Patents Represented by Attorney John M. Genova
-
Patent number: 5801269Abstract: Processes for recovering 4,4'-dimethyl bibenzoate (DMBB) from byproduct streams of dimethyl terephthalate (DMT) production are disclosed. The byproduct streams are treated to produce an overhead stream which includes DMBB. In one aspect of the invention, the overhead product stream is added to an organic solvent under conditions sufficient to rapidly form a suspension of crystallized DMBB. In another aspect of the invention, the overhead is dissolved in an appropriate organic solvent and cooled to form a suspension of DMBB crystals in the solvent. A portion of the suspension is removed, and the remaining portion of the suspension centrifuged to recover DMBB crystals. In still another aspect of the invention, the overhead stream is treated with an organic solvent to form a slurry of DMBB crystals, and the resultant slurry thermally treated to increase the concentration of DMBB crystals therein while also solubilizing any organic contaminants.Type: GrantFiled: April 30, 1997Date of Patent: September 1, 1998Assignee: Hoechst Celanese Corp.Inventors: Carrie A. Feeney, Ida L. Jones, Bennett C. Ward, Thomas M. Kenesson, Charles B. Hilton, Michael R. Ahern, Gregory M. Adams, Edward M. de la Garza, B. Frank Wood, Jr., Thomas L. Grantland, Kan J. Tsai, James L. Ragan
-
Patent number: 5773144Abstract: A rubber-polyester composite comprising a rubber and a core-and-sheath heterocomponent fiber wherein the fiber core is formed from a linear polyester derived from an alkyl glycol and an aromatic diacid, and wherein the fiber sheath is formed from a compatibilizing acid-terminated or isocyanate-terminated polyester. The fiber sheath may also be composed of a blend of a thermoplastic elastomer and the compatibilizing polyester.Type: GrantFiled: October 26, 1995Date of Patent: June 30, 1998Assignee: Hoechst Celanese Corp.Inventors: Eui Won Choe, Charles Edward Forbes, Jennifer Ann Filbey, Stephan Fredrick Sherriff
-
Patent number: 5736297Abstract: The invention relates to a positive-working radiation-sensitive mixture containing a) a compound which forms acid when exposed to actinic radiation, b) a compound containing at least one C--O--C or C--O--Si bond which can be cleaved by said acid, and c) a water-insoluble polymeric binder which is soluble, or at least swellable, in aqueous alkaline solutions, wherein the compound a) comprises the structure of the formulae I, II or III: ##STR1## The radiation-sensitive mixture according to the invention is notable for a high resolution and a high sensitivity over a wide spectral range. It also has high thermal stability and does not form any corrosive photolysis products on exposure to light.The invention furthermore relates to a radiation-sensitive recording material produced therefrom which is suitable for producing photoresists, electronic components, printed circuit boards or for chemical milling.Type: GrantFiled: July 22, 1996Date of Patent: April 7, 1998Assignee: Clariant GmbHInventors: Horst Roeschert, Georg Pawloski
-
Patent number: 5731132Abstract: The invention relates to a metal-ion-free developer which contains, in addition to at least one of the standard basic compounds, certain anionic and, optionally, non-ionic surfactants, and to a corresponding concentrate.Type: GrantFiled: May 16, 1995Date of Patent: March 24, 1998Assignee: Clariant GmbHInventors: Karl van Werden, Marlies Eltgen
-
Patent number: 5725950Abstract: A process for the preparation of carbon and/or silicon coated ceramic fibers is disclosed involving contact of a preceramic fiber with a hydrocarbon or a silane which decomposes at a temperature no higher than 500.degree. C. at 1 atmosphere.Type: GrantFiled: September 19, 1986Date of Patent: March 10, 1998Assignee: Hoechst Celanese Corp.Inventors: Paul Foley, Linda C. Sawyer
-
Patent number: 5710269Abstract: Methods of synthesizing starch acetate containing at least 20% high molecular weight carbohydrates using a MSA catalyst alone, or in combination with a co-catalyst promoting cross-linking, such a phosphoric acid, are described. The MSA is desirably added slowly following beginning of the exothermic reaction of starch, acetic acid and acetic anhydride.Type: GrantFiled: January 16, 1996Date of Patent: January 20, 1998Assignee: Hoechst Celanese Corp.Inventor: Bernice I. Feuer
-
Patent number: 5709740Abstract: A thermally expandable wax composition and its use in polymer-based actuators is disclosed and claimed. The compositions are wax-based and include conductive filler as well as a viscosity modifier to stabilize the composition against segregation. Optionally included are thermoxidative stabilizers.Type: GrantFiled: February 23, 1996Date of Patent: January 20, 1998Assignee: Hoechst Celanese Corp.Inventors: M. Ishaq Haider, James E. Kuder, Barbara J. Long, Joseph D. Menczel, James B. Stamatoff, Michael Bayer
-
Patent number: 5698645Abstract: A process for preparing a cycloolefin copolymer by polymerization of at least one cycloolefin and at least one acyclic olefin in the presence of a catalyst which contains at least one cocatalyst and at least one metal-locene of the formula (I) ##STR1##Type: GrantFiled: February 7, 1997Date of Patent: December 16, 1997Assignee: Hoechst AktiengesellschaftInventors: Thomas Weller, Frank Osan, Frank Kuber, Michael Aulbach
