Abstract: Disclosed is a free radical polymerization process for the preparation of a thermoplastic resin or resins comprising heating a mixture of a free radical initiator, a stable free radical agent, and at least one polymerizable monomer compound to form a thermoplastic resin or resins with a high monomer to polymer conversion; cooling said mixture; optionally isolating the thermoplastic resin or resins; and optionally washing and drying thermoplastic resin or resins.Related free radical processes are also disclosed for the preparation of mixtures and block copolymer thermoplastic resins. Resins prepared by the disclosed processes possesses a narrow polydispersity and a modality that is controlled by the selection of a free radical initiator and stable free radical agent addition step or steps.

Abstract: A process for the preparation of toner compositions comprising: forming a mixture comprised of at least one free radical reactive monomer, a colorant, a stabilizer compound containing a stable free radical reactive group, and a liquid vehicle; and heating the mixture from about 75.degree. to about 200.degree. C. to effect polymerization of said monomer, wherein there results stabilized core resin particles containing said colorant and wherein said stabilized core particles are stabilized by said stable free radical reactive stabilizer compounds being bonded directly to the core particles.

Abstract: A process for the preparation of pigmented toner compositions comprising: a) forming at a first temperature, a first melt mixture comprised of a partially crosslinked thermoplastic resin, pigment, optionally a wax, and optional additives, wherein the partially crosslinked thermoplastic resin is comprised of a mixture of crosslinked resin macrogel particles, crosslinked resin microgel particles, and uncrosslinked resin; and b) melt mixing at a second temperature, the first melt mixture to form a second mixture, wherein the macrogel particles are partially converted into microgel particles, and wherein the second temperature is less than or equal to the first temperature.

Abstract: A polymerization process comprising: heating a mixture comprised of a free radical initiator, a stable free radical agent, at least one polymerizable monomer compound, and optionally a solvent, to form a polymer with a high monomer to polymer conversion and a narrow polydispersity, wherein said polymer is comprised of a covalently bound free radical initiator fragment at one end and a covalently bound stable free radical compound at the other end of the polymer, and wherein said stable free radical agent has high thermal, acidic, and photochemical stability.

Abstract: Disclosed is a process for enhancing xerographic developer tribo product longevity comprising providing developer particles comprised of a toner comprised of at least one resin, pigment, charge additive, surface additive particles, a charge control agent retention additive or compound, and a carrier.

Abstract: A process for preparing a liquid developer composition comprising: a) forming a melt mixture comprised of a polymer resin or resins, a colorant, a charge director additive, and a hydrocarbon liquid carrier, to obtain a first suspension of colored polymeric particles with an area average diameter of from about 2 to about 100 microns; b) dispersing said first suspension in a supercritical fluid medium and thereafter continuously feeding the resultant dispersion to a liquid fluidizing means under pressure to obtain a second suspension comprising a supercritical fluid and liquid developer mixture containing colored polymeric particles with an area average diameter of from about 0.1 to about 10 microns; and c) reducing the pressure to evaporate, and optionally recovering, the supercritical fluid medium from said second suspension, wherein there results a liquid developer mixture containing colored polymeric particles with an area average diameter of less than about 3.

Abstract: Disclosed is a negatively charged toner composition comprised of resin particles, pigment particles, optional surface additives, and a hydroxy naphthoic acid charge enhancing additive of the following formula: ##STR1## wherein X is halogen, hydroxy, or hydrogen, M is hydrogen, an alkaline earth, an alkali metal, or NR.sub.4 wherein R is alkyl with from 1 to 5 carbon atoms, and n is the number 1 or 2.

Abstract: A process for preparing ultrafine pigment dispersions comprising providing a solubilized mixture of pigment-Lewis acid complex and an aprotic organic solvent; precipitating the resulting solubilized complex into a protic solvent thereby forming a dispersion of ultrafine pigment particles; removing the aprotic and protic solvents to afford a wet cake containing finely divided pigment particles; optionally neutralizing and washing the wet cake particles; and redispersing the resulting ultrafine pigment particles in an aqueous solution, an organic solvent, or mixtures thereof, and a binder resin to form an ultrafine pigment and binder resin dispersion.

Abstract: A carrier composition comprised of a core with a coating thereover comprised of a composite comprised of a conductive aromatic or heteroaromatic polymer comprised of a monomer or monomers selected from the group consisting of pyrrole, indole, thiophene, thianaphthene, indene, azulene and ring pendant substitutent derivatives thereof; and a fluoropolymer host resin.

