Patents Represented by Attorney Joseph C. Suhadolnik
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Patent number: 7736866Abstract: A time temperature indicator for indicating temperature change over time is provided, comprising an immobilized enzyme and a substrate of the enzyme, wherein the reaction of the substrate catalyzed by the enzyme produces a reaction product in a time and temperature dependent manner and wherein the formation of the reaction product can be detected by monitoring a physical characteristic of the substrate and/or the product which is linked to its concentration. Also provided is a method of time temperature indication comprising the step of an enzyme-catalyzed reaction, a method of printing the enzyme-based time temperature indicator on a packaging material or a label, a printing ink or printing ink concentrate comprising components of the enzyme-based time temperature indicator and a packaging material or a label comprising the enzyme-based time temperature indicator.Type: GrantFiled: August 3, 2005Date of Patent: June 15, 2010Assignee: Ciba CorporationInventors: Hans Reichert, Peter Simmendinger, Thomas Bolle
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Patent number: 7732504Abstract: The invention relates to novel photoinitiators of formula (I) wherein each of the substituents is given the definition as set forth in the Specification and the claims. The photoinitiators can be used to prepare multifunctional photoinitiators.Type: GrantFiled: January 24, 2005Date of Patent: June 8, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Kurt Dietliker, Rinaldo Hüsler, Jean-Luc Birbaum, Jean-Pierre Wolf
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Patent number: 7731791Abstract: The present invention relates to the field of color filters and LCDs.Type: GrantFiled: September 21, 2005Date of Patent: June 8, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Takashi Deno, Thomas Eichenberger, Joachim Voigt
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Patent number: 7731985Abstract: A method is provided for the antimicrobial treatment of a surface which comprises the contacting a surface with substituted 4-aminopyrimidines.Type: GrantFiled: March 10, 2003Date of Patent: June 8, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Sophie Marquais-Bienewald, Werner Hölzl, Wolfgang Haap, Andrea Preuss, Andreas Mehlin
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Patent number: 7727702Abstract: A method is provided for irreversibly coloring a coating composition containing a color former comprising the steps of a) providing a coating composition that contains an UV curable resin, a thermosetting resin or an alkyd resin with the proviso that the coating composition contains no developer nor any additive which may function as developer; b) mixing the coating composition with the color former whereby no color is formed; c) applying the colorless composition obtained in step b) to a substrate; d) in case of a thermosetting resin curing the resin between 100 and 300° C., preferably between 100 and 150° C., whereby no color is formed, in case of alkyd resin drying of the resin at room temperature, whereby no color is formed; e) exposure to UV or high energy radiation below 400 nm whereby the color is formed.Type: GrantFiled: March 29, 2005Date of Patent: June 1, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Johannes Benkhoff, Karin Powell
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Patent number: 7722893Abstract: The use of 2,4—bis(alkylamino)pyrimidines of formula (1) R1 is C1-C12alkyl or C6-C10laryl; R2 is hydrogen or C1-C12alkyl; or R1 and R2 together form a radical of formula (1a) R? and R? are each independently of the other hydrogen, C1-C6alkyl or C1-C6alkoxy, R3 and R5 are each independently of the other hydrogen or C1-C8alkyl; R4 is C1-C20alkyl, unsubstituted phenyl, C6-C10aryl, C6-C10aryl-C1-C6alkyl, hydroxy-C1-C6alkyl, di-C1-C6alkylamino-C 1-C6alkyl, mono-C1-C6alkylamino-C1-C6alkyl, —(CH2)2-(O—(CH2)2)1-4—OH or —(CH2)2—(O—(CH2)2)1-4—NH2; R6 is C1-C20alkyl, C6-C10aryl, C6-C10aryl-C1-C6alkyl, hydroxy-C1-C6alkyl, di-C1C6alkylamino-C1-C6alkyl, mono- C1-C6alkylamino-C1-C 6alkyl, —(CH2)2—(O—(CH2)2)1-4—OH or —(CH2)2—(O—(CH2)2)1-4—NH2; or R3 and R 4 and/or R5 and R6, together form a pyrrolidine, piperidine, hexamethyleneimine or morpholine ring; in the antimicrobial treatment of surfaces.Type: GrantFiled: July 16, 2004Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Sophie Marquais-Bienewald, Werner Hölzl, Andrea Preuss, Andreas Mehlin
