Patents Represented by Attorney, Agent or Law Firm James C. Paschall
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Patent number: 8193401Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.Type: GrantFiled: December 11, 2009Date of Patent: June 5, 2012Assignee: UOP LLCInventors: James F. McGehee, Lorenz J. Bauer
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Patent number: 8173567Abstract: Disclosed is a catalyst distributor and process for spreading catalyst over a regenerator vessel. Nozzles disposed angular to a header of the distributor spread catalyst throughout a full cross section of the catalyst bed.Type: GrantFiled: December 16, 2008Date of Patent: May 8, 2012Assignee: UOP LLCInventors: Paolo Palmas, Lawrence A. Lacijan, Sujay R. Krishnamurthy, Mohammad-Reza Mostofi-Ashtiani, Paul S. Nishimura, Lisa M. Wolschlag
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Patent number: 8173856Abstract: One exemplary embodiment can be a process for reducing corrosion during removal of one or more sulfur-containing hydrocarbons from a gas. Generally, the process includes producing an effluent including a caustic, one or more hydrocarbons, one or more sulfur compounds, and a gas from an oxidation vessel; sending the effluent to a stack of a disulfide separator; passing the gas, including oxygen and one or more sulfur compounds, through the stack; and passing a stream including one or more hydrocarbons to the stack at a temperature of less than about 38° C. for absorbing the one or more sulfur compounds. Typically, the stack includes one or more walls surrounding a void and adapted to receive a fluid including one or more phases, a packed bed positioned within the void, and a distributor including one or more risers and one or more compartments coupled to a substantially horizontal member forming a plurality of apertures there-through.Type: GrantFiled: June 30, 2010Date of Patent: May 8, 2012Assignee: UOP LLCInventor: Jonathan Andrew Tertel
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Patent number: 8173009Abstract: One exemplary embodiment can be a process for improving a hydrotreated stream for lubricating a machine. The hydrotreated stream can include an effective amount of one or more saturated hydrocarbons. Generally, the process includes hydrogenating the hydrotreated stream having no more than about 300 ppm, by weight, sulfur based on the weight of the stream in a hydrogenation reaction zone to produce a product stream having no more than about 5 ppm, by weight, sulfur.Type: GrantFiled: February 6, 2009Date of Patent: May 8, 2012Assignee: UOP LLCInventor: Tom N. Kalnes
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Patent number: 8163247Abstract: A process is disclosed for contacting feed with mixed catalyst in a secondary reactor that is incorporated into an FCC reactor. The mixed catalyst used in the secondary reactor is regenerated catalyst from a regenerator that regenerates spent catalyst from an FCC reactor that is mixed with spent catalyst from either the FCC reactor or the secondary reactor. The mixing of spent and regenerated catalyst reduces the catalyst temperature and tempers catalyst activity to inhibit both thermal and catalytic cracking reactions.Type: GrantFiled: March 7, 2011Date of Patent: April 24, 2012Assignee: UOP LLCInventors: David A. Lomas, Rusty M. Pittman
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Patent number: 8158069Abstract: An apparatus is disclosed for hydroprocessing two hydrocarbon streams at two different pressures. A hydrogen stream is compressed and split. A first split compressed stream is further compressed to feed a first hydroprocessing unit that requires higher pressure for operation. A second split compressed stream is fed to a second hydroprocessing unit that requires lower pressure. Recycle hydrogen from the second hydroprocessing unit is recycled back to the compression section.Type: GrantFiled: March 31, 2011Date of Patent: April 17, 2012Assignee: UOP LLCInventor: Andrew P. Wieber
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Patent number: 8158070Abstract: An apparatus is disclosed for hydroprocessing two hydrocarbon streams at two different pressures. A hydrogen stream is compressed and split. A first split compressed stream is further compressed to feed a first hydroprocessing unit that requires higher pressure for operation. A second split compressed stream is fed to a second hydroprocessing unit that requires lower pressure. Recycle hydrogen from the second hydroprocessing unit is recycled back to the compression section.Type: GrantFiled: March 31, 2011Date of Patent: April 17, 2012Assignee: UOP LLCInventor: Andrew P. Wieber
