Patents Represented by Attorney, Agent or Law Firm Janet E. Hasak
  • Patent number: 4376102
    Abstract: Acidic gases containing carbon dioxide are removed from a normally gaseous mixture by absorbing CO.sub.2 from the gaseous mixture with an aqueous solution comprising a basic alkali metal salt or hydroxide and an activator or promoter system for the salt or hydroxide which contains (i) at least one diaminoalcohol of the formula:H.sub.2 N--(CH.sub.2).sub.4 --NRR'wherein R and R' each independently represent a C.sub.1 -C.sub.6 alkyl group and either R or R' or both R and R' have a pendant hydroxyl group, and (ii) an amino acid, and desorbing at least partially the absorbed CO.sub.2 from the aqueous solution.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: March 8, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventors: Warren A. Thaler, Guido Sartori, Chang J. Kim
  • Patent number: 4368267
    Abstract: A process is disclosed for the epoxidation of lower .alpha.-olefins dienes or vinyl aromatic compounds by contacting said compounds, under aerobic conditions in the presence of microorganisms, genetically engineered organisms thereof or enzyme preparations derived from said microorganisms. The microorganisms, genetically engineered organisms, or enzyme preparations derived therefrom are preferably those microorganisms which are known as methylotrophs particularly those which have previously grown under aerobic conditions in a nutrient medium containing methane.
    Type: Grant
    Filed: February 6, 1980
    Date of Patent: January 11, 1983
    Assignee: Exxon Research and Engineering Co.
    Inventors: Ching-Tsang Hou, Ramesh N. Patel, Allen I. Laskin
  • Patent number: 4344863
    Abstract: The foam in acid gas scrubbing solutions created during an acid gas scrubbing process is reduced or eliminated by the addition of certain polyoxyethylene polyoxypropylene block cpolymers as defoaming agents. The defoaming agents are particularly effective when the acid gas scrubbing solution contains an amine having a large hydrophobic moiety.
    Type: Grant
    Filed: December 21, 1979
    Date of Patent: August 17, 1982
    Assignee: Exxon Research & Engineering Co.
    Inventors: Max L. Robbins, Edwin R. Ernst
  • Patent number: 4310356
    Abstract: In an improved process for printing newsprint paper with a light-weight keyless printing press system the mineral oil ink standardly used is replaced by an aqueous newsprint ink having a total solids content of about 13-80% and containing about 2-30% of a colorant consisting of a pigment and/or dye, about 3-60% of a dispersed starch, and water to total 100%, wherein the percentages are by weight based on total weight of the ink. The ink may optionally contain a viscosity stabilizer if necessary to prevent retrogradation of the starch or a thickener. In a preferred embodiment the pigment is carbon black and the starch is a dextrin or waxy fluidity starch.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: January 12, 1982
    Assignees: National Starch and Chemical Corporation, Synres Chemical Corporation
    Inventors: Paolo C. Trubiano, Aaron Y. Cohen
  • Patent number: 4284572
    Abstract: Copolymerizable blocked isocyanate diols are prepared by reacting a blocking agent with an isocyanate group of an organic diisocyanate under controlled conditions, thereby forming a blocked isocyanate group, and reacting the second isocyanate group in a subsequent step with the amine portion of a selected amine diol under anhydrous conditions. The resultant products are used to prepare self-crosslinkable, linear polyurethanes of high molecular weight.
    Type: Grant
    Filed: December 15, 1978
    Date of Patent: August 18, 1981
    Assignee: National Starch and Chemical Corporation
    Inventors: Henry Stanley, Dilip K. Ray-Chaudhuri
  • Patent number: 4283525
    Abstract: In an improved process for preparing discrete particles from solution polymers in which water and neutralizing agent are added to the polymer to form a suspension, the organic solvent is removed therefrom, and the particles are collected by filtration, washing and drying, the suspension is formed by co-feeding the flowable polymer and the aqueous phase containing neutralizing agent into a reactor vessel under specified conditions; stirring the reactants; and discharging the resultant suspension from the reactor vessel, with all steps being carried out in a continuous manner. In one embodiment of the process, additional neutralizing agent, which is preferably sodium hydroxide, is added to the suspension during removal of the solvent therefrom.
