --O--(G).sub.p (II)in which R.sup.2 is an alkyl radical containing 12 to 16 carbon atoms; G is a glucose unit and p is a number of 1.3 to 1.8.Also, finished compositions containing the above surfactant mixture.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: September 2, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Giesen, Wolfgang Pittermann, Karl Schmid, Walter Sterzel
  • Patent number: 5658875
    Abstract: An ultramild surfactant mixture consisting ofa) from about 5 to about 12% by weight of at least one alkyl oligoglucoside corresponding to formula (I):R.sup.1 --O--(G).sub.p (I)in which R.sup.1 is an alkyl radical containing 8 to 10 carbon atoms, G is a glucose unit and p is a number of 1.3 to 1.8; andb) from about 88 to about 95% by weight of at least one alkyl oligoglucoside corresponding to formula (II):R.sup.2 --O--(G).sub.p (II)in which R.sup.2 is an alkyl radical containing 12 to 16 carbon atoms, G is a glucose unit and p is a number of 1.3 to 1.8.Also, finished compositions containing the above surfactant mixture.
    Type: Grant
    Filed: December 14, 1995
    Date of Patent: August 19, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Giesen, Wolfgang Pittermann, Karl Schmid, Walter Sterzel
  • Patent number: 5656200
    Abstract: Foaming emulsions comprising:(A) oily mixture comprising fatty alcohols polyglycol ethers, Guerbet alcohols, and fatty acid esters selected from the group consisting of:(a) a fatty ester of formula III,R.sup.2 CO--OR.sup.3 (III)wherein R.sup.2 CO is an aliphatic acyl radical containing 6 to 22 carbon atoms and 0, 1, 2 or 3 double bonds and R.sup.3 is a linear or branched alkyl radical containing 1 to 4 carbon atoms, and(b) a polyol partial ester of glycerol, oligoglycerol or oligoglycerol polyglycol ether with fatty acids containing 12 to 22 carbon atoms; dialkyl ethers and paraffin hydrocarbons,(B) fatty alcohol sulphates and/or fatty alcohol polyglycol ether sulphates,(C) an anionic polymer,(D) an alkyl oligoglycosides,(E) a cationic surfactant or polymers,(F) an electrolytic salt, and(G) water.These emulsions have a cosmetically elegant appearance and are suitable for example for producing two-in-one shower baths.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: August 12, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Axel Boettcher, Hermann Hensen, Werner Seipel, Holger Tesmann
  • Patent number: 5654453
    Abstract: A process is disclosed for preparing .alpha.-branched aliphatic monocarboxylic acids with 12 to 48 carbon atoms. In a first step of the process (a), .alpha.-branched aliphatic monohydric alcohols (Guerbet alcohols) are converted in the presence of caustic alkali into the alkali salts of the corresponding .alpha.-branched aliphatic monocarboxylic acids. In a second step of the process (b), the .alpha.-branched aliphatic monocarboxylic acids are released from the alkali salts by soap splitting in the presence of an inert diluting agent.
    Type: Grant
    Filed: August 29, 1995
    Date of Patent: August 5, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gerhard Mueller, Bernhard Gutsche, Karl-Heinz Schmid, Frank Bongardt, Lutz Jeromin, Eberhard Peukert, Hermann Frankenbach
  • Patent number: 5648518
    Abstract: The invention relates to a process for the production of (meth)acrylic acid esters of polyhydric alcohols by reaction of the reactants with acrylic acid and/or methacrylic acid in the presence of acidic esterification catalysts with addition of sterically hindered phenolic compounds as polymerization inhibitors. The process is characterized in that tocopherols are used as the sterically hindered phenolic compounds and .alpha.-tocopherol is preferably at least partly used. The process is preferably carried out using reaction mixtures which are liquid at room temperature and which are at least substantially free from solvents and/or azeotropic entraining agents; more particularly, the water of condensation formed is removed from the gas phase of the reaction zone.
    Type: Grant
    Filed: August 23, 1991
    Date of Patent: July 15, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Wolfgang Ritter, Hans-Dieter Sitz, Ludwig Speitkamp
  • Patent number: 5646103
    Abstract: A detergent or cleaning composition containing a copolymeric polycarboxylic acid or salt thereof which is a terpolymer of (a) a monoethylenically unsaturated C.sub.3-8 carboxylic acid, (b) a 2-alkyl or aryl allylsulfonic acid, and (c) a carbohydrate. The invention also relates to builder compositions containing the above terpolymer.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: July 8, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Beatrix Kottwitz, Joerg Poethkow, Peter Krings, Horst Upadek
  • Patent number: 5646306
    Abstract: The practicality of known depolymerization reactions in which there is a danger of building up adherent residues on heat transfer surfaces is greatly improved by performing the process under conditions that provide a driving force which assures that none of the feed material and none of any liquid or solid residue produced during the depolymerization of the feed material remains in contact with any heat transfer surface for a time sufficiently long to form any adherent solid residue on the surface. A preferred apparatus for achieving such a driving force includes a horizontal thin film evaporator, a controlled continuous input of liquid feed material, and continuous collection of desired reaction product and any residue that remains condensed throughout its passage through the reaction zone.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: July 8, 1997
    Assignee: Henkel Corporation
    Inventor: A. Frederick Elsasser, Jr.
  • Patent number: 5646320
    Abstract: Fatty acid esters of isethionate salts are made by reacting ethylene oxide and a bisulfite salt, that may be made in situ, in aqueous ammonia while maintaining (1) the pH in the range of about 5.5 to about 6.5 and (2) the temperature in the range of 25.degree. C. to 85.degree. C. to form an isethionate salt. The isethionate salt is then esterified with a fatty acid to produce a product having little or no unwanted fatty acid esters of ethylene glycol.
    Type: Grant
    Filed: June 16, 1994
    Date of Patent: July 8, 1997
    Assignee: Henkel Corporation
    Inventors: Timothy John Cassady, Norman Milstein, Richard P. Crews