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Patent number: 8137534Abstract: Catalyst compositions comprising a siliceous zeolite component, either in separately formed catalyst particles or dispersed in the same binder or matrix as other zeolites of the compositions, are described. The catalyst compositions, for example as blends of three different bound zeolite catalysts, are particularly useful in fluid catalytic cracking (FCC) processes due to the reductions in coke and dry gas yields that allow FCC throughput, which is normally constrained by gas handling and/or catalyst regeneration capacity, to be increased.Type: GrantFiled: April 23, 2009Date of Patent: March 20, 2012Assignee: UOP LLCInventors: Lawrence L. Upson, Lazlo T. Nemeth
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Patent number: 8137631Abstract: One exemplary embodiment can be a fluid catalytic cracking unit. The fluid catalytic cracking unit can include a first riser, a second riser, and a disengagement zone. The first riser can be adapted to receive a first feed terminating at a first reaction vessel having a first volume. The second riser may be adapted to receive a second feed terminating at a second reaction vessel having a second volume. Generally, the first volume is greater than the second volume. What is more, the disengagement zone can be for receiving a first mixture including at least one catalyst and one or more products from the first reaction vessel, and a second mixture including at least one catalyst and one or more products from the second reaction vessel. Typically, the first mixture is isolated from the second mixture.Type: GrantFiled: December 11, 2008Date of Patent: March 20, 2012Assignee: UOP LLCInventors: Paolo Palmas, Robert L. Mehlberg
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Patent number: 8133446Abstract: Slurry hydrocracking a heavy hydrocarbon feed produces a HVGO stream and a pitch stream. At least a portion of the pitch stream is subjected to SDA to prepare a DAO stream low in metals. The DAO is blended with at least a portion of the HVGO stream to provide turbine or marine fuel with acceptable properties for combustion in gas turbines or for marine fuel grades.Type: GrantFiled: December 11, 2009Date of Patent: March 13, 2012Assignee: UOP LLCInventors: James F. McGehee, Lorenz J. Bauer
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Patent number: 8128810Abstract: A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron sulfide crystallites have diameters in the nanometer range.Type: GrantFiled: June 30, 2008Date of Patent: March 6, 2012Assignee: UOP LLCInventors: Alakananda Bhattacharyya, Beckay J. Mezza
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Patent number: 8128879Abstract: The apparatus converts FCC olefins to heavier compounds. The heavier compounds are more easily separated from the unconverted paraffins. The heavier compounds can be recycled to an FCC unit or delivered to a separate FCC unit. Suitable conversion zones are oligomerization and aromatic alkylation zones.Type: GrantFiled: March 31, 2010Date of Patent: March 6, 2012Assignee: UOP LLCInventors: Joao Jorge da Silva Ferreira Alves, James E. Rekoske, Christopher P. Nicholas
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Patent number: 8128807Abstract: This invention is directed to a process for fluid catalytic cracking, including, fluidizing a hydrocarbon stream in a riser, cracking the hydrocarbon stream with catalyst in the riser to produce a cracked stream and spent catalyst, separating the cracked stream and the spent catalyst in a primary separator to obtain a cracked stream with a first concentration of spent catalyst, and transporting the cracked stream with the first concentration of spent catalyst through a conduit to a multi-cyclone separator comprising multiple cyclones extending through a tube sheet to obtain a cracked stream with a second concentration of spent catalyst. The invention is also directed to an apparatus for catalytic cracking including a riser, a primary separator, a disengagement vessel surrounding the primary separator to collect the catalyst, a gas conduit having a first end in fluid connection with the disengagement vessel, and a multi-cyclone separator comprising a plurality of cyclones.Type: GrantFiled: March 31, 2010Date of Patent: March 6, 2012Assignee: UOP LLCInventors: Kelly D. Seibert, Todd P. Mitchell, Mindy B. Kuhn
