Abstract: A soil-repellent treatment method for articles based on woven cotton, wherein an amphiphilic soil-repellent agent soluble or dispersible in the treatment medium is deposited on the article during one or more washing, rinsing and/or softening or dying steps, is disclosed. Said soil-repellent agent comprises at least one unit with a function (FAd) capable of being absorbed onto the surface of the cotton by electrostatic interaction; and at least one hydrophobic unit (MH) capayble of configuring said agent at the cotton/water interface. A soil-repellent agent comprising at least one unit with a cationic function (MC) capable of being absorbed onto the surface of the cotton, and the counter-ion thereof, as well as at least one hydrophobic unit (MH) containing at least four carbon atom chemically bonded to the unit having said cationic function (MC) via an oligomeric, polymeric or copolymeric vinyl alcohol chain, is also disclosed.

Abstract: The subject-matter of the present invention is a process of use in perfluoroalkylation and a reactant for making use of this process. This process is defined in that it comprises a stage in which a material of formula RfH and a base (or a species capable of generating a base) are brought into contact, in a polar and anhydrous medium, with a substrate carrying at least one electrophilic functional group. Application to organic synthesis.

Abstract: The present invention relates to a drilling fluid comprising cellulose nanofibrils comprising at least 80% of cells with primary walls and charged with carboxylic acids and with acidic polysaccharides, alone or as a mixture. This additive, alone, gives the drilling fluid shear-thinning properties and is stable up to temperatures of about 180° C.

Abstract: The invention relates to a composition based on a grafted metal oxide, its preparation and its use in a process of polymerization by opening oxygenated rings such as alkyl oxides, cyclic esters or cyclic carbonates. The composition comprises a support chosen from the group of metal oxides capable of containing hydroxyl functions, onto which is grafted a group of formula (1) —M(OR)n in which M is an element chosen from scandium, zirconium, hafnium, niobium, tantalum, rare-earth metals and actinides, R is an organic group and n is an integer greater than or equal to 1. The composition is prepared by forming a suspension of the abovementioned support and then placing in contact and reacting this suspension with a compound of formula (2) M(OR)n+1 in which M, R and n are defined as above.

Abstract: The invention concerns buccodental formulation characterized in that it comprises at least a thickening agent comprising cellulose nanofibrils, said cellulose nanofibrils being substantially amorphous, having a crystallinity index not more than 50%. The invention also concerns said cellulose nanofibrils as thickening agent and/or flavour enhancer in buccodental formulations.

Abstract: The process for simultaneously molding and rendering water-repellent molded components made of concrete, mortar, cement or the like consists, before pouring the concrete, cement or the like, in covering the interior of the mold with a composition comprising a resin which is a silicone copolymer in the absence of crosslinking agent of hydrolysable silane type and of curing catalyst in the composition. Molded component thus obtained and compositions for removing from the mold and rendering water-repellent.

Abstract: The present invention relates to compositions comprising essentially amorphous cellulose nanofibrils, at least one additive chosen from carboxycellulose with a degree of substitution of more than 0.95, a natural polysaccharide, a polyol, and optionally at least one co-additive, the content of additive and of optional co-additive being less than or equal to 30% by weight relative to the weight of nanofibrils and of additive and of optional co-additive. Similarly, a subject of the invention is a process for preparing such compositions, which consists in adding the additive and the optional co-additive to a suspension of essentially amorphous nanofibrils, and then in drying the suspension thus supplemented. The compositions obtained are readily redispersable and conserve their initial rheological properties.

Abstract: The present invention relates to a process for removing fatty substances. According to this process, the following steps are carried out:1) at least a first degreasing operation is carried out on the article to be treated, in the presence of a solvent mixture comprising at least one compound (a) chosen from C1-C4 dialkyl esters of at least one C4-C6 aliphatic diacid, and at least one compound (b) which is miscible in the compound (a) and which at least partially dissolves the fatty substance contaminating the article, 2) at least a second degreasing operation is optionally carried out, in the presence of a solvent mixture comprising at least one compound (a) and at least one compound (b) as defined above, with a compound (a)/compound (b) volume ratio of greater than or equal to 1, 3) a third degreasing operation is carried out in the presence of compound (a), 4) the article thus treated is rinsed with water.

Abstract: A water-soluble or water-dispersible copolymer comprising: at least one polyoxyalkylene (POA) unit; and at least one sulfonated polyamide (PAS) unit; the quantity of SO3M functions, expressed as the mass of SO3− function, in said (PAS) unit or units is such that it represents at least 0.1% of the total mass of said copolymer; the total (POA) units/total (PAS) units mass ratio is 95/5 to 30/70/ the number of amine functions —NH2 present in said copolymer is at most 80 milliequivalents per kilogram of copolymer; the number of carboxyl functions —COOH present in said copolymer is at least 80 milliequivalents, preferably at least 100 milliequivalents per kilogram of copolymers.

Abstract: Water-redispersible granules prepared by drying a water-in-oil emulsion including at least one active material in the form of a hydrophobic liquid; at least one water-soluble compound capable of forming, during the drying process, a solid continuous film in which droplets of the hydrophobic active material are trapped; water; and at least one main surfactant with a binary water-surfactant phase diagram comprising an isotropic phase which is fluid at 25° C. up to a surfactant concentration of at least 50% by weight, followed at higher concentrations by a hexagonal, cubic or lamellar liquid crystal phase that is stable at least up to 65° C.

