Patents Represented by Attorney, Agent or Law Firm John M. Fernbacher
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Patent number: 7879138Abstract: Pressure swing adsorption process for the separation of a feed gas mixture comprising (a) providing a pressure swing adsorption system comprising one or more composite beds, each composite bed comprising adsorbent material disposed in two or more vessels in parallel flow configuration, each vessel having a feed end and a product end; (b) performing cyclic sequential steps comprising adsorption/make product, withdrawing gas at decreasing pressure from the composite bed, purging the composite bed, and introducing gas into the composite bed at increasing pressure; and (c) for any of the sequential steps, setting a flow rate or flow rates of one or more gases selected from the group consisting of gas introduced into or withdrawn from the feed end or ends of any of the two or more vessels and gas introduced into or withdrawn from the product end or ends of any of the two or more vessels.Type: GrantFiled: July 20, 2006Date of Patent: February 1, 2011Assignee: Air Products and Chemicals, Inc.Inventors: Sang Kook Lee, Justin David Bukowski, Carolyn Taylor Zelson, Mark Ephraim Levine
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Patent number: 7771519Abstract: Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and (d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.Type: GrantFiled: August 14, 2007Date of Patent: August 10, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Michael Francis Carolan, Christopher Francis Miller
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Patent number: 7717981Abstract: PSA process for oxygen production comprising (a) providing an adsorber having a first layer of adsorbent selective for water and a second layer of adsorbent selective for nitrogen, wherein the heat of adsorption of water on the adsorbent in the first layer is ?about 14 kcal/mole at water loadings ?about 0.05 to about 3 mmol per gram; (b) passing a feed gas comprising at least oxygen, nitrogen, and water successively through the first and second layers, adsorbing water in the first layer of adsorbent, and adsorbing nitrogen in the second layer of adsorbent, wherein the mass transfer coefficient of water in the first layer is in the range of about 125 to about 400 sec?1 and the superficial contact time of the feed gas in the first layer is between about 0.08 and about 0.50 sec; and (c) withdrawing a product enriched in oxygen from the adsorber.Type: GrantFiled: October 4, 2006Date of Patent: May 18, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Matthew James LaBuda, Timothy Christopher Golden, Roger Dean Whitley
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Patent number: 7651549Abstract: Process step in a pressure swing adsorption process using multiple parallel adsorbent beds operating in cyclic process steps to recover a less strongly adsorbable component from a feed gas mixture containing at least one less strongly adsorbable component and at least one more strongly adsorbable component, wherein each adsorbent bed has a feed end and a product end, wherein each bed is subjected to at least a feed/product step, one or more depressurization steps, a purge step in which a purge gas enriched in the less strongly adsorbable component is introduced into the product end of the bed and a purge effluent gas is withdrawn from the feed end of the bed, and one or more repressurization steps. The process step comprises introducing at least a portion of the purge effluent gas from a first bed into the feed end of a second adsorbent bed at any time other than during the feed/product step in the second adsorbent bed.Type: GrantFiled: June 13, 2006Date of Patent: January 26, 2010Assignee: Air Products and Chemicals, Inc.Inventor: Roger Dean Whitley
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Patent number: 7510601Abstract: Portable medical oxygen concentrator comprising an air separation system adapted to recover oxygen from air; a bottom platform and a shell having an outer wall, wherein the shell is detachably connected to the bottom platform, wherein the shell and bottom platform define an enclosed volume when the shell is connected to the bottom platform, and wherein the air separation system is disposed in the enclosed volume; and one or more rechargeable batteries detachably connected to the outer wall of the shell and adapted to provide power to drive the air separation system. The air separation system may comprises a pressure swing adsorption system having two or more adsorbent columns and a rotary valve for directing gas flow sequentially to, from, and among the columns. A base assembly attached to the bottom platform may be adapted to support the two or more adsorbent columns and the rotary valve.Type: GrantFiled: December 20, 2005Date of Patent: March 31, 2009Assignee: Air Products and Chemicals, Inc.Inventors: Roger Dean Whitley, Glenn Paul Wagner, Matthew James LaBuda, David R. Schiff, Peter D. Byar, Andrew M. Weiman, Seth GaleWyrick
