Patents Represented by Attorney, Agent or Law Firm James G. Vouros
  • Patent number: 7749934
    Abstract: A method for polymerizing ethylenically unsaturated monomers, including non-polar olefinic monomers, polar olefinic monomers, and combinations thereof, using a protected catalytic composition in an aqueous medium, is disclosed. An aqueous dispersion containing the protected catalytic composition is also disclosed, along with an aqueous dispersion of the addition polymer produced by the polymerization.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: July 6, 2010
    Assignee: Rohm and Haas Company
    Inventors: Ralph Craig Even, Willie Lau
  • Patent number: 6337106
    Abstract: This invention relates to a method of producing a two-pack or multi-pack fast-setting waterborne paint composition, particularly a traffic paint, which has a reducing component in one pack and an oxidizing component in the other pack of the two-pack paint composition. The present invention also relates to the two-pack or multi-pack waterborne paint composition produced therefrom.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: January 8, 2002
    Assignee: Rohm and Haas
    Inventor: Ward Thomas Brown
  • Patent number: 6337366
    Abstract: A method of improving the viscosity stability of an aqueous composition by the addition to the aqueous composition of a mixture of at least one multiphobe and at least one monophobe is disclosed. The method is particularly useful for stabilizing the viscosity of an aqueous composition containing at least one associative thickener, when surfactants or additives containing surfactants, such as for example colorants, particularly at high levels, are added to the aqueous composition.
    Type: Grant
    Filed: March 10, 2000
    Date of Patent: January 8, 2002
    Assignee: Rohm and Haas
    Inventors: David Richard Amick, James Watson Neely
  • Patent number: 6072039
    Abstract: A hybrid polypeptide is disclosed, comprising a polypeptide for attachment of a prosthetic group to avidin fused to at least one polypeptide of interest, and a method of making the same. The hybrid polypeptide is produced by recombinant DNA techniques, using a DNA expression vector composed of a DNA fragment coding for the polypeptide for attachment to avidin fused to DNA coding for one or more polypeptides of interest. The hybrid polypeptide may also contain linking amino acid sequences for cleavage of the polypeptide of interest from the polypeptide for attachment using an appropriate proteolytic or chemical reagent. The hybrid polypeptide is expressed in appropriate host cells transformed with the DNA expression vector encoding the hybrid polypeptide, and may be recovered from crude cell extracts in high yield and high purity using avidin affinity chromatography.
    Type: Grant
    Filed: April 19, 1991
    Date of Patent: June 6, 2000
    Assignee: Rohm and Haas Company
    Inventors: Ferdinand Carl Haase, Dean Ervin Cress
  • Patent number: 5922661
    Abstract: A detergent tablet is disclosed which comprises at least 50 wt. % of a non-phosphate builder and from 0 to 20 wt. % of a phosphate builder, and has incorporated therein as binder from 0.3 to 5 wt. % of a neutralised polymer of hydrophilic or hydrophobic monomers which have a glass transition temperature (Tg) of from 40 to 120.degree. C., which monomers comprise(meth)acrylic acid, maleic anhydride, alkyl (meth)acrylates, alkylhydroxy (meth)acrylates, or styrene, the polymer having a weight average molecular weight of from 10,000 to 120,000.
    Type: Grant
    Filed: November 30, 1998
    Date of Patent: July 13, 1999
    Assignee: Rohm & Haas Company
    Inventors: Yves Duccini, Paul Francis David Reeve, Charles Elwood Jones, Francois Gauthier
  • Patent number: 5908877
    Abstract: A water dispersible powder composition is provided. The powder composition contains at least one film-forming polymer having at least one functional group and at least one reactive component that reacts to form a non-ionic bond with the polymer functional group following dispersion of the powder composition in water. The reaction between the polymer particles in the admixture and the reactive component renders the resulting coating water-resistant. The powder composition of this invention is useful for producing water-resistant coatings.
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: June 1, 1999
    Inventors: Xiaohong Ci, David RIchard Amick, Richard Foster Merritt
  • Patent number: 5650261
    Abstract: A positive-acting photoresist composition which produces crosslinked images and processes for using the photoresist composition are disclosed. The photoresist composition is prepared from a mixture containing a film forming, polymer-containing, acid hardening resin system, an acid or acid generating material (preferably in the form of a thermal acid generator) for crosslinking the acid hardening resin system, and a photobase generating compound. The photoresist composition is applied as a film onto a substrate surface and selectively imagewise exposed through a photomask to actinic radiation. The actinic radiation causes the photobase generator to produce a base in the imagewise exposed portions of the photoresist film. The photochemically generated base neutralizes the acid in the imagewise exposed areas of the photoresist film.
