Patents Represented by Attorney, Agent or Law Firm Howard Troffkin
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Patent number: 7754798Abstract: An oxygen scavenger composition includes a block co-polymer having at least one block including a polyester condensation polymer segment having cycloalkenyl group(s) or functionality directly or indirectly bonded to the polymer chain of said block, and having at least one second block including a polymer segment of a thermoplastic, film forming material. The block copolymer has been found to act as an oxygen scavenger agent under both ambient and refrigerated conditions, to be compatible with conventional film forming packaging materials, and to provide compositions exhibiting low tack which can be readily formed and processed using conventional film forming equipment. A packaging material, such as a film or laminated product suitable for packaging applications, can include the oxygen scavenger composition.Type: GrantFiled: August 28, 2003Date of Patent: July 13, 2010Assignee: Cryovac, Inc.Inventors: Cynthia L. Ebner, Arthur L. Berrier
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Patent number: 7452601Abstract: An oxygen scavenger composition includes mer units that have at least one cycloalkenyl group or functionality and, further, has mer units derived from isophthalic acid or terephthalic acid or certain derivatives thereof. The oxygen scavenger composition has been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment. A film and laminated product having said oxygen scavenger composition are also disclosed.Type: GrantFiled: May 30, 2006Date of Patent: November 18, 2008Assignee: Cryovac, Inc.Inventors: Cynthia L. Ebner, Andrew E. Matthews, Terry O. Millwood
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Patent number: 7078100Abstract: An oxygen scavenger composition includes mer units that have at least one cycloalkenyl group or functionality and, further, has mer units derived from isophthalic acid or terephthalic acid or certain derivatives thereof. The oxygen scavenger composition has been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment. A film and laminated product having said oxygen scavenger composition are also disclosed.Type: GrantFiled: August 28, 2003Date of Patent: July 18, 2006Assignee: Cryovac, Inc.Inventors: Cynthia L. Ebner, Andrew E. Matthews, Terry O. Millwood
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Coordination catalyst systems employing chromium support-agglomerate and method of their preparation
Patent number: 6946420Abstract: The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.Type: GrantFiled: April 10, 2002Date of Patent: September 20, 2005Assignee: W. R. Grace & Co.-ConnInventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza -
Patent number: 6872451Abstract: A film, laminated product, and other packaging materials are disclosed, each including an oxygen scavenger composition including mer units derived from a substituted alicyclic compound having non-aromatic, ethylenic functionality, mer units including an ionomeric group, and mer units of a di- or polyfunctional hydrocarbon compound. Certain oxygen scavenger compositions have been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment.Type: GrantFiled: August 28, 2003Date of Patent: March 29, 2005Assignee: Cryovac, Inc.Inventors: Cynthia L. Ebner, Arthur L. Berrier
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Patent number: 6670302Abstract: High melt index polyolefins have been obtained with chromium silica catalysts under conventional polymerization conditions without the use of titanium or other additives. The useful chromium silica catalysts have a pore volume in the range of 1.9-2.9 cc/g and a narrow pore size distribution. The silica is a silica gel preferably obtained from a low solids, rapid gelation process.Type: GrantFiled: October 31, 2002Date of Patent: December 30, 2003Assignee: W. R. Grace & Co.-ConnInventors: Rimantas Glemza, Dean A. Denton
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Patent number: 6562922Abstract: The present invention is directed to vicinal hydroxyl-functionalized hydrocarbon polymers having a mole ratio of methylene to hydroxyl group of greater than 1 and to films, coatings and articles useful in packaging applications containing said polymers.Type: GrantFiled: March 23, 1999Date of Patent: May 13, 2003Assignee: Cryovac, IncInventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, William Peyton Roberts
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Patent number: 6410664Abstract: The present invention is directed to processes of polymerization of olefins and copolymerization of olefins and functionalized olefins in the presence of certain late transition metal bidentate salicylaldimine chelates represented by the formula: wherein each of the symbols R, R1, R2, R3, R4, R5, R6, L, M, A, X and z are defined within the specification herein below.Type: GrantFiled: January 15, 1998Date of Patent: June 25, 2002Assignee: Cryovac, Inc.Inventors: Donald Albert Bansleben, Stefan K. Friedrich, Todd Ross Younkin, Robert Howard Grubbs, Chunming Wang, Robert Tan Li
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Patent number: 6395403Abstract: A novel precious metal doped porous metal catalyst is disclosed. The precious metal is present in from 0.01 to 1.5 weight percent and distributed throughout the particles of porous metal to provide a surface to bulk ratio distribution of not greater than 60. The present invention is further directed to a process of forming said doped catalyst and to improved processes of catalytic hydrogenation of organic compounds.Type: GrantFiled: July 6, 2001Date of Patent: May 28, 2002Assignee: W. R. Grace & Co.Inventor: Stephen Raymond Schmidt
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Patent number: 6313241Abstract: The subject invention is directed to new and novel copolymers having long chain branches formed from ethylene and at least one vinyl alicyclic monomer, to solution polymerization using certain unstrained bridged metallocene catalyst which has been found capable of forming said copolymers and to packaging material formed therefrom.Type: GrantFiled: October 1, 1997Date of Patent: November 6, 2001Assignee: Cryovac, Inc.Inventors: William John Gauthier, Ronald Dean Moffitt, Galen Richard Hatfield
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Patent number: 6284153Abstract: An oxygen scavenging composition composed of a carrier and a metal coated, inert, porous particulate material having the metal substantially in a zero valence state. The composition is contained within the interior cavity of a container to scavenge oxygen therein. The composition may form at least a part of the interior surface of the container or be present therein in the form of a film, mat, sachet or ceramic.Type: GrantFiled: August 19, 1999Date of Patent: September 4, 2001Assignee: W.R. Grace & Co.-ConnInventors: James George Miller, Thomas Andrew Blinka, Drew Ve Speer, William Alfred Feehley, Jr.
