Abstract: Graphite carbon surfaces are protected from elevated temperature oxidation and mechanical wear by electric arc thermal spray coating exposed surfaces with a titanium nitride or multi-element (e.g., aluminum-silicon-titanium) coating.

Abstract: A coated carbon body having improved resistance to high temperature oxidation and a method for producing the coated carbon body are described. The coated carbon body comprises a carbon body, an intermediate glass forming coating within said converted layer, and an outer refractory coating on the intermediate coating. The body has a converted porous layer formed by etching and reacting the body with gaseous boron oxide and the resulting converted layer contains interconnecting interstices and boron carbide formed by the reaction of the boron oxide and the carbon body. The method comprises contacting a carbon body with boron oxide at an elevated temperature sufficient to cause the reaction between the carbon body and boron oxide to form a converted porous layer which contains interconnecting interstices in the body and boron carbide and then applying the intermediate glass forming coating over the converted layer and an outer refractory coating over the intermediate coating.

Abstract: An improved process for producing nitrogen-based atmospheres suitable for annealing ferrous metals and alloys, brazing metals, sintering metal and ceramic powders, and sealing glass to metals from non-cryogenically generated nitrogen is presented. These atmospheres are produced by 1) humidifying non-cryogenically generated nitrogen containing less than 5.0 vol. % residual oxygen, 2) mixing it with a specified amount of a hydrocarbon gas, 3) feeding the gaseous mixture into the heating zone of a furnace through a diffuser, and 4) converting in-situ the residual oxygen and moisture present in it to a mixture of carbon dioxide, carbon monoxide, moisture, and/or hydrogen. The key features of the present invention include a) humidifying the feed gas prior to introducing it into the heating zone of a furnace operated above about 800.degree. C.

Abstract: The present invention is directed to active compositions, such as adsorbents and catalysts, which comprise cuprous compounds dispersed on amorphous oxide or carbon macroporous supports. The compositions are prepared by impregnating cupric compounds on pretreated supports with the aid of an aqueous solution of an ammonium salt of a di- or polycarboxylic acid dispersant, such as ammonium citrate, followed by activation of the cupric compound or reduction of the cupric compound to the corresponding cuprous compound. Methods of synthesis and processes utilizing the compositions are also disclosed.

Abstract: Gas transport and bio-inert fluid administration to biological systems methods using a novel composition of matter are disclosed wherein the composition of matter comprises perfluorinated, ethyldimethyl cyclohexane. The compound has unique utilities in vapor phase heating and soldering, oxygen transport for biological fluids and other requirements for an inert, stable fluid.

Abstract: Vinyl acetate and an N-vinyl formamide are copolymerized to yield poly(vinyl acetate)-co-poly(N-vinyl formamide) which is base hydrolyzed to poly(vinyl alcohol)-co-poly(N-vinyl formamide). Two phase hydrolysis of particles of poly(vinyl alcohol)-co-poly(N-vinyl formamide) as a slurry in methanol yields particles of poly(vinyl alcohol)-co-poly(vinylamine).provided is a copolymer of the following general formula ##STR1## where m is 0 to 15 mole %. n is 50 to 99 mole %.x is 0 to 30 mole %. andy is 1 to 50 mole % .

Abstract: Bundles of hollow filament membranes suitable for use in fluid separation, such as in the separation of air into gases more concentrated in oxygen and nitrogen are made in a cylindrical form and annular cross-section with multiple filaments of each layer lying in generally parallel helical paths at a common angle to the axis of symmetry of the bundle. Continuous lengths of filaments are laid down on the core while same is rotated first in a "forward" sense and the filament lay-down point is traversed from a first end of the core to the second, and then in a "reverse" sense while the filament lay-down point is traversed from the second end to the first. Reversing of the direction of core rotation and filament end-to-end traversal is repeated with said reversing controlled in such a manner that the path of the filament returning from either end to the other is displaced incrementally from that of the filament portion laid down in the immediately preceding traversal.

Abstract: A process for converting polyurethane foam into reusable polyol composition which comprises glycolyzing the polyurethane foam to yield a glycolysis polyol product containing amines and reacting the glycolysis polyol product with an alkylene oxide in a mole ratio of <1 mole of alkylene oxide per mole of active amine hydrogen atom in the glycolysis polyol product.

Abstract: A method for preventing or reducing the marine life buildup on a submerged surface by applying to the surface an antifouling coating composition comprising a combination of a silicone fluid and a silicone resin.

Abstract: A process for thermal oxidation of silicon or cleaning of furnace tubes used in semiconductor manufacturing by exposing the silicon or tube to temperatures above 700.degree. C. while flowing a carrier gas containing oxygen and a chlorohydrocarbon having a general formula C.sub.x H.sub.x Cl.sub.x where x is 2, 3, or 4 over the silicon or tube. The chlorohydrocarbon is selected to readily and completely oxidize at temperature.

