Patents Represented by Attorney, Agent or Law Firm Jonathan D. Wood
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Patent number: 6077945Abstract: A novel process for making an alkylpolyglycoside comprises reacting a monosaccharide with an alcohol in the presence of a binary sulfate catalyst under heat. The particular binary sulfate catalyst is a mixture of H.sub.2 SO.sub.4 and inorganic base at a normal ratio of about 0.7:1 to 1.1:1 of H.sub.2 SO.sub.4 to inorganic base. Also the alkylpolyglycoside product from the reaction mixture can be isolated so that the alkylpolyglycoside process contains less than 5 weight percent free alcohol, and further separated into a white, free flowing powder of high DP (degree of polymerization) alkylpolyglycoside and a low DP alkylpolyglycoside paste.Type: GrantFiled: February 9, 1998Date of Patent: June 20, 2000Assignee: Eastman Chemical CompanyInventors: Charles Michael Buchanan, Matthew Davie Wood
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Patent number: 6070394Abstract: Disclosed herein is a stretch wrapping process wherein a roll of film is unwound and stretched, at a speed up to about 70 meters per minute, and the film is wrapped about the girth of a unitized plurality of goods, with the overlapping layers of film being held together by cling force. The film used in the present process is produced from a composition comprising about 85 to about 99 weight percent of a polymeric ethylenic containing component having a density no greater than 0.94 g/cc, and about 1 to about 15 weight percent of a propylene polymer comprising 0 to about 40 weight percent olefin comonomer units having 2 to 10 carbon atoms, and from about 60 to about 100 weight percent propylene.Type: GrantFiled: September 2, 1998Date of Patent: June 6, 2000Assignee: Eastman Chemical CompanyInventors: Marc Stacey Somers, Guy Glen Luneau
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Patent number: 6060584Abstract: A novel process for the production of degraded polyolefin is described. The process involves introducing polyolefin into one end of a vented multi-screw extruder, in the substantial absence of free radical initiator and oxidizing agent, and removing degraded polyolefin from the opposite end of the extruder.Type: GrantFiled: May 13, 1998Date of Patent: May 9, 2000Assignee: Eastman Chemical CompanyInventors: Brenda Linette Neely, James Houston Scott
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Patent number: 6046279Abstract: A novel, continuous process for the manufacture of novel higher molecular weight and higher acid numbered maleated polypropylenes with lower color at higher efficiencies involving specified ratios of polypropylene, maleic anhydride, and free radical initiator is described. The novel maleated polypropylenes have an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process entails continuously forming an intimate mixture of molten polypropylene and molten maleic anhydride at one end of a reactor, continuously introducing a free radical initiator, and continuously removing high acid number high molecular weight maleated polypropylene of low color from the opposite end of the reactor.Type: GrantFiled: February 24, 1999Date of Patent: April 4, 2000Assignee: Eastman Chemical CompanyInventors: Thomas David Roberts, Stephen Wayne Coe
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Clear aerosol hair spray formulations containing a sulfopolyester in a hydroalcoholic liquid vehicle
Patent number: 6007794Abstract: This invention relates to an aerosol hair spray formulation containing 0.5 to 15 weight percent of a water-dispersible or water-dissipatible, linear sulfopolyester having a Tg of 40.degree. C. to 50.degree. C. and an inherent viscosity of 0.24 to 0.60 dl/g which contains repeat units from 20 to 26 mole percent dimethyl-5-sodiosulfoisophthalate and 74 to 80 mole percent isophthalic acid, based on 100 mole percent dicarboxylic acid; 10 to 30 mole percent 1,4-cyclohexanedimethanol and 70 to 90 percent diethylene glycol, based on 100 mole percent diol; and up to 60 weight percent of an alcohol. The aerosol hair spray formulations are clear, have improved dry time and curl retention, and exhibit less than 20 NTU's, which is a measure of turbidity, even at high concentrations of alcohol.Type: GrantFiled: December 16, 1998Date of Patent: December 28, 1999Assignee: Eastman Chemical CompanyInventors: Scott E. George, Vicki L. Underwood, D. Michael Garber, Andy H. Singleton -
Patent number: 6007910Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.Type: GrantFiled: February 2, 1998Date of Patent: December 28, 1999Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
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Patent number: 6003567Abstract: A process for packaging normally tacky amorphous polyolefins, and other materials having similar melt viscosities, is provided. The process entails flowing a heated material into a molded polyolefin container having a minimum wall thickness of about 0.1 mm to less than 0.24 mm at a temperature above the melting point of the container, followed by slowly cooling the filled container. The process is conducted at ambient conditions without the use of cooling fluids.Type: GrantFiled: January 8, 1999Date of Patent: December 21, 1999Assignee: Eastman Chemical CompanyInventor: Marc Stacey Somers
