Patents Represented by Attorney Hugh C. Crall
  • Patent number: 5693103
    Abstract: A single bath process for exhaust dyeing polyester and cotton fiber blends by the use of a fiber reactive, vinyl sulfone dye in admixture with a disperse dye under alkaline pH conditions.
    Type: Grant
    Filed: January 24, 1997
    Date of Patent: December 2, 1997
    Assignee: Dystar, L.P.
    Inventors: Thomas Van Chambers, Christine Feuchtner
  • Patent number: 5597873
    Abstract: A surface crosslinked superabsorbent polymer composition, a process for its preparation and articles made therefrom wherein said superabsorbent composition is prepared by surface crosslinking the polymerization product of a carboxyl or carboxylate group containing monomer with a crosslinker solution comprising water, C.sub.3 -C.sub.6 diol and a crosslinking compound having at least two functional reactive groups with the carboxyl or carboxylate groups of said polymerization product.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: January 28, 1997
    Assignee: Hoechst Celanese Corporation
    Inventors: Douglas R. Chambers, William G-J Chiang, Guy T. Woodrum
  • Patent number: 5563248
    Abstract: The invention is a dye composition containing two or more dyes of the vinyl sulfone type which can be used in combination to dye polyamide substrates. Preferably the dye compositions of the invention contain at least three dyes of different primary colors.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 8, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: Walter Helmling, Philomen DeCroos
  • Patent number: 5539109
    Abstract: The invention is that of a new triphenodioxazine dye of the formula: ##STR1## wherein: ##STR2## K is independently selected from SO.sub.3 H and COOH; W=a substituted or unsubstituted arylene, alkylene or arylene-alkylene group;Y.sup.1 =Vinyl, .beta.-Sulfatoethyl, .beta.-Thiosulfatoethyl, .beta.-Halogenethyl-group, .beta.-Phosphatoethyl, andX=H.R, R.sub.1 and R.sub.2 are independently selected from hydrogen and substituted or unsubstituted alkyl.T is independently selected from hydrogen, Cl, Br, C.sub.1 to C.sub.6 alkyl, C.sub.1 to C.sub.6 alkoxy, phenyl or phenoxy; andn is selected from 0, 1 or 2.
    Type: Grant
    Filed: July 11, 1995
    Date of Patent: July 23, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: Walter Helmling, Uwe Reiher
  • Patent number: 5532362
    Abstract: The present invention is directed to a dioxazine dye which provides brilliant reddish blue dyeings possessing superior fastness properties and high tinctorial strength.
    Type: Grant
    Filed: May 25, 1995
    Date of Patent: July 2, 1996
    Assignee: Hoechst Celanese Corporation
    Inventors: Walter Helmling, David Brunetti, Uwe Reiher
  • Patent number: 5488111
    Abstract: This invention relates to a compound of the formula: ##STR1##
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: January 30, 1996
    Assignee: Hoechst Celanese Corporation
    Inventor: John C. Saukaitis
  • Patent number: 5484455
    Abstract: A process for dyeing cationic polyamide with a vinyl sulfone dye wherein said vinyl sulfone dyed polyamide is color stable. The vinyl sulfone dyed cationic polyamide may be overdyed with acid without staining the dyed cationic nylon.
    Type: Grant
    Filed: May 26, 1994
    Date of Patent: January 16, 1996
    Assignee: Hoechst Celanese Corporation
    Inventor: Larry C. Kelley
  • Patent number: 5484459
    Abstract: This invention is directed to a dioxazine fiber reactive dye composition which provides brilliant blue shades comparable to those obtained with dyes of the anthraquinone series.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: January 16, 1996
    Assignee: Hoechst Celanese Corporation
    Inventor: Walter Helmling
  • Patent number: 5478894
    Abstract: This invention is directed to a recurring polymeric moiety of the following formula: ##STR1## wherein R is independently selected from hydrogen and C.sub.1 to C.sub.4 alkyl; Y is independently selected from O and NH; and X is independently selected from Cl, F, Br, I, NO.sub.3, HSO.sub.4 and H.sub.2 PO.sub.4.Polymers of the above structure may be crosslinked by treating the polymer with a base and heating it.
    Type: Grant
    Filed: July 2, 1993
    Date of Patent: December 26, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: William G. Chiang, Joy L. McCrickard
  • Patent number: 5466808
    Abstract: This invention is a process for preparing 8-sulfo-7-chloro-6-fluoro-4-oxo-1,4-dihydro-3-quinolinic acid wherein the amino analinomethylenomalonate starting material of Formula 1 is unsubstituted at the R.sub.1 and R.sub.2 positions i.e. these moieties are hydrogen. In the ring closing process when R.sub.1 and R.sub.2 are hydrogen, not only does the ring close but the ring position at R.sub.2 is sulfonated.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: November 14, 1995
    Assignee: Hoechst Celanese Corporation
    Inventor: John C. Saukaitis
  • Patent number: 5463033
    Abstract: A monoazo fiber reactive dye of the formula: ##STR1## wherein X and Y are independently selected from .beta.-sulfatoethyl, .beta.-thiosulfatoethyl and .beta.-phosphatoethyl group and R is hydrogen, and C.sub.1 -C.sub.4 alkyl; preferably methyl. These dyes are useful in conducting exhaust dyeings at low dye bath salt concentrations.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: October 31, 1995
    Assignee: Hoechst Celanase Corporation
    Inventors: John W. Donovan, Frank P. Lavieri
  • Patent number: 5456727
    Abstract: The invention is a dye composition containing two or more dyes of the vinyl sulfone type which can be used in combination to dye polyamide substrates. Preferably the dye compositions of the invention contain at least three dyes of different primary colors.