    Type: Grant
    Filed: February 19, 1980
    Date of Patent: August 11, 1981
    Assignee: National Starch and Chemical Corporation
    Inventor: Krishna K. Rao
  • Patent number: 4273760
    Abstract: Hair conditioning shampoo compositions are described containing cationic polymers, anionic surfactants and optional nonionic surfactants. The shampoo compositions deposit the cationic polymer on the hair while the hair is washed using the shampoo, rendering the hair to be more manageable.
    Type: Grant
    Filed: September 14, 1979
    Date of Patent: June 16, 1981
    Assignee: National Starch and Chemical Corporation
    Inventors: F. Theodore Koehler, Albert L. Micchelli, Frank A. Nowak, Jr.
  • Patent number: 4272557
    Abstract: A gelatin dessert prepared from a dessert powder containing gelatin, sugar and optionally flavor and color is improved by adding to the powder from about 0.5 to 5%, by weight, of guar gum, based on the weight of the powder. The guar gum imparts low-temperature stable properties to the gelatin dessert without substantially adversely affecting the physical appearance and texture thereof.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: June 9, 1981
    Assignee: National Starch and Chemical Corporation
    Inventor: Bernard H. Nappen
  • Patent number: 4242488
    Abstract: A modified polyurethane adhesive composition characterized by its improved viscosity and high initial bond strength contains an isocyanate-terminated prepolymer or a fully reacted polyurethane and a carbamate ester which is compatible and not reactive with the prepolymer or polyurethane. The resultant adhesive is suitable for laminating many types of substrates. In a preferred embodiment the prepolymer is employed with the carbamate ester in a reactive hot-melt adhesive for use in bonding flexible substrates.
    Type: Grant
    Filed: May 9, 1979
    Date of Patent: December 30, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Henry Stanley, Dilip K. Ray-Chaudhuri
  • Patent number: 4229489
    Abstract: A cold-water dispersible, modified starch characterized by forming a gel having a Bloom strength of at least 50 grams is prepared by reacting a tapioca starch with a crosslinking agent to within defined Brabender viscosity limits; converting the crosslinked starch in a sufficient amount to provide the modified starch with gelling properties; and drum-drying the crosslinked and converted starch to obtain the modified starch product. The gelling instant starch thus prepared is particularly useful in food systems of the type which gel upon standing, such as pie filling, jellies, and puddings.
    Type: Grant
    Filed: May 29, 1979
    Date of Patent: October 21, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Chung W. Chiu, Morton W. Rutenberg
  • Patent number: 4228199
    Abstract: A cold-water dispersible, modified starch characterized by forming a gel having a Bloom strength of at least 60 grams is prepared by reacting a potato starch with a crosslinking agent to within defined Brabender viscosity limits sufficient to provide the modified starch with gelling properties and drum-drying the crosslinked starch to obtain the modified starch product. The starch may be optionally converted to a fluidity starch either before or after the crosslinking step and prior to drum drying. The gelling instant starch thus prepared is particularly useful in food systems of the type which gel upon standing, such as pie fillings, jellies, and puddings.
    Type: Grant
    Filed: July 5, 1979
    Date of Patent: October 14, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Chung W. Chiu, Morton W. Rutenberg
  • Patent number: 4216310
    Abstract: Starch is phosphorylated by a virtually pollution-free, continuous process whereby an aqueous reagent solution of a tripolyphosphate, orthophosphate or pyrophosphate salt or a mixture thereof is sprayed onto a moist starch cake on a rotary vacuum filter in an amount sufficient to achieve efficient impregnation of the starch cake without losing significant levels of salt to the effluent. In a preferred embodiment, the reagent solution contains alkali metal tripolyphosphate salt and is obtained by diluting a concentrated solution thereof. The thus-impregnated starch is subsequently dried and heat-reacted by known procedures to produce an orthophosphate starch monoester.