-
Patent number: 5693836Abstract: A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.Type: GrantFiled: June 7, 1995Date of Patent: December 2, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Martin Antberg, Bernd Bachmann, Volker Dolle, Frank Kuber, Jurgen Rohrmann, Walter Spaleck
-
Patent number: 5672668Abstract: A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.Type: GrantFiled: August 16, 1993Date of Patent: September 30, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Martin Antberg, Bernd Bachmann, Volker Dolle, Frank Kuber, Jurgen Rohrmann, Walter Spaleck
-
Patent number: 5668235Abstract: Polyolefin molding composition comprising of a polyolefin formed from an olefin having at least 3 carbon atoms of the formula R.sup.a --CH.dbd.CH--R.sup.b, where R.sup.a and R.sup.b are identical or different and each is hydrogen or C.sub.1 -C.sub.15 -alkyl, straight-chain or branched, or R.sup.a and R.sup.b together with the atoms joining them together form a ring system, and from 0 to 10% by weight of ethylene or of a second olefin have the abovementioned meaning as comonomer, characterized by a 230/2.16 MFI from 5 to 1000 g/10 min, a 230/5 MFI from 15 to 3000 g/10 min, n, a molecular weight (M.sub.w) from 75,000 to 350,000 g/mol, a polydispersity (M.sub.w /M.sub.n) from 1.8 to 3.5, a viscosity number from 70 to 300 cm.sup.3 /g, a melting point from 120.degree. to 165.degree. C., an isotactic block length from 25 to 150, and ether extractables less than 2% by weight, based on the total weight of the polymer.Type: GrantFiled: June 6, 1995Date of Patent: September 16, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Annette Vollmar, Friedrich Kloos, Bernd Bachmann
-
Patent number: 5649343Abstract: An apparatus having a plurality of needle rollers (1) which are rotatable about their longitudinal axis (3) and the respective longitudinal axes (3) of which are themselves movable on a circular path. In this apparatus, the needle rollers (1) and support rollers (2) for the material web (9) alternate with one another.Type: GrantFiled: April 8, 1996Date of Patent: July 22, 1997Assignee: Hoechst AktiengesellschaftInventor: Hans Jurgen Profe
-
Patent number: 5637666Abstract: Polyolefin molding composition comprising a polyolefin formed from an olefin having at least 3 carbon atoms of the formula R.sup.a --CH.dbd.CH--R.sup.b, where R.sup.a and R.sup.b are identical or different and each is hydrogen or C.sub.1 -C.sub.15 -alkyl, straight-chain or branched, or R.sup.a and R.sup.b together with the atoms joining them together form a ring system, and from 0 to 10% by weight of ethylene or of a second olefin have the abovementioned meaning as comonomer, characterized by a 230/2.16 MFI from 5 to 1000 g/10 min, a 230/5 MFI from 15 to 3000 g/10 min, a molecular weight (M.sub.w) from 75,000 to 350,000 g/mol, a polydispersity (M.sub.w /M.sub.n) from 1.8 to 3.5, a viscosity number from 70 to 300 cm.sup.3 /g, a melting point from 120.degree. to 165.degree. C., an isotactic block length from 25 to 150, and ether extractables less than 2% by weight, based on the total weight of the polymer.Type: GrantFiled: February 10, 1995Date of Patent: June 10, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Annette Vollmar, Friedrich Kloos, Bernd Bachmann
-
Patent number: 5623039Abstract: The present invention relates to a cycloolefin polymer having a solution viscosity >0.25 dl/g and containing polymerized units of at least one cycloolefin and, if desired, polymerized units of one or more acyclic olefins, wherein the cycloolefin polymer has at one or both ends an olefinically unsaturated group having at least 3 carbon atoms.Type: GrantFiled: July 11, 1995Date of Patent: April 22, 1997Assignee: Hoechst AktiengesellschaftInventors: Wilfried Hatke, Frank Osan
-
Patent number: 5616747Abstract: A process for the preparation of a compound of the formula III ##STR1## comprising, deprotonating a solution or suspension of an indene of the formula I ##STR2## in a solvent or solvent mixture containing a base to give a suspension of a metallated product of the compound of formula I,adding to the suspension of the metallated product a compound of the formula IIX--R.sup.6 --X (II)and reacting the suspension of the metallated product and compound of the formula II.Type: GrantFiled: November 15, 1994Date of Patent: April 1, 1997Assignee: Hoechst AktiengesellschaftInventors: J urgen Rohrmann, Frank K uber
-
Patent number: 5614309Abstract: A polypropylene or polyethylene film or fiber coated with a maleic-acid grafted polypropylene or polyethylene copolymer layer over which is coated a layer of selective polymer. The copolymer securely bonds the selective polymer to the film or fiber. These fibers and films can be used in fluid separation membranes.Type: GrantFiled: May 19, 1992Date of Patent: March 25, 1997Assignee: Hoechst Celanese Corp.Inventors: Tai-Shung Chung, Edward R. Kafchinski, Rachel S. Kohn, Frank J. Onorato, Jr.