Abstract: The invention concerns a method of sulphonation characterised in that it consists in contacting a nucleophile whose nucleophilic atom is a nitrogen atom with a reagent comprising by successive or simultaneous addition: a heavy sulphonyl halide (i.e. whose atomic number is not less than that of chlorine), advantageously suphonyl chloride; and an organic base both not capable of alkylation and lipid soluble; and the organic part of said sulphonyl is perfluorinated on the carbon carried by the sulphur. The invention is applicable to organic synthesis.

Abstract: The present invention is concerned with a titanium-, -and alkaline- or alkaline-earth-based compound, processes for the preparation thereof, and use thereof as a coloring pigment. The product of the invention is characterized in that it corresponds to formula (1) MxCeyTizOt wherein M represents an alkaline or an alkaline-earth, and x, y and z satisfy the following equations: 0.1≦y/z≦1.5, 1≦(x+z)/y≦15, x+y+z=1, (x+3y=4z)/2≦t≦(x+4y+4z)/2.

Abstract: The polyorganosiloxane composition resulting in a silicone elastomer of high thermal conductivity, which can reach and even exceed 1.2 W/m.K, the elastomer retaining an elongation at break of greater than 30%, comprises at least one functional polyorganosiloxane which crosslinks by a polyaddition or polycondensation reaction or by the radical route, optionally a polyorganohydrosiloxane, a catalyst, optionally a reinforcing filler and a filler intended to increase the thermal conductivity which is present in the composition in the proportion of 35 to 70% by volume with respect to the total composition, this filler comprising at least two groups of particles of very different mean diameters, a first group having a mean particle diameter of between 10 and 40 mm, present in a predominant amount in the filler, and a second group having a mean particle diameter of less than 5 mm.

Abstract: The present invention relates to multifunctionalized alkoxy, the alkoxy functionality Y being introduced onto a suitable polyhydroorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the functionality W by a hydrosilylation reaction from the olefinic compound form which W derives. The multifunctionalized alkoxy polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions and as silica covering agents in silicone compositions containing fillers.

Abstract: The present invention relates to a process and a reagent useful for the synthesis of sulphanilide which is perhalogenated on the carbon borne by the sulphur atom of the sulphanilide function. This persulphonylation process is characterized in that it comprises a step of placing a nucleophile, whose nucleophilic atom is a nitrogen, in contact with a reagent comprising, for successive or simultaneous addition, a heavy halide of sulphonyl, advantageously sulphonyl chloride, and an organic base comprising a trivalent atom from column V whose lone pair is conjugated directly or indirectly to a bond, and in that the organic part of the said sulphonyl is perhalogenated, advantageously perfluorinated, on the carbon borne by the sulphur. Application to the synthesis of intermediates for organic chemistry.

Abstract: The invention concerns a novel method for making paper based on sheet cellulose fibre, wherein a novel retention system comprising a suspension of bentonite and a cationic galactomannan is used to improve in particular the retention of the incorporated mineral fillers. The invention also concerns a method for making paper using a retention system which substantially improves draining.

Abstract: The invention concerns novel compositions containing at least a polyorganosiloxane (A) with crosslinkable functional groups, stable for use and storing, characterized in that said compositions contain at least a stabilizing amino agent consisting of a polyorganosiloxane (B) functionalised with at least an amino group, and a priming system for hardening by radiation, particularly UV radiation, the polyorganosiloxane (B) being miscible with the polyorganosiloxane (A). In general these stable and cross-linkable compositions are in liquid form and homogeneous.

Abstract: Water-redispersible granules including at least one active material in the form of a hydrophobic liquid, at least one non-ionic surfactant selected from polyoxyalkylene derivatives, and at least one water-soluble compound selected from polyelectrolytes belonging to the weak polyacid family are disclosed. A method for prepang such granules by preparing an aqueous emulsion of at least one active material, at least one non-ionic surfactant and at least one water-soluble compound, and drying the resulting emulsion, is also disclosed.

Abstract: The invention concerns a method for treating an aqueous solution derived from sluicing of crude mononitrated or dinitrated aromatic compounds obtained by nitration of the corresponding aromatic compounds, consisting in: (a) contacting said aqueous solution with said aromatic compound thereby obtaining an aqueous phase and an organic phase; (b) recycling said organic phase in the nitration process; (c) distilling said aqueous phase; (d) recycling the resulting concentrated acid solution in the nitration process; (e) recycling or eliminating the recuperated water after distillation.

Abstract: The invention concerns a method for obtaining alkylmonohydrogenohalogenosilanes (AHHS), for example Me2HSiCl.Said AHHS are prepared by redistribution from MeHSiCl2 and Me3HSiCl in the presence of a catalyst such as AlCl3, which can start a parasitic disproportionation which affects the AHHS produced. In order to avoid this, the method consists in using an inhibitor which neutralizes AlCl3 after redistribution, The problem which still prevails and on which the present invention is based is related to the fact that during distillation, which aims at separating the required AHHS, the latter are again subjected to the parasitic disproportionation.