Patents Represented by Attorney James J. Drake
  • Patent number: 5658798
    Abstract: The invention is a method of monitoring for the presence of certain constituents of food processing streams by measurement of fluorescence. The constituent monitored can be a fluorescing impurity of a food product, or the food product itself if such naturally fluoresces. Moreover, losses of the constituent to be monitored may be determined by concurrent measurement of fluorescence of a fluorescent material added to the food process stream. The method is applicable to the following food processing streams among others: meat, vegetable oil, sugar beet, sugar cane, grain, poultry, fruit and soybean processing streams. Upon determination of a variation of the fluorescing constituent to be measured, the food process can be adjusted accordingly.
    Type: Grant
    Filed: February 8, 1996
    Date of Patent: August 19, 1997
    Assignee: Nalco Chemical Company
    Inventors: Gregory K. Bertin, Theresa P. Cawley, John E. Hoots, Brian V. Jenkins, Christine M. Stuart, Terry L. Stuebner
  • Patent number: 5659002
    Abstract: The invention is a process for preparing alkylated tannin Mannich polymers by reacting a tannin Mannich condensation polymer, prepared from a condensed tannin, and amine, and formaldehyde, with an alkylating agent at a pH between 5 and 14. Optionally, the alkylated tannin Mannich polymer may be reacted further with formaldehyde to increase its viscosity.The invention further comprises a method of removing color form waste water utilizing the alkylated tannin Mannich polymer produced by the above process.
    Type: Grant
    Filed: March 24, 1995
    Date of Patent: August 19, 1997
    Assignee: Nalco Chemical Company
    Inventors: Peter E. Reed, Martha R. Finck
  • Patent number: 5658467
    Abstract: The present invention provides a composition and method of administering same for inhibiting the growth of microorganisms. The composition of the present invention includes sufficient amounts of a peracetic acid and a non-oxidizing biocide. The method of the present invention includes the step of adding sufficient amounts of the peracetic acid and the non-oxidizing biocide to industrial process waters.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: August 19, 1997
    Assignee: Nalco Chemical Company
    Inventors: Judy G. LaZonby, Robert E. McCarthy, Nancy L. Casselman
  • Patent number: 5653886
    Abstract: The present invention related to the use of certain cross-linked diallyldimethyl ammonium chloride polymers in water-in-oil emulsion form for use as coagulants in suspensions of inorganic solids. The diallyldimethyl ammonium chloride polymers are preferably polymers of diallyldimethyl ammonium chloride, acrylamide, and triallylamine. The water-in-oil emulsions are formulated to invert after addition to the inorganic solids suspension, as the suspension travels to a mechanical thickening device for further processing. The inorganic solids from refuse or concentrate mineral processing applications may be coal, copper ore, sand, gravel, taconite, beryllium, trona, kaolin or precious metals.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: August 5, 1997
    Assignee: Nalco Chemical Company
    Inventors: E. Michael Kerr, John R. Hurlock, Lawrence J. Connelly
  • Patent number: 5650072
    Abstract: The invention provides a method for the inhibition of fouling in petrochemical processes. The method comprises adding from about 0.1 to about 10,000 parts per million sulfonated oils, sulfonated fatty acids, sulfated oils, sulfated fatty acids, or naphthalene sulfonate formaldehyde condensates to a petrochemical process to disperse water insoluble foulant into an aqueous system.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: July 22, 1997
    Assignee: Nalco/Exxon Energy Chemicals L.P.
    Inventors: Robert D. Mc Clain, Vincent E. Lewis
  • Patent number: 5648508
    Abstract: Novel metal-organic microporous materials are prepared in solution using mild reaction conditions from a metal or metalloid ion with a ligand containing multidentate functional groups in the presence of a templating agent. The resultant microporous materials are useful in the purification of liquids and gases.