Abstract: A composite metal oxide charge enhancing additive composition comprised of a first metal oxide forming a core particle, and a second metal oxide forming an outer layer on the first metal oxide core particle of the formula [(M.sup.1 O.sub.n)x]-[(M.sup.2 O.sub.n).sub.y ] wherein M.sup.1 represents the first metal oxide metal, M.sup.2 represents the second metal oxide metal, n is an integer representing the number of oxygen atoms and is determined by the valence of the metal M to which the oxygen atoms are bonded, x and y represent the relative molar ratios of the first and second metal oxides, and wherein M.sup.1 is different from M.sup.2.Another embodiment is a composite metal oxide toner charge enhancing additive composition comprising an organosilane outer layer or coating covalently bonded on the outer surface of the second metal oxide layer of the formula {(M.sup.1 O.sub.n).sub.x }-{M.sup.2 O.sub.n).sub.y }-{Si R.sub.4-n).sub.z } wherein (Si R.sub.4-n).sub.

Abstract: A polymerization process for the preparation of homopolymeric acrylate containing thermoplastic resin or resins comprising heating a mixture comprised of a free radical initiator, an oxo nitroxide stable free radical agent, at least one polymerizable acrylate monomer compound, and optionally a solvent, to form a homopolymeric acrylate containing thermoplastic resin or resins with a high monomer to polymer conversion and a narrow polydispersity.

Abstract: Disclosed is a process for the preparation of chloroindium phthalocyanine which comprises heating a mixture of indium trichloride and ortho-phthalodinitrile in a mixture of solvents comprised of a dialkylaminoalkanol and a high boiling second solvent; and cooling the mixture to enable precipitation.

Abstract: Disclosed is a process for forming thin films of pigment compounds, comprising providing a solubilized pigment-Lewis acid complex contained in an aprotic organic solvent system and coating the solubilized pigment-Lewis acid complex containing solvent system on a substrate.

Abstract: Disclosed is a free radical polymerization process for the preparation of a thermoplastic resin or resins comprising heating a mixture of a free radical initiator, a stable free radical agent, and at least one polymerizable monomer compound to form a thermoplastic resin or resins with a high monomer to polymer conversion; cooling said mixture; optionally isolating the thermoplastic resin or resins; and optionally washing and drying thermoplastic resin or resins.Related free radical processes are also disclosed for the preparation of mixtures and block copolymer thermoplastic resins. Resins prepared by the disclosed processes possesses a narrow polydispersity and a modality that is controlled by the selection of a free radical initiator and stable free radical agent addition step or steps.

Abstract: A reactive melt mixing process for preparing toner resin, comprising: melting a reactive base resin, thereby forming a polymer melt; adding to said polymer melt a free radical initiator compound and optionally a vinyl monomer compound to form a second melt; and heating and mixing under high shear said second melt with optional addition of a vinyl monomer compound to form a partially crosslinked and partially gelled toner resin.

Abstract: A process for fusing toner images to a substrate comprising: providing a fusing member having a fusing surface; heating said fuser member to an elevated temperature to fuse toner to said substrate; applying directly to said fusing surface a fuser release agent oil blend composition wherein volatile emissions arising from the fuser release agent oil blend are minimized or eliminated.

Abstract: Disclosed is a process for preparing a liquid or dry electrophotographic developer comprising: (a) forming a melt mixture comprised of a polymer resin or resins, a colorant, a charge director, and a nonaqueous solvent to obtain a first suspension of colored polymeric particles with a volume average diameter of from about 5 to about 100 microns; and (b) homogenizing with a dairy piston homogenizer said first suspension under pressure of from about 100 to about 500 Bars to obtain a second suspension containing colored polymeric particles with a volume average diameter of from about 0.1 to about 5 microns.

Abstract: A positive-working electrostatic liquid developer consisting essentially of (A) a nonpolar liquid having a Kauri-butanol value of less than 30, present in a major amount;(B) thermoplastic resin particles having dispersed therein a quaternary ammonium compound which is substantially insoluble in the nonpolar liquid and is represented by the general formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 may be the same or different and are hydrogen, alkyl of 1 to 40 carbon atoms, aryl of 6 to 30 carbon atoms, and any of the group R.sub.1, R.sub.2, R.sub.3, and R.sub.4 may be joined to form a 5 or 6 membered ring, and A.sup.- is an anion; and (C) a nonpolar liquid soluble ionic or zwitterionic charge director compound. The process of preparation of the electrostatic liquid developer is described. The liquid developers are useful in copying, color proofing including digital color proofing, lithographic printing plates and resists.

Abstract: A process for preparing silane metal oxides comprising reacting a metal oxide with an amine compound to form an amine metal oxide intermediate, and subsequently reacting said intermediate with a halosilane.

Abstract: A fuser member comprising a supporting substrate, and a outer layer comprised of an integral interpenetrating hybrid polymeric network comprised of a haloelastomer, a coupling agent, a functional polyorganosiloxane and a crosslinking agent.