Abstract: The present invention is a process for producing organic esters wherein a dialkyl ether and a carboxylic acid are reacted in the presence of a solid phase acidic catalyst having an acidity factor of at least 0.30, preferably at least 1, under reaction conditions sufficient to form a reaction mixture comprising the desired organic ester and an alcohol and recovering the organic ester. For example, methyl acetate can be prepared by reacting dimethyl ether and acetic acid in the presence of montmorillonite, amorphous silica-alumina or .kappa.-alumina under conditions sufficient to form methyl acetate. While typical processes produce an azeotropic mixture of the desired organic ester and water, the claimed process utilizes a combination or reactants and catalysts wherein water is not produced in appreciable amounts. Therefore, the organic ester product can be separated conveniently thereby avoiding a cumbersome azeotropic distillation step as required in prior art processes.

Abstract: A process for generating in-situ low-cost atmospheres suitable for annealing and heat treating ferrous and non-ferrous metals and alloys, brazing metals and ceramics, sealing glass to metals, and sintering metal and ceramic powders in a continuous furnace from non-cryogenically produced nitrogen containing up to 5% residual oxygen is presented. The disclosed process involves mixing nitrogen gas containing residual oxygen with a pre-determined amount of a reducing gas such as hydrogen, a hydrocarbon, or a mixture thereof, feeding the gaseous mixture through a non-conventional device into the hot zone of a continuous heat treating furnace, converting residual oxygen to an acceptable form such as moisture, a mixture of moisture and carbon dioxide, or a mixture of moisture, hydrogen, carbon monoxide and carbon dioxide, and using the resultant gaseous mixture for annealing and heat treating metals and alloys, brazing metals and ceramics, sintering metal and ceramic powders, and sealing glass to metals.

Abstract: Resins which comprise polymers which contain multiple acetal groups have been developed which are useful for crosslinking and adhesion promotion in coating and adhesive applications. The polymers which make up these resins are prepared by the addition of aminoacetals to polymers containing anhydride functionality. Optionally, these polymers may be modified by titration with a tertiary amine or alkali base which solubilizes the polymer in aqueous systems.

Abstract: A process for producing low-cost atmospheres suitable for annealing, brazing, and sintering non-ferrous metals and alloys from non-cryogenically produced nitrogen containing up to 5%, residual oxygen is disclosed. According to the process, suitable atmospheres are produced by 1) pre-heating the non-cryogenically produced nitrogen stream containing residual oxygen to a desired temperature, 2) mixing it with more than a stoichiometric amount a hydrocarbon gas, 3) passing it through a reactor packed with a platinum group of metal catalyst to reduce the residual oxygen to very low levels and convert it to a mixture of moisture and carbon dioxide, and 4) using the reactor effluent stream for annealing, brazing, and sintering non-ferrous metals and alloys in a furnace.

Abstract: A method is disclosed for cleaning microelectronic surfaces using an aerosol of at least substantially solid argon or nitrogen particles which impinge upon the surface to be cleaned and then evaporate and the resulting gas is removed by venting along with the contaminants dislodged by the cleaning method.

Abstract: A method is disclosed for the electric arc spraying of powder-filled cored wires to apply hard, wear-resistant coatings to various substrates. Inert gas, preferably nitrogen, is supplied to the arc spray gun such that the mass ratio of the wire feed rate to the gas feed rate is preferably between about 0.07 and about 0.11. Operation in this range yields an optimum combination of coating hardness properties and arc spray gun operating characteristics.

Abstract: High capacity solid state compositions comprising cyanocobaltate complexes have been developed which are capable of reversibly chemically binding oxygen to selectively remove oxygen from an oxygen-containing fluid stream. The cyanocobaltate complexes which make up the compositions comprise a cobalt (II)-containing anion having from 3 to 5 cyanide ligands wherein at least one cyanide stretching mode, as measured by infrared spectroscopy, is between 2074 cm.sup.-1 and 2140 cm.sup.-1. Additionally, these complexes have a charge-balancing cation having a molecular volume in excess of 40.ANG..sup.3.

Abstract: A metal powder is produced by atomizing molten metal in an electric arc spray gun and rapidly quenching the resulting droplets in a liquid cryogen to form fine, highly spherical, oxide-free particles. The rapid quenching yields particles with a very fine, uniform microstructure which melt rapidly and uniformly when later heated. The powder is especially well-suited for making solder paste for device fabrication in the electronics industry.

Abstract: The present invention is a process for recovering hydrogen from dilute refinery off gases using a vacuum swing adsorption process having a simultaneous cocurrent depressurization to provide purge gas for another bed under the influence of a vacuum and countercurrent depressurization to vent void space gas and/or adsorbed gas to ambient.

Abstract: In a process for preparing poly(vinyl alcohol), an improved method for separating the methanol/acetate azeotropes that result from said process. The azeotropes are separated by selective adsorption of methanol on an adsorbent followed by regeneration of the adsorbent with hot methanol vapor.