Abstract: 2,5-dihydroxyterephthalic acid is produced in high yields and high purity from 2,5-dihaloterephthalic acid by contact with a copper source and a ligand that coordinates to copper under basic conditions.
Abstract: Multidentate phosphite ligands are disclosed for use in reactions such as hydrocyanation and isomerization. The catalyst compositions made therefrom and the various catalytic processes which employ such multidentate phosphite ligands are also disclosed. In particular, the ligands have heteroatom-containing substituents on the carbon attached to the ortho position of the terminal phenol group.
Type:
Grant
Filed:
April 9, 2002
Date of Patent:
November 2, 2004
Assignee:
Invista North America S.a.r.l.
Inventors:
Kristina Ann Kreutzer, Wilson Tam, J. Michael Garner, John Ronald Boyles
Abstract: Disclosed is an invention concerning triazolyloligosaccharides, oligosaccharides wherein the bonding between the saccharide groups is via a triazole group and methods for their preparation.
Abstract: Process for preparing a 2,3-dihaloperfluoropropionyl halide wherein an alkali metal chloride, bromide or iodide is contacted with a 3-haloperfluoropropene oxide in admixture in an inert liquid reaction medium.
Type:
Grant
Filed:
June 25, 1992
Date of Patent:
September 17, 1996
Assignee:
The Dow Chemical Company
Inventors:
Kevin P. Darst, Bobby R. Ezzell, Nobuyuki Ishibe
Abstract: A halogenated ester is prepared by addition of a halogenated nucleophile to a diester at a temperature less than 15.degree. C. but greater than -25.degree. C.
Abstract: A process for preparing a halogenated polycarbonate wherein phenolic-terminated, halogenated carbonate oligomers are prepared in the presence of a coupling catalyst, and are then condensed by contact with a carbonate precursor.
Abstract: A process for preparing halogenated polycarbonate wherein the total amount of base, the end pH of the aqueous phase, and the amount of coupling catalyst employed in the reaction are controlled to selected levels.
Type:
Grant
Filed:
August 8, 1991
Date of Patent:
May 18, 1993
Assignee:
The Dow Chemical Company
Inventors:
Sarat Munjal, Clark J. Cummings, Che-I Kao
Abstract: A process for the preparation of fluorinated carbonyl compounds from a fluorinated methyl or ethyl ether using tin tetrachloride as a catalyst. The fluorinated ether is contacted with the tin tetrachloride catalyst at a temperature between 0.degree. C. and 250.degree. C.
Abstract: A process for preparing polycarbonate wherein a chain terminator is added to the reaction mixture after substantial reaction of a carbonate precursor, a coupling catalyst is added to the reaction mixture after substantial reaction of the chain terminator, and base is added to the reaction mixture after reaction mixture after substantial reaction of the chain terminator in an amount sufficient to give a negative chloroformate test.
Type:
Grant
Filed:
July 2, 1991
Date of Patent:
April 6, 1993
Assignee:
The Dow Chemical Company
Inventors:
Sarat Munjal, Thomas M. Wardlow, Andrew F. Hall
Abstract: A composition possessing a desirably high balance of resistance to thermal deformation and to chemical solvents, and reduced notch sensitivity, prepared from a polycarbonate having a glass transition temperature in excess of at least 165.degree. C., an aromatic polyester, a polyphenylene ether, and an elastomeric impact modifier.
Abstract: A polycarbonate pellet having a size between 200 and 1,500 microns, not inclusive, is produced by extruding molten polycarbonate through a die and cutting such extrudate with a die face cutter.
Abstract: Thermoplastic molding composition containing a polycarbonate, a polyester, an olefin/carbon monoxide copolymer, a mono-alkenyl aromatic/diene block copolymer and a grafted core-shell elastomer.
Type:
Grant
Filed:
August 21, 1990
Date of Patent:
June 23, 1992
Assignee:
The Dow Chemical Company
Inventors:
Michael K. Laughner, Brenda N. Herron, Clive P. Bosnyak
Abstract: A process of blow molding, and compositions useful in the process. The articles are blow molded from compositions formed from thermoplastic polymeric material, a fluorinated olefinic polymer or copolymer and, optionally, an elastomeric impact modifier.
Abstract: Filled thermoplastic molding composition containing a polycarbonate, a polyester, an olefin/carbon monoxide copolymer, a grafted core-shell elastomer, and a talc filler.
Type:
Grant
Filed:
August 21, 1990
Date of Patent:
January 21, 1992
Assignee:
The Dow Chemical Company
Inventors:
Chai-Jing Chou, Gregory M. Smith, Hani Farah
Abstract: A halogenated copolycarbonate, which contains reduced levels of phenolic end groups and end groups which result from side reactions of process chemicals with the copolycarbonate chain, has improved resistance to the degradation-inducing effects of such end groups and has improved washability.
Abstract: A polycarbonate composition, and process for making same, wherein the monocarbonate and dicarbonate content is eliminated or limited to negligibly low levels by withholding introduction of chain terminator to the reaction mixture until the reaction of dihydroxy and carbonic acid derivative starting materials has run substantially to completion.
Type:
Grant
Filed:
November 16, 1988
Date of Patent:
July 3, 1990
Assignee:
The Dow Chemical Company
Inventors:
Sarat Munjal, Che I. Kao, Jimmy D. Allen
Abstract: A polycarbonate blend of good impact strength, solvent resistance and weldline properties is prepared by admixing with polycarbonate a grafted olefin/carbon monoxide copolymer and, optionally, a toughening agent such as a rubber.
Abstract: A polycarbonate blend having both improved solvent resistance and improved impact strength comprising in admixture a polycarbonate, a styrenic thermoplastic resin, a grafted olefin/carbon monoxide copolymer and, optionally, a rubber toughening agent.
Type:
Grant
Filed:
May 4, 1989
Date of Patent:
May 29, 1990
Assignee:
The Dow Chemical Company
Inventors:
Michael K. Laughner, Gerald M. Lancaster, Yun C. Sun