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Patent number: 7473299Abstract: System for producing an oxygen-rich gas comprising (a) a primary gas mover including a first and a second compressor, wherein the primary gas mover is characterized by a weight Wp; (b) a drive motor adapted to drive the first and second compressors; (c) a rechargeable power supply characterized by a weight, Wb; and (d) a pressure/vacuum swing adsorption unit adapted to separate the pressurized feed air into an oxygen-rich product at a product flow rate Fp and an oxygen-depleted waste gas, wherein the adsorption unit comprises a plurality of adsorber beds containing an adsorbent and characterized by a total adsorbent weight Wa; and wherein the combined weight, Wt, of the adsorbent, the primary gas mover, and the rechargeable power supply is characterized by the expression 0.75 Fp<Wt<2.02 Fp where Fp is in liters per min (at 23° C. and 1 atma pressure), and Wa, Wp, and Wb are in pounds.Type: GrantFiled: August 27, 2007Date of Patent: January 6, 2009Assignee: Air Products and Chemicals, Inc.Inventors: James Michael Occhialini, Roger Dean Whitley, Glenn Paul Wagner, Matthew James LaBuda, Craig E. Steigerwalt
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Patent number: 7350521Abstract: Oxygen concentrator system having a portable oxygen generator unit adapted to generate a non-humidified oxygen-rich gas and a stationary base unit adapted to generate a humidified oxygen-rich gas, wherein the portable oxygen generator unit and the stationary base are adapted for operation in a coupled mode and an uncoupled mode. The portable oxygen generator unit includes a first flow coupling adapted to receive the humidified oxygen-rich gas when operating in the coupled mode, piping means adapted to combine the non-humidified oxygen-rich gas and the humidified oxygen-rich gas to form a humidified oxygen-rich gas product, and an oxygen-rich gas product delivery port. The stationary base unit is adapted to recharge a rechargeable power supply system in the portable oxygen generator unit when the units are coupled.Type: GrantFiled: January 13, 2005Date of Patent: April 1, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Roger Dean Whitley, Glenn Paul Wagner, Matthew James LaBuda
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Patent number: 7279029Abstract: System for producing an oxygen-rich gas comprising (a) a primary gas mover including a first and a second compressor, wherein the primary gas mover is characterized by a weight Wp; (b) a drive motor adapted to drive the first and second compressors; (c) a rechargeable power supply characterized by a weight, Wb; and (d) a pressure/vacuum swing adsorption unit adapted to separate the pressurized feed air into an oxygen-rich product at a product flow rate Fp and an oxygen-depleted waste gas, wherein the adsorption unit comprises a plurality of adsorber beds containing an adsorbent and characterized by a total adsorbent weight Wa; and wherein the combined weight, Wt, of the adsorbent, the primary gas mover, and the rechargeable power supply is characterized by the expression 0.75 Fp<Wt<2.02 Fp where Fp is in liters per min (at 23° C. and 1 atma pressure), and Wa, Wp, and Wb are in pounds.Type: GrantFiled: May 21, 2004Date of Patent: October 9, 2007Assignee: Air Products and Chemicals, Inc.Inventors: James Michael Occhialini, Roger Dean Whitley, Glenn Paul Wagner, Matthew James LaBuda, Craig E. Steigerwalt
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Patent number: 6866075Abstract: Apparatus for dispersing particles flowing from an orifice comprising a deflecting surface disposed relative to the orifice, wherein the deflecting surface is fixed relative to the orifice, whereby particles flowing from the orifice can impinge upon and can be dispersed by the deflecting surface, wherein the orifice is one of a plurality of orifices disposed in a wall of a conduit, and wherein the conduit has an axis which is oriented between about 45 degrees and about 70 degrees from the vertical such that particles can flow through the conduit and through the orifices by gravity.Type: GrantFiled: August 9, 2002Date of Patent: March 15, 2005Assignee: Air Products and Chemicals, Inc.Inventors: Roger Dean Whitley, Stephen Clyde Tentarelli, David Ross Graham, Craig E. Steigerwalt, Luigi Depari
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Patent number: 6745801Abstract: Mobile hydrogen generation and supply system comprising hydrogen precursor storage means for storing one or more hydrogen precursors; one or more hydrogen precursor conversion means selected from the group consisting of means for converting a hydrogen precursor into gaseous hydrogen and means for converting a hydrogen precursor into a hydrogen-containing intermediate; one or more delivery means selected from the group consisting of delivery means for offloading gaseous hydrogen and delivery means for offloading a hydrogen-containing intermediate; and mobile support means for mounting the hydrogen precursor storage means, hydrogen precursor conversion means, and one or more delivery means. The system may further comprise one or more means selected from the group consisting of means for converting gaseous hydrogen into stored hydrogen; means for containing stored hydrogen; means for converting stored hydrogen into gaseous hydrogen; and storage means for storing a hydrogen-containing intermediate.Type: GrantFiled: March 25, 2003Date of Patent: June 8, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Joseph Perry Cohen, Tama Maya Copeman