    Type: Grant
    Filed: November 22, 1995
    Date of Patent: July 15, 1997
    Assignee: Nalco Chemical Company
    Inventor: Omar M. Yaghi
  • Patent number: 5647995
    Abstract: An improved method is disclosed for the preparation of novel alkali metal diphosphinate salts by the reaction of an acetylenic compound with an alkali metal hypophosphite in the presence of a free radical source, the use of these novel compounds in further reactions to prepare diphosphonate compounds and diphosphinate containing adducts, oligomers and polymers and utilization of these compounds, polymers and oligomers to control calcium carbonate scale and mild steel corrosion in cooling water.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: July 15, 1997
    Assignee: Nalco Chemical Company
    Inventors: James F. Kneller, Donald A. Johnson, Vytas Narutis, Binaifer S. Khambatta
  • Patent number: 5645799
    Abstract: The invention comprises an apparatus for optimizing the dosage of a chemical waste water treatment agent using a fluorescent tracer by processing a sample of the waste water stream and allowing continuous on-stream monitoring of the performance of the chemical waste water treatment agent. The apparatus is comprised of a series of components that sample the waste stream, process the sample for analysis, analyze the sample, record the data in a historical database and, based upon the analysis as compared to historical data, adjust the chemical feed system to optimize the chemical waste water treatment agent according to the programmed optimization logic.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: July 8, 1997
    Assignee: Nalco Chemical Company
    Inventors: Jitendra T. Shah, Ananthasubramanian Sivakumar, David W. Scheimann
  • Patent number: 5643460
    Abstract: A method for separating emulsified oil from water in petroleum production is disclosed. Low molecular weight polymers of dimethylaminoethyl acrylate methyl chloride and benzyl chloride quaternary salt have good activity as reverse emulsion breakers for freeing oil tied up as a oil-in-water emulsion. The polymer reverse emulsion breakers are preferably prepared and used as aqueous solutions to obviate the need for inversion techniques and the use of hydrocarbon compatibilizers and surfactants as required for a latex polymer.
    Type: Grant
    Filed: June 30, 1995
    Date of Patent: July 1, 1997
    Assignee: Nalco/Exxon Energy Chemicals, L. P.
    Inventors: Robert A. Marble, Manian Ramesh, Norman Edward Byrne
  • Patent number: 5641396
    Abstract: 2-amino-1-methoxypropane is used as a neutralizing amine in crude oil distillation units. The amine of the invention gives superior neutralization at the first initial condensate compared to other commonly used neutralizing amines.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: June 24, 1997
    Assignee: Nalco/Exxon Energy Chemicals L. P.
    Inventors: Veronica K. Braden, Tannon S. Woodson
  • Patent number: 5641394
    Abstract: The invention is a composition for use in deactivating iron species in hydrocarbon fluids, comprising the products resulting from the reaction of (I), with (II) and (III) is disclosed; wherein (I) is a substituted catechol of the structure ##STR1## where R is chosen from alkyl, aryl, alkaryl, or arylalkyl from about 1 to 20 carbon atoms; wherein (II) is a mixture of polyamines having the repeat structure ##STR2## wherein m ranges from 1 to 10 and where X is an alkyl, branched alkyl, cyclic or branched cyclic alkyl of from 1 to 10 carbon atoms, and where Y is a substituted alkylphenol of structure ##STR3## where R" is chosen from alkyl, aryl, alkaryl, arylalkyl of from about 1 to 22 carbon atoms; wherein (III) is an aldehyde of structure ##STR4## where R' is chosen from hydrogen, and an alkyl of from 1 to 6 carbon atoms. Also disclosed is the function of the said same composition, resulting from the reaction of (I) with (II) and (III), as an antioxidant in hydrocarbon fluids.
    Type: Grant
    Filed: April 6, 1995
    Date of Patent: June 24, 1997
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: Sherri L. Fisher, Joseph P. Street
  • Patent number: 5637587
    Abstract: This invention provides a surprisingly efficacious combination useful for inhibiting microorganism growth, particularly in aqueous slurries containing mineral ore. In particular embodiments, the invention provides an antimicrobial composition comprising 1-(3-chloroallyl)-3,5,7 triaza-1-azoniaadamantane chloride and 2-bromo-2-nitropropane-1,3-diol. The invention also provides a method for inhibiting microbial growth in an aqueus mineral or ore slurry, e.g. a kaolin slurry. The method includes the step of adding to the slurry a microbiocidal composition of 1-(3-chloroallyl)-3,5,7 triaza-1-azoniaadamantane chloride and 2-bromo-2-nitropropane-1,3-diol.
    Type: Grant
    Filed: February 7, 1996
    Date of Patent: June 10, 1997
    Assignee: Nalco Chemical Company
    Inventors: Anthony E. Gross, Nancy L. Casselman
  • Patent number: 5635112
    Abstract: A method for breaking an oil-in-water emulsion which comprises the addition of a hydrophobically-modified polyelectrolyte copolymer comprising a diallyldimethylammonium chloride and a hydrophobically-associating monomer selected from the group consisting of quaternized dialkylaminoalkylacrylates, quaternized dialkylaminoalkylmethacrylates, and alkyl esters of (meth)acrylic acids, preferably ethylhexylacrylate, to the emulsion.