    Type: Grant
    Filed: October 27, 1989
    Date of Patent: July 22, 1997
    Assignee: Rohm and Haas Company
    Inventor: Mark Robert Winkle
  • Patent number: 5503767
    Abstract: This invention relates to a rinse added fabric softening composition comprising from about 25 to about 95 percent by weight water, from about 2 to about 60 percent by weight of a cationic softening agent and from about 0.5 to about 18 percent by weight of a water-soluble polymer, wherein said polymer is a reaction product of (a), (b) and, optionally (c), wherein;(a) is selected from the group consisting of ethylenically unsaturated monocarboxylic acids and their salts, ethylenically unsaturated dicarboxylic acids, their salts and anhydrides,(b) is selected from the group consisting of surfactant radicals and polyalkylenoxy compounds, wherein the surfactant radicals consist of a hydrophobic group linked to a polyalkylenoxy group and(c) is a carboxylate-free monomer.
    Type: Grant
    Filed: May 16, 1994
    Date of Patent: April 2, 1996
    Assignee: Rohm and Haas Company
    Inventor: Curtis Schwartz
  • Patent number: 5498675
    Abstract: This invention relates to a block copolymer comprising: a) at least one first block of polymerized units of at least one first ethylenically unsaturated monomer and at least one latent thiol mercaptan chain transfer agent wherein the latent thiol mercaptan chain transfer agent has the general formula; ##STR1## wherein A is a polyvalent organic radical; x and y are positive integers such that x+y equals the valence of A; B is an organic acyl radical; and n and m are integers from 1 to 6; and b) at least one second block of polymerized units of at least one second ethylenically unsaturated monomer, wherein said at least one second block is attached to said at least one first block by reacting with terminal thiol functional groups contained on said at least one first block. In addition, this invention relates to the method of making this block copolymer.
    Type: Grant
    Filed: December 9, 1994
    Date of Patent: March 12, 1996
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Andrew W. Gross
  • Patent number: 5492965
    Abstract: This invention relates to a polymer composition of a block copolymer dispersed in water wherein the block copolymer is composed of: a) at least one first block of polymerized units of at least one first ethylenically unsaturated monomer and at least one latent thiol mercaptan chain transfer agent wherein the latent thiol mercaptan chain transfer agent has the general formula; ##STR1## wherein A is a polyvalent organic radical; x and y are positive integers such that x+y equals the valence of A; B is an organic acyl radical; and n and m are integers from 1 to 6; and b) at least one second block of polymerized units of at feast one second ethylenically unsaturated monomer, wherein said at least one second block is attached to said at least one first block by reacting with terminal thiol functional groups contained on said at least one first block.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: February 20, 1996
    Assignee: Rohm and Haas Company
    Inventors: William D. Emmons, Andrew W. Gross
  • Patent number: 5457176
    Abstract: The present invention relates to an acid catalyzed thermal polycondensation process for producing amino acid polymers. More specifically, amino acid polymers are produced by thermally condensing a mixture of one or more amino acids and optionally one or more polyfunctional monomers, using an acid catalyst, while maintaining an intimate admixture. Processing techniques useful for maintaining an intimate admixture include adding to the mixture one or more processing aids, using mechanical means, and combinations thereof. The amino acid polymers produced by this process are useful as cleaning and detergent additives; fertilizer and pesticide additives; personal care product additives; dispersants for inorganic particulates, aqueous emulsions, and drilling muds; and water treatment and oil production operation additives as corrosion and scale inhibitors.
    Type: Grant
    Filed: March 16, 1994
    Date of Patent: October 10, 1995
    Assignee: Rohm and Haas Company
    Inventors: David E. Adler, Michael B. Freeman, James M. Lipovsky, Yi H. Paik
  • Patent number: 5435879
    Abstract: Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers containing pendant functional groups attached to a polymer backbone and having the formula: ##STR1## in which R.sub.
