Abstract: A photographic element is disclosed comprised of a support and at least one layer containing a photographic imaging dye or its precursor. The imaging dye is chosen to have an absorption peak below 590 nm. An azomethine dye having an absorption peak above 700 nm is associated with the imaging dye or its precursor within the photographic layer. The azomethine dye reduces the rate of fading of the imaging dye upon exposure to visible light. A process for stabilizing a photographic dye image is also disclosed.
Type:
Grant
Filed:
February 3, 1975
Date of Patent:
August 16, 1977
Assignee:
Eastman Kodak Company
Inventors:
Wendell F. Smith, Jr., Kenneth L. Eddy, Donald P. Harnish
Abstract: Phosphors which have a host matrix of yttrium oxide or a rare earth metal oxide and are activated by one or more rare earth metal activators are prepared by heating a mixture of salts of the host and activator metals (preferably this mixture is formed by co-precipitating the salts of the host and activator metals) at an elevated temperature in an oxygen-containing atmosphere to form the oxide phosphor, and subsequently heating the phosphor at an elevated temperature in a non-oxidizing atmosphere, which is free of halogenating agents, chalcogenating agents, or fluxes. The step of heating in a non-oxidizing atmosphere brings about a substantial increase in the X-ray speed of the phosphor, improves the stability of the phosphor to light, and increases the reflectance of the phosphor in the visible region of the spectrum. Phosphors prepared by use of this process are useful in the manufacture of X-ray intensifying screens.
Abstract: A photothermographic element and composition for providing a dye image comprises (a) photographic silver halide in association with (b) an oxidation-reduction image-forming combination comprising (i) a silver salt oxidizing agent, with (ii) an organic reducing agent, (c) a polymeric binder for the element or composition and (d) a leuco-base dye which is oxidizable to form a dye image. After imagewise exposure of a photothermographic element or composition containing the described combination, a color image can be developed by overall heating the photothermographic element. Negative or positive dye images can be provided. The dye image can be transferred to an image receiver.
Abstract: In a photothermographic element, composition or process for producing developed images employing processing with heat, a combination comprising (a) photographic silver halide in association with (b) an oxidation-reduction image-forming combination comprising (i) a silver salt oxidizing agent and (ii) a reducing agent which is a 2,6-dichloro or 2,6-dibromo-4-sulfonamidophenol such as the corresponding benzenesulfonamidophenol, and (c) a four equivalent color-forming coupler, and (d) a polymeric binder, provides an image in color. After imagewise exposure of the photothermographic element or composition, a color image can be developed by heating the photothermographic element or composition containing this combination. The combination can be in a diffusion transfer, photothermographic element.
Type:
Grant
Filed:
December 22, 1975
Date of Patent:
May 3, 1977
Assignee:
Eastman Kodak Company
Inventors:
Felice Mary Cerquone, Rolf Steven Gabrielsen, Roland George Willis
Abstract: Light-sensitive compositions including a polymer of the type that is reactable with an azide sensitizer when exposed to light and a sensitizing amount of a naphthalene sensitizer having ortho diazo and oxo substituents at the 1,2 or the 2,1 positions of the naphthalene nucleus and further having an azidosulfonyl substituent group of which the sulfonyl moiety is bonded directly to the naphthalene nucleus at the 4 or the 5-position, are advantageous in the preparation of positive-working photolithographic materials. IN the azidosulfonyl group, the azido moiety can be linked directly or indirectly to the sulfonyl moiety, such as in the compounds 2-diazo-1,2-dihydro-1-oxo-5(4'-azidophenoxysulfonyl)naphthalene and 5-azidosulfonyl-2-diazo-1,2-dihydro-1-oxonaphthalene. The light-sensitive compositions can be coated on support materials to prepare composite photographic elements having utility as photolithographic printing masters and photoresists for etching operations.
Type:
Grant
Filed:
February 9, 1971
Date of Patent:
October 5, 1976
Assignee:
Eastman Kodak Company
Inventors:
Colin Holstead, Wojciech Maria Przezdziecki, Hans M. Wagner
Abstract: Quaternary salts having a pyrido-[1,2-a]-indole nucleus are useful optical brightening agents for synthetic and natural fibers and fabrics. The quaternary salts are especially useful optical brighteners for paper and acrylic fibers.
Abstract: Photographic elements are disclosed containing a hydrophilic colloid layer hardened with a compound having the structural formula:XCH.sub.2 CH.sub.2 SO.sub.2 Q(OQ).sub.m SO.sub.2 CH.sub.2 CH.sub.2 Xwherein X in each occurrence is halogen, Q is an aliphatic or phenyl substituted aliphatic divalent hydrocarbon radical having from 1 to 6 aliphatic carbon atoms and m is an integer of from 0 to 3 inclusive. The hardener also serves as an anti-foggant in photographic applications. Preferred are novel hardening and anti-fogging compounds having the structural formula: ##EQU1## in which X is halogen and R is hydrogen, phenyl or alkyl having from 1 to 6 carbon atoms.
Abstract: Photographic elements are disclosed containing a hydrophilic colloid layer hardened with a compound having two vinylsulfonyl radicals coupled through a divalent hydrocarbon radical chosen from the group consisting of (1) an aliphatic radical having from 1 to 6 carbon atoms, (2) --X--Y--X-- in which X is an alkylene group having 1 or 2 carbon atoms and Y is a phenylene group and (3) a phenyl-substituted methylene group. The compounds may be utilized generally in hardenable hydrophilic colloid compositions. Except for those compounds incorporating an alkylene divalent hydrocarbon radical, the hardeners are new compounds. .Iadd.