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Patent number: 8124020Abstract: A process and apparatus is described in which a sulfiding agent is added to a catalytic conversion reactor to prevent metal catalyzed coking. The catalytic reactor may be downstream from a first fluid catalytic cracking reactor that provides C10— hydrocarbons as feed to the downstream catalytic reactor.Type: GrantFiled: March 4, 2009Date of Patent: February 28, 2012Assignee: UOP LLCInventors: Keith A. Couch, Christopher D. Gosling
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Patent number: 8124822Abstract: A process and apparatus is described in which a sulfiding agent is added to a catalytic conversion reactor to prevent metal catalyzed coking. The catalytic reactor may be downstream from a first fluid catalytic cracking reactor that provides C10-hydrocarbons as feed to the downstream catalytic reactor.Type: GrantFiled: March 4, 2009Date of Patent: February 28, 2012Assignee: UOP LLCInventors: Keith A. Couch, Christopher D. Gosling
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Patent number: 8124034Abstract: One exemplary embodiment can be a method of modifying an alkylation unit to increase capacity. The method may include combining a first alkylation zone with a second alkylation zone. Generally, the first alkylation zone includes a first settler having a height and a width. Typically, the width is greater than the height. In addition, the second alkylation zone may have a second settler having a height and a width. Usually, the height is greater than the width.Type: GrantFiled: June 24, 2009Date of Patent: February 28, 2012Assignee: UOP LLCInventors: Daryl Dunham, Dale James Shields
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Patent number: 8123933Abstract: A process and apparatus is disclosed for converting heavy hydrocarbon feed into lighter hydrocarbon products. The heavy hydrocarbon feed is slurried with a catalyst comprising iron oxide and alumina to form a heavy hydrocarbon slurry and hydrocracked to produce lighter hydrocarbons. The iron oxide and alumina catalyst does not require as much iron content relative to non-gaseous material in the reactor to obtain useable products.Type: GrantFiled: June 30, 2008Date of Patent: February 28, 2012Assignee: UOP LLCInventors: Alakananda Bhattacharyya, Beckay J. Mezza
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Patent number: 8110090Abstract: Integrated slurry hydrocracking (SHC) and solvent deasphalting (SDA) methods for making slurry hydrocracking (SHC) distillates are disclosed. Representative methods involve passing a slurry comprising a vacuum column resid, a recycled, deasphalted oil obtained from SDA, and a solid particulate through an SHC reaction zone in the presence of hydrogen to obtain the SHC distillate. Fractionation or distillation in the SHC product recovery section yields a combined SHC gas oil/SHC pitch stream that is sent to SDA. In a representative embodiment, vacuum distillation in the SHC product recovery is avoided, thereby eliminating equipment that is often most susceptible to fouling.Type: GrantFiled: March 25, 2009Date of Patent: February 7, 2012Assignee: UOP LLCInventors: Paul R. Zimmerman, Mark Van Wees, Robert S. Haizmann, Milan Skripek
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Patent number: 8110092Abstract: Disclosed is a process for recovery power from an FCC product. Gaseous hydrocarbon product from an FCC reactor is heat exchanged with a heat exchange media which is delivered to an expander to generate power. Cycle oil from product fractionation may be added to the gaseous FCC product to wash away coke precursors.Type: GrantFiled: August 23, 2010Date of Patent: February 7, 2012Assignee: UOP LLCInventor: John A. Petri
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Patent number: 8066867Abstract: Methods are disclosed for the hydrotreating and hydrocracking of highly aromatic distillate feeds such as light cycle oil (LCO) to produce ultra low sulfur gasoline and diesel fuel. Optimization of hydrotreater severity improves the octane quality of the gasoline or naphtha fraction. In particular, the operation of the hydrotreater at reduced severity to allow at least about 20 ppm by weight of organic nitrogen into the hydrocracker feed is shown to lead to these important benefits. Post-treating of the hydrocracker effluent over an additional hydrotreating catalyst bed may be desired to meet specifications for ultra low sulfur fuel components.Type: GrantFiled: November 10, 2008Date of Patent: November 29, 2011Assignee: UOP LLCInventors: Bart Dziabala, Vasant P. Thakkar, Suheil F. Abdo