Patents Represented by Attorney I. A. Murphy
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Patent number: 7041244Abstract: A process for producing tablets comprising one or more active substances, in which pulverulent to granular starting components are shaped and then solidified, wherein the solidification takes place by reacting a component A and a component B with one another, components A and B being mixed with the starting components, applied to them or added after shaping.Type: GrantFiled: February 23, 2001Date of Patent: May 9, 2006Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventor: Peter Schmiedel
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Patent number: 4431768Abstract: Aqueous acidic compositions which contain a combination of an organic polymer having a bound latent source of thiolate ions, such as isothiouronium groups and an organic polymer having bound cationic onium groups, such as sulfonium groups, or a polymer containing both kinds of groups can be cured in the wet state by raising the pH to above about 9 at a temperature from about 0.degree. C. to about 100.degree. C.Type: GrantFiled: May 4, 1982Date of Patent: February 14, 1984Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Thomas C. Klingler
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Patent number: 4383073Abstract: Water-compatible compositions are described which consist essentially of at least one resinous compound whose backbone is linear or substantially linear and consists essentially of at least one oxyaryleneoxyalkylene or oxyaryleneoxy(1,3-(2-hydroxy)alkylene) unit and which bears at least two functional organic moieties through which cross-linking can occur (preferably groups having active hydrogen, more preferably aliphatic hydroxyl groups) and at least one terminal carbamoylpyridinium group covalently bonded through the ring nitrogen atom combined with an acid curable cross-linking agent. The compositions are useful coating compositions which find particular utility in cathodic electrodeposition. The compounds are prepared, for example, by reacting a linear or substantially linear epoxy resin with a carbamoylpyridine in the presence of sufficient amount of a Bronsted acid and water to stabilize the carbamoylpyridinium salt thus formed.Type: GrantFiled: August 20, 1981Date of Patent: May 10, 1983Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Larry D. Yats, William O. Perry
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Patent number: 4337185Abstract: Structured particle latexes are prepared by emulsion polymerizing monomeric materials in aqueous media in one or more stages wherein in at least one of the stages a reactive polymeric surfactant is used. The resulting latex contains nonionic particles to which are bound the reactive polymeric surfactant which forms a layer containing stabilizing "ionic" groups such as sulfonium groups, quaternary ammonium groups or sulfonate groups chemically bound at or near the surface of the polymer particles, which are dispersed in aqueous media. The cationic latexes are particularly suitable for beater additives and organic pigments.Type: GrantFiled: June 23, 1980Date of Patent: June 29, 1982Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Dale M. Pickelman, Sr.
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Patent number: 4225406Abstract: A method for electrodeposition of an organic material on an electroconductive surface comprising placing the electroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, film-forming, organic polymer as cation-active particles wherein the cation-activity is provided at least predominantly by sulfonium cations and passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current both electrodes become coated with the polymer.Type: GrantFiled: June 16, 1975Date of Patent: September 30, 1980Assignee: The Dow Chemical CompanyInventors: Earl H. Wagener, Ritchie A. Wessling, Dale S. Gibbs
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Patent number: 4225383Abstract: A sheet which is a composite of (A) from about 1 percent to about 30 percent of a water-dispersible fiber such as wood fiber, (B) from about 2 percent to about 30 percent of a film-forming, water-insoluble, organic polymer such as a copolymer of styrene and butadiene and (C) from about 60 percent to about 95 percent of a finely-divided, substantially water-insoluble, non-fibrous, inorganic filler such as magnesium hydroxide is prepared by steps comprising:(I) providing an aqueous dispersion of the fiber;(II) mixing therewith (A) the inorganic filler and (B) the organic polymer in the form of an ionically stabilized latex;(III) colloidally destabilizing the resulting mixture to form a fibrous agglomerate in aqueous suspension;(IV) distributing and draining the aqueous dispersion on a porous substrate such as a wire to form a wet web; and(V) drying the web.Type: GrantFiled: December 14, 1978Date of Patent: September 30, 1980Assignee: The Dow Chemical CompanyInventor: Kent B. McReynolds