-
Patent number: 5612169Abstract: The invention relates to N,N-disubstituted sulfonamides of the formulae R.sup.1 [--N(CO--OR.sup.2)--SO.sub.2 --R.sup.3 ].sub.n (I) and R.sup.1 [--SO.sub.2 --N(CO--OR.sup.2)--R.sup.3 ].sub.n (II), in which R.sup.1 --for n=1--is a (C.sub.1 -C.sub.20)alkyl, (C.sub.3 -C.sub.10)cycloalkyl, (C.sub.6 -C.sub.14) aryl or (C.sub.7 -C.sub.20)aralkyl radial, for n>1--the 2-, 3- or 4-valent radical of a (C.sub.1 -C.sub.20)alkane or (C.sub.6 -C.sub.7)cycloalkane, a non-condensed or condensed mono- or polynuclear (C.sub.6 -C.sub.18)aromatic compound, R.sup.2 is a (C.sub.3 -C.sub.11)alkyl, (C.sub.3 -C.sub.11)alkenyl or (C.sub.7 -C.sub.11)aralkyl radical, R.sup.3 is an unsubstituted or substituted (C.sub.1 -C.sub.6)alkyl, (C.sub.3 -C.sub.6)cycloalkyl, (C.sub.6 -C.sub.14)aryl or (C.sub.7 -C.sub.20)aralkyl radical.Type: GrantFiled: August 8, 1994Date of Patent: March 18, 1997Assignee: Hoechst AktiengesellschaftInventors: Mathias Eichhorn, Gerhard Buhr
-
Patent number: 5609676Abstract: A process which comprises suspending a reactive-dyed cellulose material, optionally in mixture with pulp, in an alkali metal hydroxide solution (alkali cellulose), optionally subjecting the alkali cellulose to the action of a reducing sulfur compound at a temperature from 20.degree. to 80.degree. C., then allowing the alkali cellulose to ripen at temperatures from 30.degree. to 80.degree. C. for at least 30 minutes, dissolving the alkali cellulose at a temperature from 10.degree. to 30.degree. C. by conversion with carbon disulfide into the xanthate, and spinning the xanthated alkali cellulose into fibers, makes it possible to recycle cellulosic waste textiles into similarly colored or colorless cellulose fiber materials.Type: GrantFiled: December 8, 1995Date of Patent: March 11, 1997Assignee: Hoechst AktiengesellschaftInventor: Andreas von der Eltz
-
Patent number: 5610253Abstract: The present invention relates to a cycloolefin polymer having a solution viscosity <0.25 dl/g, comprising polymerized units of at least one cycloolefin and, if desired, polymerized units of one or more acyclic olefins, wherein the cycloolefin polymer has at one or both ends an olefinically unsaturated group having at least 3 carbon atoms.Type: GrantFiled: July 11, 1995Date of Patent: March 11, 1997Assignee: Hoechst AktiengesellschaftInventors: Wilfried Hatke, Frank Osan
-
Patent number: 5597881Abstract: A polyolefin molding composition essentially comprising a polyolefin derived from an olefin having at least 3 carbon atoms, of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are hydrogen or C.sub.1 -C.sub.15 -alkyl, straight-chain or branched, or R.sup.a and R.sup.b, together with the atoms connecting them, form a ring, where the polyolefin molding composition may contain up to 10% by weight of ethylene or a second olefin as defined above as comonomer, having a molecular weight M.sub.w of >80,000 g/mol, a polydispersity M.sub.w /M.sub.n of from 1.8 to 3.5, a viscosity of >70 cm.sup.3 /g, a melting point of from 130.degree. to 160.degree. C., an aligned transparency of >30% and an ether-extractable content of less than 2% by weight.Type: GrantFiled: March 20, 1996Date of Patent: January 28, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Winter, Horst Bormuth, Bernd Bachmann