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Patent number: 6742357Abstract: Method for liquefying a gas which comprises cooling a feed gas stream successively through first and second temperature ranges to provide a liquefied product, wherein refrigeration for cooling the feed gas stream in the first temperature range is provided by a first vaporizing refrigerant and refrigeration for cooling the stream in the second temperature range is provided by a second vaporizing refrigerant, and further wherein the second vaporizing refrigerant provides additional refrigeration by vaporization at temperatures above a lowest temperature in the first temperature range.Type: GrantFiled: March 18, 2003Date of Patent: June 1, 2004Assignee: Air Products and Chemicals, Inc.Inventor: Mark Julian Roberts
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Patent number: 6723155Abstract: A method for removing a first and a second minor component from a gas mixture comprising the first and second minor components and one or more major components. The method comprises providing a first adsorbent zone containing a first adsorbent material and a second adsorbent zone containing a second adsorbent material wherein the selectivity of the first adsorbent material for the first minor component relative to the second minor component is greater than the selectivity of the second adsorbent material for the first minor component relative to the second minor component. The average particle diameter of the first adsorbent material and the average particle diameter of the second adsorbent material preferably are substantially the same. The gas mixture is passed through the first adsorbent zone and subsequently through the second adsorbent zone. A purified gas containing the one or more major components and depleted in the first and second minor component is withdrawn from the second adsorbent zone.Type: GrantFiled: April 29, 2002Date of Patent: April 20, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Gregory Scott Weyrich, Shyam Ramchand Suchdeo, Christopher James Raiswell, Elizabeth Helen Salter
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Patent number: 6719007Abstract: Apparatus for attenuating the amplitude of a time-variant property of a fluid stream which comprises an enclosed volume, wherein the enclosed volume includes a mixing zone having an inlet and three or more outlets; piping means for introducing an inlet fluid stream into the inlet of the mixing zone; and piping means for withdrawing from the mixing zone three or more individual fluid portions through the three or more outlets and combining the three or more individual fluid portions into an outlet fluid stream. The distance between at least one pair of adjacent outlets may be different than the distance between another pair of adjacent outlets, and the distance between adjacent outlets may decrease as the distance of each outlet from the inlet increases.Type: GrantFiled: June 11, 2003Date of Patent: April 13, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Oliver Jacob Smith, IV, David Ross Graham
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Patent number: 6709486Abstract: A pressure swing adsorption process for recovering a less readily adsorbable component from a feed gas mixture comprising at least one less readily adsorbable component and at least one more readily adsorbable component. The process utilizes a plurality of adsorbent beds, each bed having a feed end and product end, wherein the process includes the gas transfer steps of (1) transferring gas from the product end of the bed to the product end of another bed; followed by (2) withdrawing waste depressurization gas from the feed end of the bed while continuing to transfer gas from the product end of the bed to the product end of another bed; (3) during either or both of (1) and (2), transferring gas from the feed end of the bed to the feed end or ends of the one or more other beds; and (4) prior to (1), transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure.Type: GrantFiled: April 8, 2002Date of Patent: March 23, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Sang Kook Lee, Justin David Bukowski
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Patent number: 6706770Abstract: Method for the production of methanol and hydrogen which comprises steam reforming a hydrocarbon-containing feed in a steam reforming zone to yield a synthesis gas comprising hydrogen, carbon monoxide, and carbon dioxide; introducing a first portion of the synthesis gas into a methanol synthesis zone to form methanol; reacting a second portion of the synthesis gas with steam to convert carbon monoxide to hydrogen and carbon dioxide to yield a shifted synthesis gas; cooling the shifted synthesis gas to yield a cooled shifted synthesis gas; separating the cooled shifted synthesis gas into a high-purity hydrogen product stream and a reject stream enriched in carbon dioxide; and introducing some or all of the reject stream into either or both of the steam reforming zone and the methanol synthesis zone.Type: GrantFiled: April 4, 2002Date of Patent: March 16, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Nitin Madhubhai Patel, Shoou-I Wang, Eugene S. Genkin