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Patent number: 4225407Abstract: A method for electrodeposition of an organic material on an electroconductive surface comprising placing the electroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically nonconductive, film-forming, organic polymer as cation-active particles wherein the cation-activity is provided at least predominantly by reducible nitrogen-containing cations and passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current, both electrodes become coated with an adherent coating of polymer.Type: GrantFiled: April 4, 1979Date of Patent: September 30, 1980Assignee: The Dow Chemical CompanyInventors: Earl H. Wagener, Ritchie A. Wessling, Dale S. Gibbs
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Patent number: 4189345Abstract: A fibrous product containing (a) a papermaking grade of pulp, (b) a structured particle latex having pH independent cationic groups bound at or near the particle surface and (c) a co-additive. The pulp is represented by unbleached softwood kraft. The latex is represented by a structured-particle latex having (a) a core of a copolymer of styrene and butadiene (b) an encapsulating layer of styrene, butadiene and vinylbenzyl chloride which is reacted with 2-(dimethylamino) ethanol to form quaternary ammonium groups. The co-additive is represented by a hydrolyzed polyacrylamide having a degree of polymerization of 5500. To an aqueous slurry of the pulp are added the latex and an aqueous solution of the co-additive, the resulting suspension is dewatered and dried by heating.Type: GrantFiled: August 17, 1977Date of Patent: February 19, 1980Assignee: The Dow Chemical CompanyInventors: William A. Foster, Dale M. Pickelman, Ritchie A. Wessling
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Patent number: 4187142Abstract: A process for preparing a high strength composite by (A) mixing (1) an aqueous slurry of negatively charged, water-insoluble natural or synthetic fiber such as cellulose fiber, (2) a latex having a high density of pH independent cationic charges, such as sulfonium, bound at or near the particle surface, (3) a water-soluble, high molecular weight anionic polymer co-additive, such as a hydrolyzed polyacrylamide and optionally (4) conventional wet end additives; (B) draining water from the resulting aqueous suspension; (C) drying by heating.Type: GrantFiled: August 17, 1977Date of Patent: February 5, 1980Assignee: The Dow Chemical CompanyInventors: Dale M. Pickelman, William A. Foster, Ritchie A. Wessling
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Patent number: 4178205Abstract: A high strength, non-woven fibrous material is prepared by (a) mixing an aqueous slurry of a negatively charged, water-insoluble natural or synthetic fiber or blend of fibers with an amount up to the fiber charge reversal point of a structured particle latex having pH independent cationic charges bound at or near the particle surface to form an aqueous suspension, (b) draining water from the aqueous suspension to form a wet web (c) wet pressing the web and (d) drying the web by heating.Type: GrantFiled: August 17, 1977Date of Patent: December 11, 1979Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, William A. Foster, Dale M. Pickelman
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Patent number: 4061833Abstract: An aqueous latex coating composition comprising a non-conductive, water-insoluble copolymer of (1) methacrylic acid or maleic acid, (2) a styrene compound, and (3) a conjugated diene hydrocarbon or an alkyl ester of methacrylic acid or of acrylic acid is coated onto a sheet which is conductive or is non-conductive but may have a conductive layer adhered thereto. Thereby, sheets having a dielectric coating for electrographic printing are produced.Type: GrantFiled: January 6, 1976Date of Patent: December 6, 1977Assignee: The Dow Chemical CompanyInventors: Ronald R. Pelletier, Robert D. Hansen, James J. Vanderbush
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Patent number: 4056501Abstract: Structured-particle latexes are prepared from nonionic or slightly cationic latexes, either preformed or polymerized in situ, by emulsion polymerizing monomeric materials which include an ethylenically unsaturated, activated-halogen monomer such as vinylbenzyl chloride in the absence of a sufficient amount of a surfactant to initiate new particles whereby the activated-halogen monomer is copolymerized on the surface of the existing particles which are dispersed in an aqueous media. The resulting structured-particle latex may then be reacted with a nucleophile such as dimethyl sulfide or trimethyl amine to form a latex having stabilizing "onium" groups such as sulfonium groups or quaternary ammonium groups chemically bound at or near the surface of the polymer particles which are dispersed in aqueous media. The cationic latexes are suitable for coatings and organic pigments.Type: GrantFiled: April 21, 1975Date of Patent: November 1, 1977Assignee: The Dow Chemical CompanyInventors: Dale S. Gibbs, Earl H. Wagener, Ritchie A. Wessling