    Type: Grant
    Filed: July 26, 1995
    Date of Patent: June 3, 1997
    Assignee: Nalco Chemical Company
    Inventors: Manian Ramesh, Ananthasubramanian Sivakumar
  • Patent number: 5630964
    Abstract: The invention comprises a method of inhibiting naphthenic acid corrosion in a high temperature hydrocarbon system, comprising adding to the system a corrosion-inhibiting amount of a phosphate ester and a corrosion-inhibiting amount of organic polysulfide.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: May 20, 1997
    Assignee: Nalco/Exxon Energy Chemicals, L.P.
    Inventors: Elizabeth Babaian-Kibala, John G. Hyatt, Theodore J. Rose
  • Patent number: 5629368
    Abstract: A process for preparing a liquid slurry of bentonite which comprises the steps of charging a reactor vessel with between about 25 to about 75% of water by weight. The water is heated to a temperature range between about 50.degree. C. to about 95.degree. C. The reactor vessel is charged with between about 0, 1 and about 10% of sodium salt of silicic acid by weight and with between about 15 to about 35% of bentonite by weight. The reactor vessel is also charged with between about 10 to about 30% of a polyacrylate by weight.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: May 13, 1997
    Assignee: Nalco Canada, Inc.
    Inventor: Daniel K. Chung
  • Patent number: 5624569
    Abstract: The invention is a method for clarifying ink-containing effluent water from recycled paper production which comprises the step of adding a water-soluble, surface active, silicon-containing polyelectrolyte polymer coagulant to the ink-containing effluent water from recycled paper production, wherein the polymer has from 0.01 to 10 mole percent of a vinyl alkoxysilane monomer. A preferred silicon-containing polyelectrolyte polymer is the product of a free radical synthesis from vinyltrimethoxysilane and diallyldimethylammoniumchloride monomers.
    Type: Grant
    Filed: January 23, 1996
    Date of Patent: April 29, 1997
    Assignee: NALCO Chemical Company
    Inventors: Daniel K. Chung, Manian Ramesh, Karen R. Tubergen
  • Patent number: 5624575
    Abstract: The present invention relates generally to controlling the growth of microorganisms, including the inhibition of the growth of filamentous microorganisms in industrial process waters. The invention is directed to a method for preventing and removing the formation of deposits by microorganisms in the wet end of a paper machine with a combination of peracetic acid and an ethylene oxide/propylene oxide copolymer.
    Type: Grant
    Filed: July 28, 1995
    Date of Patent: April 29, 1997
    Assignee: Nalco Chemical Company
    Inventors: Robert J. Meade, Linda R. Robertson, Nicole R. Taylor, Judy G. LaZonby
  • Patent number: 5622647
    Abstract: A method for dewatering coal tailings, clean coal products and mineral slurries, as well as for the clarification of water contained in coal refuse slurries, employing a copolymer of diallyldimethlylammonium halide and a vinyl alkoxysilane, which is preferably a copolymer of diallyldimethylammonium chloride and vinyltrimethoxysilane as a coagulant is disclosed.
    Type: Grant
    Filed: May 22, 1995
    Date of Patent: April 22, 1997
    Assignee: Nalco Chemical Company
    Inventors: E. Michael Kerr, Manian Ramesh
  • Patent number: 5622533
    Abstract: The invention provides a method for dewatering coal tailing aqueous slurries in a twin belt press process. The method including the step of adding to the slurry a coagulant composition including a vinylamine copolymer including from about 1 to about 99 mole percent vinylamine and from about 1 to about 99 mole percent of at least one monomer selected from the group consisting of vinylformamide, vinyl alcohol, vinyl acetate, vinyl pyrrolidinone and the esters, amides and salts of acrylic acid and methacrylic acid.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: April 22, 1997
    Assignee: Nalco Chemical Company
    Inventors: Anthony G. Sommese, Krishnan J. Pillai
  • Patent number: 5620629
    Abstract: This invention relates to a composition of matter of a silica sol/water soluble cationic polymer mixture. The colloidal silica may also be conditioned by passing over a cationic exchange resin prior to addition of cationic polymer.
    Type: Grant
    Filed: November 26, 1995
    Date of Patent: April 15, 1997
    Assignee: Nalco Chemical Company
    Inventors: Kristine S. Salmen, Pek L. Choo, David A. Picco, Michio Kobayashi