Patents Represented by Attorney, Agent or Law Firm Howard Troffkin
  • Patent number: 7754798
    Abstract: An oxygen scavenger composition includes a block co-polymer having at least one block including a polyester condensation polymer segment having cycloalkenyl group(s) or functionality directly or indirectly bonded to the polymer chain of said block, and having at least one second block including a polymer segment of a thermoplastic, film forming material. The block copolymer has been found to act as an oxygen scavenger agent under both ambient and refrigerated conditions, to be compatible with conventional film forming packaging materials, and to provide compositions exhibiting low tack which can be readily formed and processed using conventional film forming equipment. A packaging material, such as a film or laminated product suitable for packaging applications, can include the oxygen scavenger composition.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: July 13, 2010
    Assignee: Cryovac, Inc.
    Inventors: Cynthia L. Ebner, Arthur L. Berrier
  • Patent number: 7452601
    Abstract: An oxygen scavenger composition includes mer units that have at least one cycloalkenyl group or functionality and, further, has mer units derived from isophthalic acid or terephthalic acid or certain derivatives thereof. The oxygen scavenger composition has been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment. A film and laminated product having said oxygen scavenger composition are also disclosed.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: November 18, 2008
    Assignee: Cryovac, Inc.
    Inventors: Cynthia L. Ebner, Andrew E. Matthews, Terry O. Millwood
  • Patent number: 7078100
    Abstract: An oxygen scavenger composition includes mer units that have at least one cycloalkenyl group or functionality and, further, has mer units derived from isophthalic acid or terephthalic acid or certain derivatives thereof. The oxygen scavenger composition has been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment. A film and laminated product having said oxygen scavenger composition are also disclosed.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: July 18, 2006
    Assignee: Cryovac, Inc.
    Inventors: Cynthia L. Ebner, Andrew E. Matthews, Terry O. Millwood
  • Patent number: 6946420
    Abstract: The present invention is directed to a coordinating catalyst system comprising at least one pre-catalyst selected from late transition metal bidentate or tridentate ligand containing compounds, at least one support-agglomerate having chromium immobilized thereto (e.g., spray dried silica/clay agglomerate), and optionally at least one organometallic compound in controlled amounts, and methods for preparing the same. The resulting catalyst system exhibits enhanced activity for polymerizing olefins and yields polymer products having very good morphology.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: September 20, 2005
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Keng-Yu Shih, Dean Alexander Denton, Rimantas Glemza
  • Patent number: 6872451
    Abstract: A film, laminated product, and other packaging materials are disclosed, each including an oxygen scavenger composition including mer units derived from a substituted alicyclic compound having non-aromatic, ethylenic functionality, mer units including an ionomeric group, and mer units of a di- or polyfunctional hydrocarbon compound. Certain oxygen scavenger compositions have been found to act as an oxygen scavenger under both ambient and refrigeration conditions, to be compatible with conventional film forming packaging materials, to inhibit undesirable oligomer formation and oxidation by-product formation, and to be readily formable and processable using conventional film forming equipment.
    Type: Grant
    Filed: August 28, 2003
    Date of Patent: March 29, 2005
    Assignee: Cryovac, Inc.
    Inventors: Cynthia L. Ebner, Arthur L. Berrier
  • Patent number: 6670302
    Abstract: High melt index polyolefins have been obtained with chromium silica catalysts under conventional polymerization conditions without the use of titanium or other additives. The useful chromium silica catalysts have a pore volume in the range of 1.9-2.9 cc/g and a narrow pore size distribution. The silica is a silica gel preferably obtained from a low solids, rapid gelation process.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: December 30, 2003
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Rimantas Glemza, Dean A. Denton
  • Patent number: 6562922
    Abstract: The present invention is directed to vicinal hydroxyl-functionalized hydrocarbon polymers having a mole ratio of methylene to hydroxyl group of greater than 1 and to films, coatings and articles useful in packaging applications containing said polymers.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: May 13, 2003
    Assignee: Cryovac, Inc
    Inventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, William Peyton Roberts
  • Patent number: 6410664
    Abstract: The present invention is directed to processes of polymerization of olefins and copolymerization of olefins and functionalized olefins in the presence of certain late transition metal bidentate salicylaldimine chelates represented by the formula: wherein each of the symbols R, R1, R2, R3, R4, R5, R6, L, M, A, X and z are defined within the specification herein below.
    Type: Grant
    Filed: January 15, 1998
    Date of Patent: June 25, 2002
    Assignee: Cryovac, Inc.
    Inventors: Donald Albert Bansleben, Stefan K. Friedrich, Todd Ross Younkin, Robert Howard Grubbs, Chunming Wang, Robert Tan Li
  • Patent number: 6395403
    Abstract: A novel precious metal doped porous metal catalyst is disclosed. The precious metal is present in from 0.01 to 1.5 weight percent and distributed throughout the particles of porous metal to provide a surface to bulk ratio distribution of not greater than 60. The present invention is further directed to a process of forming said doped catalyst and to improved processes of catalytic hydrogenation of organic compounds.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: May 28, 2002
    Assignee: W. R. Grace & Co.