    Type: Grant
    Filed: November 7, 1990
    Date of Patent: July 25, 1995
    Assignee: Rohm and Haas Company
    Inventors: Gaylen M. Knutson, Paul J. Steinwand, Joseph J. Wilczynski, Lonnie T. Spada
  • Patent number: 5430114
    Abstract: The present invention provide water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.
    Type: Grant
    Filed: November 29, 1994
    Date of Patent: July 4, 1995
    Assignee: Rohm and Haas Company
    Inventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
  • Patent number: 5420211
    Abstract: This invention relates to a novel class of biodegradable water-soluble graff copolymers having building, anti-filming, dispersing and threshold crystal inhibiting properties comprising (a) an acid functional monomer and optionally (b) other water-soluble, monoethylenically unsaturated monomers copolymerizable with (a) grafted to a biodegradable substrate comprising polyalkylene oxides and/or polyalkoxylated materials.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: May 30, 1995
    Assignee: Rohm and Haas Company
    Inventors: Kathleen A. Hughes, Graham Swift
  • Patent number: 5401807
    Abstract: A method has been discovered for generating free radicals at saturated carbon atoms on the backbone of acrylate polymers or copolymers. This method is useful for combining at least two polymer chains at the free radical sites on each polymer chain to form a polymer or copolymer product with increased molecular weight and a controlled degree of branching. The polymers and copolymers produced by this process are useful as antiscalants, dispersants, incrustation inhibitors and superabsorbants. They are particularly useful in detergent and cleaning applications.
    Type: Grant
    Filed: October 8, 1992
    Date of Patent: March 28, 1995
    Assignee: Rohm and Haas Company
    Inventors: Kathleen A. Hughes, Graham Swift
  • Patent number: 5399642
    Abstract: This invention relates to latent thiol mercaptan chain transfer agents and their use in the synthesis of polymers. In addition, this invention relates to novel polymers and block copolymers formed using these latent thiol mercaptan chain transfer agents.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: March 21, 1995
    Assignee: Rohm & Haas Company
    Inventors: William D. Emmons, Andrew W. Gross
  • Patent number: 5395856
    Abstract: Novel, improved ligand-containing media, a method of preparation and use in the production of peptides, proteins, and the like, by chromatographic separation, and more specifically media having permanently attached via a covalent bond to an inert solid substrate an avidin polypeptide ligand in the dissociated renatured form which reversibly binds to certain molecules such as proteins, peptide, nucleotides, oligonucleotides, and the like and to other molecules which bind to avidin via biotinylation or by way of their secondary/tertiary micromolecular structures.
    Type: Grant
    Filed: August 25, 1993
    Date of Patent: March 7, 1995
    Assignee: Rohm and Haas Company
    Inventor: Ferdinand C. Haase
  • Patent number: 5395905
    Abstract: The present invention provides water-soluble poylmers containing, as polymerized units: (a) from about 3 to about 95 percent by weight of one or more cyclohexene anhydrides or the alkali metal or ammonium salts thereof. The present further provides aqueous polymerization processes for making the polymers. The water-soluble polymers are useful as water-treatment additives for boiler waters and cooling towers and as detergent additives acting as builders, anti-filming agents, dispersants, sequestering agents and encrustation inhibitors.
    Type: Grant
    Filed: January 12, 1993
    Date of Patent: March 7, 1995
    Assignee: Rohm and Haas Company
    Inventors: Marianne P. Creamer, Thomas F. McCallum, III, Graham Swift, Barry Weinstein
  • Patent number: 5380817
    Abstract: A process is provided for preparing polysuccinimides by forming a polymerization mixture of poly(alkylene glycol), aspartic acid and, optionally, one or more other amino acids; heating the mixture to an elevated temperature; and maintaining the mixture at the elevated temperature to form polysuccinimides.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: January 10, 1995
    Assignee: Rohm and Haas Company
    Inventors: Yi H. Paik, Ethan S. Simon, Graham Swift
  • Patent number: 5371177
    Abstract: A process is provided for preparing polysuccinimides by forming a polymerization mixture of poly(alkylene glycol), maleamic acid and, optionally one or more other amic acids, heating the mixture to an elevated temperature, and maintaining the mixture at the elevated temperature to form polysuccinimides.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: December 6, 1994
    Assignee: Rohm and Haas Company
    Inventors: Yi H. Paik, Ethan S. Simon, Graham Swift