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: August 5, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Otto B. Wurzburg, Wadym Jarowenko, Roger W. Rubens, Jayant K. Patel
  • Patent number: 4207355
    Abstract: A cold-water dispersible, modified starch characterized by forming a gel having a Bloom strength of at least 45 grams is prepared by converting a tapioca starch to a water fluidity of about 10 to 63, preferably 20 to 40; reacting the starch with a crosslinking agent to within defined Brabender viscosity limits sufficient to provide the modified starch with gelling properties; and drum-drying the converted, crosslinked starch to obtain the modified starch product. The gelling instant starch thus prepared is particularly useful in food systems of the type which gel upon standing, such as pie fillings, jellies, and puddings.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: June 10, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Chung-Wai Chiu, Morton W. Rutenberg
  • Patent number: 4191786
    Abstract: In an improved process for preparing water-dispersible chocolate liquor, melted chocolate liquor is mixed with starch and water in selected proportions, and the resulting mixture is then passed through an extruder at an elevated pressure and temperature for a period of time sufficient to partially hydrate the starch and finally extruded through an orifice. The product is preferably obtained in powder form and may be used in many applications such as dry food mixes.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: March 4, 1980
    Assignee: National Starch and Chemical Corporation
    Inventors: Bernard H. Nappen, Nicholas G. Marotta
  • Patent number: 4182823
    Abstract: An adhesive composition based on 2-cyanoacrylate esters contains as an anionic polymerization inhibitor an acid chelate formed of boric acid or a derivative thereof and a selected polyhydroxy compound. The chelate is conveniently formed in situ in the 2-cyanoacrylate ester, but may also be prepared separately and added to the ester directly. An exemplary acid chelate used as stabilizer is prepared from boric acid and pyrogallol. The resulting stabilized adhesive compositions have a rapid cure rate and may be used on a wide variety of substrates.
    Type: Grant
    Filed: August 18, 1978
    Date of Patent: January 8, 1980
    Assignee: National Starch and Chemical Corporation
    Inventor: Jules E. Schoenberg
  • Patent number: 4176108
    Abstract: An improved latex binder for nonwoven webs comprising an acrylate- and/or vinyl acetate-based copolymer containing 0.1-10% by weight of 2-hydroxyethyl or 2-hydroxypropyl acrylate or methacrylate is prepared by employing in combination with the copolymer 0.2-10% by weight, on latex solids, of anionic surfactant and 0.3-15% by weight, on latex solids, of nonionic surfactant in selected relative proportions and by adding to the copolymer 1-40% by weight, on latex solids, of a water-soluble salt. The resultant binder is characterized by being stable to coagulation at room temperature but coagulable at a temperature between 40.degree. and 85.degree. C. In the preparation of nonwoven fiber material, a nonwoven web is impregnated with the copolymer latex binder, heated to a temperature of within 40.degree. and 85.degree. C. sufficient to coagulate the binder within the web and thus prevent migration, and finally dried to form a chemically bonded, nonwoven fiber material in sheet form.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: November 27, 1979
    Assignee: National Starch and Chemical Corporation
    Inventors: Ronald J. Caimi, Walter F. Schlauch
  • Patent number: 4167621
    Abstract: Starch ether derivatives are prepared by reacting a starch base with about 0.5-100% by weight of a neutralized alkyl ester of 3-chloro-2-sulfopropionic acid, based on dry starch, and then isolating the resultant starch derivative. The 2-sulfo-2-carboxyethyl starch ethers thus prepared may be utilized in many applications, and are particularly useful as wet-end additives in paper manufacturing at low pH.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: September 11, 1979
    Assignee: National Starch and Chemical Corporation
    Inventor: Martin M. Tessler
  • Patent number: 4166173
    Abstract: Starch is phosphorylated by an improved pollution-free process which involves forming a reagent solution of an alkali metal tripolyphosphate salt in water having 20- 36% by weight of the salt dissolved therein, forming a starch cake containing no more than 45% by weight moisture, adding 2 - 30% by weight of the tripolyphosphate salt reagent solution to the starch cake, and drying and heat-reacting the thus-impregnated starch. In this process more efficient impregnation of the starch is achieved. The impregnation is preferably effected in a centrifuge.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: August 28, 1979
    Assignee: National Starch and Chemical Corporation
    Inventors: Otto B. Wurzburg, Wadym Jarowenko, Roger W. Rubens, Jayant K. Patel
  • Patent number: 4139693
    Abstract: Adhesive compositions having enhanced bond strength are obtained by mixing a monomeric ester of 2-cyanoacrylic acid with an anionic polymerization inhibitor and from 1 to 30 mmoles per kg. of adhesive of an adhesion promoter of the formula: ##STR1## wherein R' is hydrogen or an alkyl, aryl or cycloalkyl group having 1-10 carbon atoms. Such compositions may be used on a wide variety of substrates and are particularly useful on metals.
    Type: Grant
    Filed: March 29, 1978
    Date of Patent: February 13, 1979
    Assignee: National Starch and Chemical Corporation
    Inventor: Jules E. Schoenberg