Patents Represented by Attorney James C. Logomasini
  • Patent number: 4065428
    Abstract: Disclosed herein are polyblend molding compositions which comprise (A) a polymethylmethacrylate matrix polymer; (B) polychloroprene rubber which is grafted with methylmethacrylate; and (C) a metal oxide. Specimens molded from these polyblends have a UL-94 rating of at least V-1 and a smoke level of less than 300 D.sub.m Flaming using the NBS smoke test.
    Type: Grant
    Filed: December 5, 1975
    Date of Patent: December 27, 1977
    Assignee: Monsanto Company
    Inventor: Gary L. Deets
  • Patent number: 4064093
    Abstract: There is disclosed a process for preparing a latex comprising grafted rubber particles for ABS polyblends that is free of coagulum, the steps comprising, preparing said latex and passing it through a porous filter bed means comprising agglomerated particles of said latex, removing said coagulum and producing a filtered latex. The process also includes the steps of blending said latex with a matrix polymer latex to form a mixed latex and coagulating said mixed latex and recovering said grafted rubber particles and matrix polymer as an ABS polyblend.
    Type: Grant
    Filed: September 22, 1976
    Date of Patent: December 20, 1977
    Assignee: Monsanto Company
    Inventors: William O. Dalton, Glenn B. Hilton
  • Patent number: 4063919
    Abstract: The invention relates to a fertilizer rod composition comprising about 100 parts of a polyvinyl alcohol, about 0 to 20 parts of a plasticizer and about 10 to 350 parts of a fertilizer, a process for producing said rod and a product of said process.
    Type: Grant
    Filed: June 17, 1976
    Date of Patent: December 20, 1977
    Assignee: Monsanto Company
    Inventor: Joseph Grano, Jr.
  • Patent number: 4060504
    Abstract: This invention relates to high efficiency stable aqueous emulsifiable resoles which contain low concentrations of free phenol and free aldehyde causing less pollution than prior art resoles. Said resoles are catalyzed with alkaline earth metal hydroxides and neutralized with oxalic acid or its acid salts providing colloidal inert insoluble oxalate salts dispersed in said resoles. Said resole and said salts being emulsifiable with protein type emulsifiers providing stable emulsions when water in excess of the water tolerance of the resole is added.
    Type: Grant
    Filed: September 15, 1975
    Date of Patent: November 29, 1977
    Assignee: Monsanto Company
    Inventor: Harold P. Higginbottom
  • Patent number: 4053682
    Abstract: Adhesion of filled poly(ester-amide) adhesive compositions to metal substrates is improved by priming the metal substrate with a tie coat of an etherified methylolmelamine prior to application of the filled poly(ester-amide). The etherified methylolmelamine is the condensation product of melamine, formaldehyde and an alkanol or cycloalkanol in which the degree of methylolation is in the range of about 5 to 6, the degree of etherification is in the range of about 3 to 6 and the degree of methylation is at least about 2.
    Type: Grant
    Filed: June 21, 1976
    Date of Patent: October 11, 1977
    Assignee: Monsanto Company
    Inventor: Donald D. Donermeyer
  • Patent number: 4052359
    Abstract: This invention relates to stable water dilutable resoles. Said resoles are catalyzed with alkaline earth metal hydroxides and neutralized with oxalic acid or its acid salts providing inert insoluble oxalate salts dispersed in said resoles. Said salts are size controlled and stabilized by the presence of particular anionic type dispersing agents. A method for manufacture is disclosed.
    Type: Grant
    Filed: February 18, 1976
    Date of Patent: October 4, 1977
    Assignee: Monsanto Company
    Inventor: Harold P. Higginbottom
  • Patent number: 4048125
    Abstract: The present invention relates to an anti-migratory (as respects impregnated porous sheet members) phenol-formaldehyde resole resin in water emulsions. The emulsion is rendered anti-migratory (when impregnated into paper) through the addition thereto of an anti-migratory agent selected from the group consisting of polyelectrolytes, certain salts of inorganic acids, and combinations thereof. The composition is especially useful in the impregnation of filter paper.