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Patent number: 5985951Abstract: This invention relates to a composition of photopolymerizable coatings forming cosmetic films that are especially useful for human and animal nail coatings. The coating compositions are based on certain cellulose ester derivatives, which possess groups capable of free radical addition reactions with unsaturated ethylenic pendant groups on other compounds upon exposure to actinic radiation in the presence of an photoinitiator. The coating compositions contain solvents, pigments, modifying resins, plasticizers, and other compounds mixed and maintained in a liquid solution.Type: GrantFiled: April 29, 1998Date of Patent: November 16, 1999Assignee: Eastman Chemical CompanyInventor: Phillip Michael Cook
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Patent number: 5981738Abstract: The present invention relates to a modified cellulose ester containing unsaturated pendent groups which can be prepared by reacting a cellulose ester containing residual hydroxyl groups with, for example, maleic anhydride in acetic acid solvent with sodium acetate catalyst. The modified cellulose ester is not homopolymerizable but will copolymerize in the presence of vinyl crosslinking agents and a photoinitiator upon exposure to ultraviolet radiation. The modified cellulose ester is useful as a protective and/or decorative coating for wood, metal, plastics, paper, board, and other substrates, as well as an additive to printing inks, and as a nail polish. In addition, because of the propensity for the pendant carboxyl groups to form hydrophilic salts with amines, the modified cellulose esters can be formulated to be water-dispersible.Type: GrantFiled: August 11, 1998Date of Patent: November 9, 1999Assignee: Eastman Chemical CompanyInventors: Phillip Michael Cook, Robert Andrew Simm
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Patent number: 5973038Abstract: The present invention relates to a black polymeric composition suitable for use in films, fibers and molded articles, where a soluble, easily dispersed colorant is desirable. The black polymeric composition provides a high black color quality and is small enough to function as a black colorant in microdenier fibers. The black polymeric composition comprises a thermoplastic resin in an amount between about 50 weight percent and about 99.9 weight percent of the black polymeric composition, and a black dye composition in an amount between about 0.1 weight percent and about 50 weight percent of the black polymeric composition. The black dye composition contains a black indanthrone compound as a major component. As used herein, black indanthrone compounds are defined as compounds having the general structure represented by Formula I: ##STR1## wherein R is hydrogen or at least one group independently selected from C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.Type: GrantFiled: May 13, 1998Date of Patent: October 26, 1999Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, Clarence Alvin Coates, Jr., Jean Carroll Fleischer, Brian Edison Maxwell
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Patent number: 5965657Abstract: A solid, air stable adhesive composition containing wax and a polyolefin having a viscosity no greater than 2,000 centipoise and a needle penetration hardness of at least 50 dmm is disclosed. It is further disclosed that propylene-ethylene copolymer is the preferred polyolefin of the present invention.Type: GrantFiled: January 23, 1997Date of Patent: October 12, 1999Assignee: Eastman Chemical CompanyInventors: Leo Paul Voegtli, Shane Kipley Kirk
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Patent number: 5962557Abstract: A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.Type: GrantFiled: August 7, 1997Date of Patent: October 5, 1999Assignee: Eastman Chemical CorporationInventors: Max Allen Weaver, Brian Edison Maxwell, Gerry Foust Rhodes, James John Krutak, Sr.
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Patent number: 5955547Abstract: A novel, continuous process for the manufacture of novel higher molecular weight and higher acid numbered maleated polypropylenes with lower color at higher efficiencies involving specified ratios of polypropylene, maleic anhydride, and free radical initiator is described. The novel maleated polypropylenes have an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process entails continuously forming an intimate mixture of molten polypropylene and molten maleic anhydride at one end of a reactor, continuously introducing a free radical initiator, and continuously removing high acid number high molecular weight maleated polypropylene of low color from the opposite end of the reactor.Type: GrantFiled: May 20, 1997Date of Patent: September 21, 1999Assignee: Eastman Chemical CompanyInventors: Thomas David Roberts, Stephen Wayne Coe
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Patent number: 5955564Abstract: This invention relates to new blue anthraquinone colorants having Formula I ##STR1## wherein R and R1 are the same or different and are selected from hydrogen and unsubstituted or substituted C1-C6 alkyl, C3-C7 cycloalkyl 2-furyl, 2-thienyl, or phenyl; R2 is aryl; X is a group selected from hydroxy, C1-C6 alkanolyloxy, carboxy, C1-C6 carbalkoxy and carbamoyloxy.The colorants are useful for copolymerizing into polymers such as polyesters and polyurethanes. In particular, they are advantageous for preparing colored sulfopolyesters which are useful for coloring human hair.Type: GrantFiled: November 21, 1997Date of Patent: September 21, 1999Assignee: Eastman Chemical CompanyInventors: Max Allen Weaver, James John Krutak, Sr., Clarence Alvin Coates, Jr.