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Patent number: 4018699Abstract: Surfactant compositions include a mixture of a mono-butyl ether of ethylene glycol and a sodium, potassium or magnesium salt of laurylsulfate or mixtures of such salts.Type: GrantFiled: September 29, 1975Date of Patent: April 19, 1977Assignee: The Dow Chemical CompanyInventor: Lowell B. Lindy
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Patent number: 4017442Abstract: Structured-particle latexes are prepared from nonionic or slightly cationic latexes, either preformed or polymerized in situ, by emulsion polymerizing monomeric materials which include an ethylenically unsaturated, activated-halogen monomer such as vinylbenzyl chloride in the absence of a sufficient amount of a surfactant to initiate new particles whereby the activated-halogen monomer is copolymerized on the surface of the existing particles which are dispersed in aqueous media. To the resulting structured particle latex may then be added conventional cationic surfactants to provide greater stability. The cationic latexes are suitable for coatings.Type: GrantFiled: April 21, 1975Date of Patent: April 12, 1977Assignee: The Dow Chemical CompanyInventors: Dale S. Gibbs, Earl H. Wagener, Ritchie A. Wessling
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Patent number: 4017372Abstract: A method for electrodeposition of an adherent, water-resistant, cross-linked, organic coating on an electroconductive surface comprising (a) placing the elecroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, film-forming, organic polymer as cation-active, structured particles wherein a substantial portion of the cation-activity is provided by pH independent cationic groups which are chemically bound to the polymer at or near the particle surface and (b) passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current both electrodes become coated with an adherent coating of polymer.Type: GrantFiled: April 21, 1975Date of Patent: April 12, 1977Assignee: The Dow Chemical CompanyInventors: Earl H. Wagener, Ritchie A. Wessling, Dale S. Gibbs
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Patent number: 4002586Abstract: Modified cationic latexes are prepared from nonionic or cationic latexes having particles containing chemically bound epoxide groups at or near the particle surface by reacting the latex with a nucleophile such as dimethyl sulfide and an acid such as acetic acid to form a latex having stabilizing onium ions chemically bound to the particle at or near the particle surface.Type: GrantFiled: April 21, 1975Date of Patent: January 11, 1977Assignee: The Dow Chemical CompanyInventors: Ritchie A. Wessling, Thomas C. Klingler, Victor E. Meyer
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Patent number: 3998776Abstract: An aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, organic polymer as cation-active particles wherein a substantial portion of the cation-activity is provided by isothiouronium cations may be obtained by various methods including emulsion polymerization of hydrophobic monomers using an isothiouronium surfactant or by emulsion copolymerization of a monomer containing isothiouronium groups with hydrophobic monomers.Type: GrantFiled: April 10, 1975Date of Patent: December 21, 1976Assignee: The Dow Chemical CompanyInventors: Earl H. Wagener, Ritchie A. Wessling, Dale S. Gibbs
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Patent number: 3994792Abstract: A method for electrodeposition of an organic material on an electroconductive surface comprising placing the electroconductive surface to be coated in contact with an aqueous dispersion containing a water-insoluble, essentially electrically non-conductive, film-forming, organic polymer as cation-active particles wherein a substantial portion of the cation-activity is provided by sulfoxonium cations and passing an electric current from an electrode through the latex to the electroconductive surface in such a direction that the electroconductive surface is negatively charged, i.e., becomes a cathode in an electrophoretic cell. By use of alternating current both electrodes become coated with an adherent coating of polymer.Type: GrantFiled: March 3, 1975Date of Patent: November 30, 1976Assignee: The Dow Chemical CompanyInventors: Earl H. Wagener, Dale S. Gibbs, Ritchie A. Wessling