Abstract: Hydrocarbyl substituted C.sub.4 to C.sub.10 monounsaturated dicarboxylic acid, anhydrides or esters, e.g. polyisobutenyl succinic anhydride, preferably made by reacting polymer of C.sub.2 to C.sub.10 monoolefin, preferably polyisobutylene, having a number arrange molecular weight of about 700 to 1200, preferably with a C.sub.4 to C.sub.10 monounsaturated acid, anhydride or ester, preferably maleic anhydride, such that there are 1.2 to 2.0 dicarboxylic acid producing moieties per molecule of said olefin polymer used in the reaction mixture. The resulting materials may be further reacted with amines, alcohols, amino alcohols, boric acid, etc. to form dispersants.
Abstract: The present invention is directed to oil-soluble lubricating oil viscosity index improver/dispersant additives comprising Mannich Base condensates of a grafted ethylene copolymer, an optionally alkyl-substituted N-hydroxyaryl compound, an aldehyde, and a monosecondary amine, whereby oil solutions, particularly oil concentrates, of said additives which are characterized by minimal viscosity change over an extended period of time. These additives comprise a copolymer of ethylene with one or more C.sub.3 to C.sub.28 alpha-olefins, preferably propylene, which have been grafted with acid moieties, e.g. maleic anhydride, preferably using a free radical initiator in a solvent such as a lubricating oil, which is then either (a) reacted with an N-hydroxyaryl amine and then condensed with an aldehyde and a monosecondary amine to form the Mannich Base viscosity index improver/dispersant material, or (b) reacted with a preformed Mannich Base condensate of an N-hydroxyaryl amine, aldehyde and the monosecondary amine.
Type:
Grant
Filed:
August 1, 1988
Date of Patent:
June 15, 1993
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Antonio Gutierrez, Robert A. Kleist, Ricardo Bloch
Abstract: Polymers of olefin monomers and a substantially uniform concentration of carboxyl, hydroxyl, thio, amino, cabonyl and imino functional group-containing monomers. Polymers of olefin monomers and carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers substantially devoid of halogen. Method for preparing polymers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds to form masked, functional group-containing monomers and polymerizing polymer chain monomers with the masked, functional group-containing monomers to produce a polymer chain. Method for forming masked, functional group-containing monomers by reacting carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers with non-halogenated organometallic compounds. Masked, carboxyl, hydroxyl, thio, amino, carbonyl and imino functional group-containing monomers.
Abstract: A method for promoting the hydrogenation of phenol to cyclohexanone in the presence of a non-promoted palladium catalyst which comprises effecting the hydrogenation reaction in the presence of an in situ promoter selected from the group consisting of alkalie metal and alkaline earth metal chlorides, fluorides, bicarbonates, carbonates, hydroxides and nitrates, ammonia, ammonium hydroxide, secondary amines and mixtures thereof.