    Type: Grant
    Filed: December 1, 1975
    Date of Patent: September 13, 1977
    Assignee: Monsanto Company
    Inventor: Woodrow Hayes Ingram, II
  • Patent number: 4045398
    Abstract: The invention relates to a binder composition comprising a low molecular weight resole resin in combination with boron compounds wherein said boron compounds are present in from about 1 to 30 parts per 100 parts by resole resin solids, said composition having a pH of about 2-6 and said resole having a viscosity of from about 5 to 5000 cps. Said binder provides laminates having superior electrical and flame retardant properties.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: August 30, 1977
    Assignee: Monsanto Company
    Inventor: Ronald H. Dahms
  • Patent number: 4045354
    Abstract: Apparatus for readily separating a low viscosity liquid from an immiscible high viscosity paste or semi-solid comprising a conduit projecting proximate to an upwardly inclined surface provided with means for gravity drainage of the low viscosity liquid. The apparatus is particularly adapted for separating water from a coagulated aqueous latex of polymerized elastomer.
    Type: Grant
    Filed: April 1, 1974
    Date of Patent: August 30, 1977
    Assignee: Monsanto Company
    Inventors: Charles E. Wyman, Robert D. Holstead
  • Patent number: 4043970
    Abstract: The invention relates to a resin binder composition comprising, in combination, a resole resin and a metal salt curing accelerator providing a binder composition that has an improved cure rate in electrical grade laminates without adversely affecting electrical properties. The binder composition provides low viscosity for impregnation and accelerated curing rates for advancing the impregnated substrate prior to laminating and final curing.
    Type: Grant
    Filed: November 24, 1975
    Date of Patent: August 23, 1977
    Assignee: Monsanto Company
    Inventor: Ronald H. Dahms
  • Patent number: 4043955
    Abstract: There is disclosed a continuous method for agglomerating lactices of a polymer to provide large particles. An acid anhydride solution is continuously admixed with an aqueous latex of a polymer followed by passing the admixture through a conduit with laminar-flow wherein the passage-time through said conduit is sufficient to hydrolyze the acid anhydride and produce agglomeration of said particles providing an agglomerated admixture followed by continuously stabilizing said agglomerated admixture with an emulsifying material providing a stabilized agglomerated latex.
    Type: Grant
    Filed: February 20, 1975
    Date of Patent: August 23, 1977
    Assignee: Monsanto Company
    Inventor: Mark D. Paster
  • Patent number: 4042551
    Abstract: The invention relates to polystyrene polyblends reinforced with grafted rubbers having improved melt flow without loss of tensile strength or toughness by incorporating 1 to 5 weight percent of a polyethylene wax having a molecular weight of from about 500 to 2400 and a dispersion index of from about 1-5.
    Type: Grant
    Filed: April 19, 1976
    Date of Patent: August 16, 1977
    Assignee: Monsanto Company
    Inventor: Robert L. Kruse
  • Patent number: 4032509
    Abstract: Disclosed herein are fire retardant polymer compositions based on interpolymers of styrene, maleic anhydride and a brominated monomer such as tribromophenyl acrylate, which have been formulated with various additives. These compositions, which have a UL-94 rating of at least V-1, are especially useful for use in radio and T.V. cabinets, furniture, appliance housings and other similar applications.
    Type: Grant
    Filed: December 29, 1975
    Date of Patent: June 28, 1977
    Assignee: Monsanto Company
    Inventor: Yoon C. Lee
  • Patent number: 4031057
    Abstract: Thermosettable liquid resin compositions comprising a reactive polymer and an N,N'-bis(alkoxymethyl)uron such as N,N'-bis(butoxymethyl)uron. The reactive polymer contains reactive groups such as hydroxyl and carboxyl and is of molecular weight in the range 300 to 5000. The uron ether is employed as a cosolvent for the polymer whereby the solution may be applied as a coating without the need for significant amounts of conventional solvents. Interaction between the polymer and the uron ether promoted by heat in the presence of acid catalyst shifts the role of the uron ether to that of a crosslinking agent for the polymer.
