Abstract: Polyethylene compositions having improved properties are provided. In one aspect, a polyethylene composition having a long chain branching index (g?avg) of 0.5 to 0.9; a Melt Flow Rate (MFR) of greater than (49.011×MI(?0.4304)), where MI is Melt Index; and a weight average molecular weight to number average molecular weight (Mw/Mn) of less than or equal to 4.6 is provided.
Type:
Grant
Filed:
October 9, 2008
Date of Patent:
December 11, 2012
Assignee:
Univation Technologies, LLC
Inventors:
Mark G. Goode, Rainer Kolb, Chi-I Kuo, Tae Hoon Kwalk, Dongming Li, Ching-Tai Lue, Francis C. Rix, Daniel P. Zilker, Jr.
Abstract: A method of performing a polymerization reaction in a gas phase polymerization reactor to produce a bimodal polymer while controlling activity of a bimodal polymerization catalyst composition in the reactor by controlling concentration of at least one induced condensing agent (‘ICA’) in the reactor is provided. In some embodiments, the ICA is isopentane (or another hydrocarbon compound) and the bimodal catalyst composition includes a Group 15 and metal containing catalyst compound (or other HMW catalyst for catalyzing polymerization of a high molecular weight fraction of the product), and a metallocene catalyst compound (or other LMW catalyst for catalyzing polymerization of a low molecular weight fraction of the product).
Type:
Grant
Filed:
December 17, 2008
Date of Patent:
November 27, 2012
Assignee:
Univation Technologies, LLC
Inventors:
Bruce J. Savatsky, John H. Oskam, Mark W. Blood, Mark B. Davis, Douglas H. Jackson, Timothy R. Lynn, Daniel P. Zilker, Jr.
Abstract: A method and apparatus are disclosed for controlling product discharge from a fluidized bed reactor and for minimizing the loss of the unreacted monomer in the fluidizing gas upon removing the solid polymer product from the reactor. The method and apparatus utilize at least one detector in the product tank or its vent line and a control system in communication with the detector and the product tank fill valve, along with certain algorithms, to adjust by an iterative process, the product discharge time, thereby maximizing resin fill in the product tank and minimizing the lost reactor gas volume.
Type:
Grant
Filed:
February 27, 2009
Date of Patent:
October 23, 2012
Assignee:
Univation Technologies, LLC
Inventors:
John R. Parrish, Jeffrey B. Drabish, Oscar M. Longoria, Jr., James L. Swecker, II