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Patent number: 7723398Abstract: The invention relates to a radiation curable coating or an ink composition comprising a photoinitiator and a stabilizer blend of a sterically hindered nitroxyl radical and a quinone methide.Type: GrantFiled: April 12, 2006Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Stephan Ilg, Edith Pighetti, Peter Nesvadba, André Fuchs
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Patent number: 7723530Abstract: The present invention relates to the use of polymerisable diketopyrrolopyrroles in colour filters, which can themselves be used for example in electro-optical systems such as TV screens, liquid crystal displays, charge coupled devices, plasma displays or electroluminescent displays and the like. In contrast to conventional pigments the polymerisable diketopyrrolopyrroles do not tend to aggregate and, hence, show very good dispersibility. Color filters prepared by using the polymerisable diketopyrrolopyrroles have high transparence and pure hue. In addition, they facilitate adjustment of color points and enable a large choice of shades.Type: GrantFiled: January 3, 2008Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Gerardus De Keyzer
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Patent number: 7723425Abstract: The present invention relates to a composition containing modified block copolymer dispersants and dispersible inorganic or organic pigments. The block copolymers are prepared by atom transfer radical polymerisation (ATRP) and modified with a salt forming group. The pigment composition is useful for preparing coating compositions, prints, images, inks or lacquers and other disperse systems.Type: GrantFiled: March 21, 2006Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Clemens Auschra, Ernst Eckstein, Marie-Odile Zink, Andreas Mühlebach
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Patent number: 7722715Abstract: A process for the preparation of pigment compositions which give improved ink flow is provided which comprises treating the pigment, during the pigment synthesis, with a small amount of a long chain aliphatic amine. The pigment compositions obtained can be used for preparing millbase inks which due to their improved flow viscosity (rheology) at high pigmentation can be easily handled as well as flexibly formulated, e.g. a number of final printing inks for different ink applications can be manufactured from a single millbase in a very economical manner. The final inks are preferably used in packaging gravure printing processes.Type: GrantFiled: March 30, 2005Date of Patent: May 25, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Stephen Haggata, Iain Frank Fraser, Stephen John Coughlin
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Patent number: 7708819Abstract: The invention relates to a composition comprising from 92 to 97% by weight pigment and from 3 to 8% by weight binder, in each case based on the composition, wherein the binder is a mixture comprising: from 5 to 60% by weight, based on the binder, of modified cellulose wherein, on average, per glucose unit, from 0.5 to 1.4 hydroxyl hydrogen atoms are replaced by R1, from 0.25 to 0.6 hydroxyl hydrogen atoms are replaced by R2, or from 0.5 to 1.4 hydroxyl hydrogen atoms are replaced by R1, and from 0 to 0.Type: GrantFiled: November 24, 2003Date of Patent: May 4, 2010Assignee: Ciba Specialty Chemicals CorporationInventor: Paolo Balliello