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Patent number: 5942304Abstract: Disclosed is a process for producing non-blocking slats of normally tacky amorphous propylene copolymers. The process entails coextruding the normally tacky amorphous propylene copolymer with a low viscosity polyolefin such as a polyethylene wax forming a core of amorphous propylene copolymer covered with a sheath of polyethylene wax. The coextruded article is cooled, cut (while exposing less than 40 percent of the core) and then coated with a non-tacky powder; thereby, forming non-blocking slats. Disclosed is also a novel amorphous propylene copolymer composition containing no more than 90 weight percent propylene and up to 70 weight percent of an alpha olefin comonomer having a needle penetration greater than 70 to less than 100 dmm at 23.degree. C. and a Brookfield Thermosel Viscosity below 1000 cP at 190.degree. C.Type: GrantFiled: August 5, 1996Date of Patent: August 24, 1999Assignee: Eastman Chemical CompanyInventor: Marc Stacey Somers
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Patent number: 5928460Abstract: Disclosed is an essentially odorless water dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. The copolyester adhesive composition can be used neat or formulated and exhibits broad compatibility with a variety of adhesive additives, including non polar tackifiers.Type: GrantFiled: February 2, 1998Date of Patent: July 27, 1999Assignee: Eastman Chemical CompanyInventors: Richard Anthony Miller, Scott Ellery George
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Patent number: 5925336Abstract: This invention relates to an aqueous nail coating composition and method for coloring nails comprising the use of a water-dispersible, colored sulfopolyester wherein the colorant moiety is incorporated into or onto a carbonyloxy and/or carbonylamide backbone of the sulfopolyester. The sulfopolyesters are uniquely designed to offer cosmetically desirable color coatings on nails.Type: GrantFiled: October 10, 1996Date of Patent: July 20, 1999Assignee: Eastman Chemical CompanyInventors: Dennis Michael Garber, James John Krutak, Sr.
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Patent number: 5878794Abstract: A process for packaging normally tacky amorphous polyolefins, and other materials having similar melt viscosities, is provided. The process entails flowing a heated material into a molded polyolefin container having a minimum wall thickness of about 0.1 mm to less than 0.24 mm at a temperature above the melting point of the container, followed by slowly cooling the filled container. The process is conducted at ambient conditions without the use of cooling fluids.Type: GrantFiled: January 21, 1997Date of Patent: March 9, 1999Assignee: Eastman Chemical CompanyInventor: Marc Stacey Somers
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Patent number: 5871573Abstract: The present invention relates to a modified cellulose ester containing unsaturated pendent groups which can be prepared by reacting a cellulose ester containing residual hydroxyl groups with, for example, maleic anhydride in acetic acid solvent with sodium acetate catalyst. The modified cellulose ester is not homopolymerizable but will copolymerize in the presence of vinyl crosslinking agents and a photoinitiator upon exposure to ultraviolet radiation. The modified cellulose ester is useful as a protective and/or decorative coating for wood, metal, plastics, paper, board, and other substrates, as well as an additive to printing inks, and as a nail polish. In addition, because of the propensity for the pendant carboxyl groups to form hydrophilic salts with amines, the modified cellulose esters can be formulated to be water-dispersible.Type: GrantFiled: June 17, 1997Date of Patent: February 16, 1999Assignee: Eastman Chemical CompanyInventors: Phillip Michael Cook, Robert Andrew Simm
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Patent number: 5859152Abstract: Disclosed is a water-dissipatable or dispersible adhesive composition that is useful in forming paper articles and other products that can be recycled through repulping in both neutral and alkaline media. The water-dispersible adhesive composition is preferably a hot melt adhesive that is a low molecular weight, branched copolyester containing a sulfomonomer. Additional utility for the invention resides in the manufacture of recyclable articles where insolubility in body fluids combined with solubility in tap water are required.Type: GrantFiled: September 12, 1997Date of Patent: January 12, 1999Assignee: Eastman Chemical CompanyInventors: Richard A. Miller, Mark A. Montgomery