    Inventor: Stephen Raymond Schmidt
  • Patent number: 6313241
    Abstract: The subject invention is directed to new and novel copolymers having long chain branches formed from ethylene and at least one vinyl alicyclic monomer, to solution polymerization using certain unstrained bridged metallocene catalyst which has been found capable of forming said copolymers and to packaging material formed therefrom.
    Type: Grant
    Filed: October 1, 1997
    Date of Patent: November 6, 2001
    Assignee: Cryovac, Inc.
    Inventors: William John Gauthier, Ronald Dean Moffitt, Galen Richard Hatfield
  • Patent number: 6284153
    Abstract: An oxygen scavenging composition composed of a carrier and a metal coated, inert, porous particulate material having the metal substantially in a zero valence state. The composition is contained within the interior cavity of a container to scavenge oxygen therein. The composition may form at least a part of the interior surface of the container or be present therein in the form of a film, mat, sachet or ceramic.
    Type: Grant
    Filed: August 19, 1999
    Date of Patent: September 4, 2001
    Assignee: W.R. Grace & Co.-Conn
    Inventors: James George Miller, Thomas Andrew Blinka, Drew Ve Speer, William Alfred Feehley, Jr.
  • Patent number: 6274210
    Abstract: An improved oxygen scavenging composition and packaging container formed therefrom is disclosed. The container is suitable for storage of oxygen sensitive materials and has as part of its exposed interior surface a composition composed of a polymeric matrix with a substantially water insoluble oxygen scavenger and a substantially water-insoluble transition metal containing compound distributed therein.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: August 14, 2001
    Assignee: W. R. Grace & Co. -Conn
    Inventors: Cynthia Louise Ebner, Thomas Andrew Blinka
  • Patent number: 6228284
    Abstract: An improved oxygen scavenging composition and packaging container formed therefrom is disclosed. The container is suitable for storage of oxygen sensitive materials and has as part of its exposed interior surface a composition composed of a polymeric matrix with a oxygen scavenger and a substantially water-insoluble transition metal containing compound distributed therein.
    Type: Grant
    Filed: October 30, 1998
    Date of Patent: May 8, 2001
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Cynthia Louise Ebner, Thomas Andrew Blinka
  • Patent number: 6203923
    Abstract: The present invention is directed to Packaging Materials and Packaging Articles having a structure composed of a substantially linear, regio-regular functionalized hydrocarbon polymer having C4-C12 hydrocarbon polymer repeating units wherein each unit has at least one functional group uniformly pendent therefrom.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: March 20, 2001
    Assignee: Cryovac, Inc.
    Inventors: Donald Albert Bansleben, Truc-Chi Huynh-Tran, Rusty Lew Blanski, Paul Anthony Hughes, William Peyton Roberts, Robert Howard Grubbs, Galen Richard Hatfield
  • Patent number: 6197714
    Abstract: Non-ionic bidentate late transition metal chelates tethered to an inert support by a covalent bond group to provide a catalyst useful in slurry and gas phase polymerization of olefins.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: March 6, 2001
    Assignee: Cryovac, Inc.
    Inventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, Jason Ivan Henderson, Andrew Robert Nadjadi, Jr., Todd Ross Younkin
  • Patent number: 6197715
    Abstract: Non-ionic late transition metal chelates of salicylaldimine and pyrrolaldimine can be tethered to an inert support by a covalent bond to provide a catalyst useful in slurry and gas phase polymerization of olefins.
    Type: Grant
    Filed: March 23, 1999
    Date of Patent: March 6, 2001
    Assignee: Cryovac, Inc.
    Inventors: Donald Albert Bansleben, Eric Francis Connor, Robert Howard Grubbs, Jason Ivan Henderson, Andrew Robert Nadjadi, Jr., Todd Ross Younkin
  • Patent number: 6153714
    Abstract: A new and novel linear, regio-regular vicinal functionalized polymer methods of forming the same are described. The polymer has a linear hydrocarbon polymer backbone with vicinal functional groups having oxygen and/or nitrogen atom containing groups, such as hydroxy, carboxylic acid or ester, carbonyl acetate, amide, nitrile and the like, pendent from the polymer backbone chain in a regio-regular manner.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: November 28, 2000
    Assignee: Cryovac, Inc.
    Inventors: Donald Albert Bansleben, Truc-Chi Thi Huynh-Tran, Rusty Lew Blanski, Paul Anthony Hughes, William Peyton Roberts, Robert Howard Grubbs, Galen Richard Hatfield
  • Patent number: 5633298
    Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: May 27, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Ahmad Arfaei, David C. Darwin, Ellis M. Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence L. Kuo
  • Patent number: 5603760
    Abstract: A cement admixture composition composed of at least one oxyalkylene compound and an ammonium salt of tall oil fatty acid.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: February 18, 1997
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Neal S. Berke, Michael P. Dallaire, Angel Abelleira
  • Patent number: 5351414
    Abstract: A device suitable to accurately determine water depth. The device comprises a rod having a weighted first end, a fixed float and a movable float.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: October 4, 1994
    Inventor: Joseph A. Cogliano