    Type: Grant
    Filed: May 24, 1994
    Date of Patent: October 10, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Walter Heimling, Mark Helle, Kerry Proulx, Leslie McIntosh, Philomen DeCroos
  • Patent number: 5453323
    Abstract: Super-absorbent polymers having superior dryness properties when incorporated into absorbent articles are made from acrylic acid and crosslinking agent polymerized under controlled conditions.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: September 26, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Douglas R. Chambers, Hubert H. Fowler, Jr., Yoji Fujiura, Fusayoshi Masuda
  • Patent number: 5430152
    Abstract: A method of preparing substituted and unsubstituted 1,4-dihydro-4-oxo-2 and -3 quinolinic carboxylic acids which comprises heating an ester selected from the group consisting of substituted and unsubstituted anilinomethylenemalonates, anilinofumurates, anilinomaleates and mixutres thereof in the presence of chlorosulfonic acid, oleum and mixtures thereof.
    Type: Grant
    Filed: January 13, 1994
    Date of Patent: July 4, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: John C. Saukaitis, Franklin B. Gupton
  • Patent number: 5409916
    Abstract: Fiber reactive dyes of the anthraquinone type which provide brilliant violet colors without metal complexing. These dyes may be represented by the formula: ##STR1## wherein W is selected from NR.sub.2 and oxygen;R is independently selected from hydrogen, C.sub.1 -C.sub.6 alkyl;C.sub.1 -C.sub.6 alkoxy, sulfo and carboxy;R.sub.1 is selected from hydrogen, C.sub.1 -C.sub.6 alkyl and phenyl;R.sub.2 is selected from hydrogen and C.sub.1 -C.sub.6 alkyl;R.sub.3 is selected from hydrogen, and C.sub.1 -C.sub.4 alkyl;n is an integer of 1 or 2; andY is CH.dbd.CH.sub.2, or CH.sub.2 CH.sub.2 Z wherein Z is a group capable of being split off by the action of an alkali reagent.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: April 25, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald P. Pedemonte, Thomas S. Phillips
  • Patent number: 5405987
    Abstract: The present invention pertains to a method of preparing substituted and unsubstituted N-hydroxy-2-aminobutane diacid derivatives which can be dehydrated to 2-aminobut-2-ene dioic acid derivatives, which can be subsequently converted to pyridine and quinoline derivatives.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: April 11, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Varadaraj Elango, Donald R. Larkin, John R. Fritch, Michael P. Bodman, Werner H. Mueller, Bernard F. Gupton, John C. Saukaitis
  • Patent number: 5393884
    Abstract: The invention is that of a water soluble fiber reactive anthraquinone blue dyes. These dyes may be used to dye and print textiles and other substrates containing hydroxy and or groups in brilliant blue colors. The dyes of the invention are free of heavy metals.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: February 28, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Ronald P. Pedemonte, Walter Helmling
  • Patent number: 5350838
    Abstract: A process for preparing monoazo dyes by coupling a aromatic diazonium salt with an amino-4-hydroxy-naphthalene sulfonic acid derivative at a temperature of 40.degree.-85.degree. C. The process of the invention provides a isomerically purer dye.
    Type: Grant
    Filed: February 8, 1993
    Date of Patent: September 27, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Mark A. Helle, Walter Helmling
  • Patent number: 5350799
    Abstract: This invention is a method for converting fine particles of superabsorbent polymers into larger particles. The invention is primarily directed to aqueous solution processes for preparing superabsorbent polymers. In such aqueous solution polymerization methods, the polymerization reaction product is a high viscosity gel which is dried and ground into particles. In this grinding step, a portion of the product is produced as undesired fine particles having poor absorbency and poor fabrication properties; i.e. they "gel block" and dust. According to the invention, fine superabsorbent polymer particles (up to about 3 parts) are mixed with the high viscosity reaction product gel (100 parts) containing about 20 parts by weight of superabsorbent polymer and water (5 parts per part of recycled particles) to form a mixture with improved rheological properties.
    Type: Grant
    Filed: May 7, 1991
    Date of Patent: September 27, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Guy T. Woodrum, Thomas H. Majette
  • Patent number: 5330539
    Abstract: A method for the exhaust dyeing of materials having hydroxy groups and materials containing carbonamide groups using a low salt content dye bath in conjunction with fiber reactive dyes exemplified by a dye of the following formula: ##STR1##
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: July 19, 1994
    Assignee: Hoechst Celanese Corporation
    Inventors: Thomas S. Phillips, Kevin D. Costa, Werner Russ, Thomas V. Chambers