Patents Represented by Attorney J. H. Beusen
  • Patent number: 4615840
    Abstract: Aqueous solutions of aminomethylenephosphonic acid selected from diethylenetriaminepenta(methylenephosphonic acid), diethylenetriaminetetra(methylenephosphonic acid), diethylenetriaminetri(methylenephosphonic acid) and mixtures thereof are stabilized against crystallization of said aminomethylenephosphonic acid by including non-oxidizing mineral acid in such solutions in an amount stoichiometrically equivalent to at least 10% hydrochloric acid by weight of the solution.
    Type: Grant
    Filed: October 11, 1984
    Date of Patent: October 7, 1986
    Assignee: Monsanto Europe S.A.
    Inventors: Michel A. O. Ledent, Bronislav H. May
  • Patent number: 4515731
    Abstract: Catalytic asymmetric hydrogenation of the Z geometric isomer of a compound of the formula ##STR1## wherein at least one of R and R.sup.1 represents hydrogen and the other represents hydrogen, lower alkyl or aryl; R.sup.2 represents ##STR2## wherein R.sup.4 and R.sup.5 each independently represent hydrogen, lower alkyl or aryl, R.sup.6 represents hydrogen, lower alkyl, aryl or an alkali metal; and R.sup.3 represents ##STR3## wherein R.sup.7 and R.sup.8 each independently represent lower alkyl or aryl; provided that, when R.sup.3 is ##STR4## R.sup.2 is --CN, in the presence of a homogeneous, coordination complex catalyst comprising rhodium, iridium or ruthenium in combination with an optically active bis phosphine ligand provides an outstanding level of optical purity.
    Type: Grant
    Filed: July 8, 1983
    Date of Patent: May 7, 1985
    Assignee: Monsanto Company
    Inventors: Gerald L. Bachman, Billy D. Vineyard
  • Patent number: 4490528
    Abstract: A process for producing chloro-s-triazine trione with improved crystal properties comprising reacting cyanuric acid, alkali metal hydroxide, and chlorine in water, and crystallizing the resulting chloro-s-triazine trione in the presence of an alpha olefin sulfonate with from 4 to 20 carbon atoms.
    Type: Grant
    Filed: August 1, 1983
    Date of Patent: December 25, 1984
    Assignee: Monsanto Company
    Inventor: James C. Wygant
  • Patent number: 4485049
    Abstract: A process is disclosed for producing crystalline nitrilotriacetonitrile from a solution of nitrilotriacetonitrile and water in excess of 95.degree. C., comprising:a. cooling the nitrilotriacetonitrile-water solution in a first stage to the range of about 70.degree. C. to about 90.degree. C., preferably from about 80.degree. C. to about 90.degree. C., and more preferably about 85.degree. C., to produce a nitrilotriacetonitrile water slurry; andb. further cooling the nitrilotriacetonitrile-water slurry in a second stage to below about 35.degree. C., carried out either continuously or in a batch process. Cooling in the first stage is preferably accomplished by recycling cooled nitrilotriacetonitrile-water slurry from the second stage. Cooling in the second stage is preferably accomplished by vacuum cooling.
    Type: Grant
    Filed: January 3, 1983
    Date of Patent: November 27, 1984
    Assignee: Monsanto Company
    Inventors: Kent P. Lannert, Chung Y. Shen, Dat S. Trieu
  • Patent number: 4447337
    Abstract: Aqueous compositions thickened by galactomannan gums are described which are stabilized by a stabilizer system comprising soluble molybdenum and a thiourea.
    Type: Grant
    Filed: February 24, 1982
    Date of Patent: May 8, 1984
    Assignee: Monsanto Company
    Inventors: Mohammad S. Adl, Gary H. Kegeler, Howard L. Vandersall