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Patent number: 6681791Abstract: Valve assembly comprising a valve base, a valve bonnet attached thereto, a rotatable valve stem extending coaxially through the valve bonnet, a rotatable valve handle attached to the valve stem and having a plane of rotation which is generally perpendicular to the axis of the valve stem, and an indicator tab attached to the valve base or the valve bonnet and extending outward from the valve body or valve bonnet in a direction generally parallel to the plane of rotation of the valve handle. The rotatable valve handle can be disposed in at least a first position and a second position, wherein the rotatable handle when disposed in the first position renders the indicator tab invisible when viewed in a direction generally perpendicular to the plane of rotation of the valve handle, and wherein the rotatable handle when disposed in the second position renders the indicator tab visible when viewed in a direction generally perpendicular to the plane of rotation of the valve handle.Type: GrantFiled: September 26, 2002Date of Patent: January 27, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Stephen Chorney, Richard Linton Samsal, Stanley Louis Morton, Peter Joseph Kielhofner, Todd Jeffrey Siegfried, Thomas Anderson
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Patent number: 6662589Abstract: Process for the recovery of components heavier than methane from natural gas, wherein the process comprises (a) cooling a natural gas feed to provide a cooled natural gas feed and introducing the cooled natural gas feed into an absorber column at a first location therein; (b) withdrawing from the absorber column a first overhead vapor stream depleted in components heavier than methane and a bottoms stream enriched in components heavier than methane; (c) introducing a methane-rich reflux stream at a second location in the absorber column above the first location; (d) separating the bottoms stream into a stream enriched in methane and one or more streams enriched in components heavier than ethane; and (e) introducing an absorber liquid comprising components heavier than ethane into the absorber column at a location between the first location and the second location.Type: GrantFiled: April 16, 2003Date of Patent: December 16, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Mark Julian Roberts, Howard Charles Rowles
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Patent number: 6651703Abstract: A system for the transportation and storage of a product comprising a tank including a cylindrical wall section and two ends which define a cylindrical tank periphery, wherein the tank periphery has an interior and an exterior; a recessed valve box including one or more side walls, a bottom wall, and a removable, sealable top cover which can be attached to the one or more side walls to seal the valve box, wherein the valve box side walls are sealably joined to the cylindrical wall section such that the valve box extends through the cylindrical wall section into the interior of the tank periphery and is partially or totally disposed in the interior of the tank periphery; and one or more valves disposed in the valve box.Type: GrantFiled: March 19, 2002Date of Patent: November 25, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Vladimir Yliy Gershtein, Robert William Ford, Christopher R. Butler, Eugene Y. Ngai
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Patent number: 6641645Abstract: A gas transfer segment of a vacuum swing adsorption process cycle utilizing multiple parallel adsorbent beds which undergo cyclic process steps to separate the components of a feed gas mixture, each bed having a feed end and a product end, wherein the gas transfer segment comprises a step of withdrawing a waste gas stream from the feed end of a first bed, withdrawing a transfer gas from the product end of the first bed and introducing the transfer gas into the product end of a second bed, and withdrawing a waste gas stream from the feed end of the second bed.Type: GrantFiled: June 13, 2002Date of Patent: November 4, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Sang Kook Lee, Justin David Bukowski
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Patent number: 6637469Abstract: A container for holding a solid, liquid and/or gaseous phase product therein and for use within a transportable or stationary support structure. The container maximizes the compressed product volume contained therein and prevents liquid and/or contaminant entrainment during gaseous product delivery from liquid phase product. The system allows for product withdraw when the level is above the delivery valves using, at a minimum, two delivery legs linked by a compartment or housing that connects the delivery point and a container head space via a removable manway.Type: GrantFiled: March 19, 2002Date of Patent: October 28, 2003Assignee: Air Products and Chemicals, Inc.Inventors: Steven W. Hoffman, Vladimir Yliy Gershtein, Alexandre De Almeida Botelho, Robert William Ford, Paul David Kottler