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Patent number: 6274210Abstract: An improved oxygen scavenging composition and packaging container formed therefrom is disclosed. The container is suitable for storage of oxygen sensitive materials and has as part of its exposed interior surface a composition composed of a polymeric matrix with a substantially water insoluble oxygen scavenger and a substantially water-insoluble transition metal containing compound distributed therein.Type: GrantFiled: December 3, 1996Date of Patent: August 14, 2001Assignee: W. R. Grace & Co. -ConnInventors: Cynthia Louise Ebner, Thomas Andrew Blinka
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Patent number: 6228284Abstract: An improved oxygen scavenging composition and packaging container formed therefrom is disclosed. The container is suitable for storage of oxygen sensitive materials and has as part of its exposed interior surface a composition composed of a polymeric matrix with a oxygen scavenger and a substantially water-insoluble transition metal containing compound distributed therein.Type: GrantFiled: October 30, 1998Date of Patent: May 8, 2001Assignee: W. R. Grace & Co.-ConnInventors: Cynthia Louise Ebner, Thomas Andrew Blinka
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Patent number: 6203923Abstract: The present invention is directed to Packaging Materials and Packaging Articles having a structure composed of a substantially linear, regio-regular functionalized hydrocarbon polymer having C4-C12 hydrocarbon polymer repeating units wherein each unit has at least one functional group uniformly pendent therefrom.Type: GrantFiled: September 29, 1998Date of Patent: March 20, 2001Assignee: Cryovac, Inc.Inventors: Donald Albert Bansleben, Truc-Chi Huynh-Tran, Rusty Lew Blanski, Paul Anthony Hughes, William Peyton Roberts, Robert Howard Grubbs, Galen Richard Hatfield
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Patent number: 6197714Abstract: Non-ionic bidentate late transition metal chelates tethered to an inert support by a covalent bond group to provide a catalyst useful in slurry and gas phase polymerization of olefins.Type: GrantFiled: March 23, 1999Date of Patent: March 6, 2001Assignee: Cryovac, Inc.Inventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, Jason Ivan Henderson, Andrew Robert Nadjadi, Jr., Todd Ross Younkin
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Patent number: 6197715Abstract: Non-ionic late transition metal chelates of salicylaldimine and pyrrolaldimine can be tethered to an inert support by a covalent bond to provide a catalyst useful in slurry and gas phase polymerization of olefins.Type: GrantFiled: March 23, 1999Date of Patent: March 6, 2001Assignee: Cryovac, Inc.Inventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, Jason Ivan Henderson, Andrew Robert Nadjadi, Jr., Todd Ross Younkin
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Patent number: 6153714Abstract: A new and novel linear, regio-regular vicinal functionalized polymer methods of forming the same are described. The polymer has a linear hydrocarbon polymer backbone with vicinal functional groups having oxygen and/or nitrogen atom containing groups, such as hydroxy, carboxylic acid or ester, carbonyl acetate, amide, nitrile and the like, pendent from the polymer backbone chain in a regio-regular manner.Type: GrantFiled: March 31, 1998Date of Patent: November 28, 2000Assignee: Cryovac, Inc.Inventors: Donald Albert Bansleben, Truc-Chi Thi Huynh-Tran, Rusty Lew Blanski, Paul Anthony Hughes, William Peyton Roberts, Robert Howard Grubbs, Galen Richard Hatfield
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Patent number: 5633298Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.Type: GrantFiled: June 6, 1995Date of Patent: May 27, 1997Assignee: W. R. Grace & Co.-Conn.Inventors: Ahmad Arfaei, David C. Darwin, Ellis M. Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence L. Kuo
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Patent number: 5603760Abstract: A cement admixture composition composed of at least one oxyalkylene compound and an ammonium salt of tall oil fatty acid.Type: GrantFiled: September 18, 1995Date of Patent: February 18, 1997Assignee: W. R. Grace & Co.-Conn.Inventors: Neal S. Berke, Michael P. Dallaire, Angel Abelleira
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Patent number: 5351414Abstract: A device suitable to accurately determine water depth. The device comprises a rod having a weighted first end, a fixed float and a movable float.Type: GrantFiled: September 30, 1992Date of Patent: October 4, 1994Inventor: Joseph A. Cogliano