    Type: Grant
    Filed: April 28, 1975
    Date of Patent: June 21, 1977
    Assignee: Monsanto Company
    Inventors: Frank J. Hahn, James O. Santer
  • Patent number: 4028367
    Abstract: High efficiency stable aqueous resoles which contain low concentration of free phenol and free formaldehyde and cause substantially less pollution of the atmosphere than prior art resins. The resoles are prepared by a two-stage reaction which controls the molecular weight, water tolerance and the ratio of methylolated 2,2'-, 2,4'- and 4,4'-dihydroxydiphenylmethanes. Stability is promoted by inhibition of the crystallization of bis(4-hydroxy-3,5-dimethylolphenyl)methane.
    Type: Grant
    Filed: March 10, 1975
    Date of Patent: June 7, 1977
    Assignee: Monsanto Company
    Inventor: Harold P. Higginbottom
  • Patent number: 4022942
    Abstract: The invention relates to high ortho phenolic resole resins and varnishes. The phenolic resole resins are produced by reacting under acidic conditions formaldehyde with a phenol in the presence of a divalent electropositive metal ion. The resulting novel resole is then dissolved in organic solvent. The solutions are useful as varnishes in the manufacture of impregnated sheets, laminates and other reinforced plastics.
    Type: Grant
    Filed: February 17, 1972
    Date of Patent: May 10, 1977
    Assignee: Monsanto Company
    Inventors: George J. Anderson, Harry M. Culbertson
  • Patent number: 4017444
    Abstract: Disclosed herein is a method for stabilizing the viscosity of polyvinyl acetal resins, especially those resins used as interlayers for laminated safety glass. The disclosed process comprises incorporating a buffer having a pH in the range of from 3 to 7 into the plasticized polyvinyl acetal.
    Type: Grant
    Filed: August 13, 1975
    Date of Patent: April 12, 1977
    Assignee: Monsanto Company
    Inventors: George E. Mont, James A. Snelgrove
  • Patent number: 4017498
    Abstract: A system for controlling the per cent of polymer in a reactor in a process in which the reactor effluent, comprising a mixture of polymer, unreacted materials and, possibly, by-products, goes through a separator to remove from such effluent unreacted materials and by-products. The system is especially useful with variable fillage, horizontal continuous stirred tank reactors.
    Type: Grant
    Filed: April 18, 1975
    Date of Patent: April 12, 1977
    Assignee: Monsanto Company
    Inventor: Byrd Hopkins
  • Patent number: 4017559
    Abstract: This invention relates to a polyblend composition and a method for preparing same, said composition comprising a copolymer of a monovinylidene aromatic monomer such as styrene and an unsaturated nitrile monomer such as acrylonitrile blended with a grafted chloroprene rubber, a grafted polybutadiene rubber and a metal oxide.
    Type: Grant
    Filed: July 1, 1975
    Date of Patent: April 12, 1977
    Assignee: Monsanto Company
    Inventors: Gary L. Deets, Robert L. Kruse
  • Patent number: 4016128
    Abstract: The reaction of a 1,4-dihalobutene-2 and a di(tertiary amine) in aqueous medium to form a quaternary ammonium resin. The reaction is carried out with an excess of 1,4-dihalobutene-2; unreacted 1,4-dihalobutene-2 is then stripped and the resin product is stabilized by addition of an alkali metal phosphate.
    Type: Grant
    Filed: May 23, 1975
    Date of Patent: April 5, 1977
    Assignee: Monsanto Company
    Inventors: Irving Serlin, Albert H. Markhart