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Patent number: 7687554Abstract: The instant invention pertains to a concentrated aqueous dispersion of organic light stabilizers with a particle size of less than 1000 nm, prepared by heterophase radical polymerization of ethylenically unsaturated monomers in the presence of the light stabilizers, wherein the weight ratio of light stabilizer to polymeric carrier is greater than 50/100. Another aspect of the invention is a process for the preparation of such aqueous dispersions with high light stabilizer content. Aqueous dispersions prepared according to this process are useful ingredients for adhesives, aqueous emulsions of natural or synthetic rubbers, water based inks or a water based coating compositions, which are consequently also subjects of the invention.Type: GrantFiled: September 1, 2004Date of Patent: March 30, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Carsten Schellenberg, Clemens Auschra, Wolfgang Peter, Delphine Kimpel, Pascal Hayoz
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Patent number: 7687657Abstract: The invention relates to a process for the preparation of (bis)acylphosphanes of formula I, wherein n and m are each independently of the other 1 or 2; R1 if n=1, is e.g. unsubstituted or substituted C1-C18alkyl or C2-C18alkenyl, or phenyl, R1 if n=2, is e.g. a divalent radical of the monovalent radical defined above; R2 is e.g. C1-C18alkyl, C3-C12cycloalkyl, C2-C18alkenyl, mesityl, phenyl, naphthyl; R3 is one of the radicals defined under R1; the process comprises the steps a) contacting e.g.Type: GrantFiled: November 14, 2005Date of Patent: March 30, 2010Assignee: Ciba Speciality Chemicals CorporationInventors: Peter Murer, Jean-Pierre Wolf, Stephan Burkhardt, Hansjörg Grützmacher, Daniel Stein, Kurt Dietliker
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Patent number: 7687220Abstract: The invention pertain to novel photoacid generator compounds of the formula I, II or III wherein R1 is for example C1-C18alkylsulfonyl or phenylsulfonyl, phenyl-C1-C3alkylsulfonyl, , naphthylsulfonyl, anthracylsulfonyl or phenanthrylsulfonyl, all optionally substituted, or R1 is a group X1, X2 and X3 independently of each other are O or S; R?1, is e.g. phenylenedisulfonyl, naphthylenedisulfonyl, diphenylenedisulfonyl, or oxydiphenylenedisulfonyl, all optionally substituted; R2 is halogen or C1-C10haloalkyl; X is halogen; Ar1 is for example biphenylyl or fluorenyl, or is substituted naphthyl; Ar?1 is heteroarylene, optionally substituted; R8, R9, R10 and R11 for example are C1-C6alkyl which is unsubstituted or substituted by halogen; or R8, R9 and R10 are phenyl which is unsubstituted or substituted by C1-C4alkyl or halogen; or R10 and R11 together are 1,2-phenylene or C2-C6alkylene which is unsubstituted or substituted by C1-C4alkyl or halogen.Type: GrantFiled: July 11, 2005Date of Patent: March 30, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Hitoshi Yamato, Toshikage Asakura, Tobias Hintermann
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Patent number: 7687451Abstract: This invention relates to thickened aqueous formulations containing cross-linked cationic polymers, novel homo- and copolymers, their production and their use as thickeners for household formulations.Type: GrantFiled: October 8, 2008Date of Patent: March 30, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Green, David Normington, Keith Graham, Gerhard Merkle, Emmanuel Martin
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Patent number: 7686877Abstract: The invention relates to pigmented tinting concentrates comprising a) stabilized pigments; b) humectant compounds obtainable by effecting a Diels Alder reaction at a temperature of 150-260° C. between a polyunsaturated compound and a co-reactant having the formula R1XOC—CH?CH—COXR2 or CH2?CH—COXR3 or CH2?CH(CH3)—COXR3 wherein X is oxygen or —NH— and wherein at least one of R1 and R2 is a polyether moiety and any other of R1 and R2 is a polyether moiety or hydrogen and R3 is a polyether moiety.Type: GrantFiled: May 8, 2006Date of Patent: March 30, 2010Assignee: Ciba CorporationInventors: Lothar Alexander Engelbrecht, Roedolph Van Bohemen, Frank Oliver Heinrich Pirrung
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Patent number: 7682439Abstract: The invention relates to a dispersing agent comprising: the reaction product of A one or more polyisocyanates having an average functionality of from 2.0 to 5, with B a mixture from B1 monohydroxyl compounds, and B2 monohydroxy-, monocarboxylic acid compounds to form an intermediate, followed by reacting the intermediate with C an unsaturated monohydroxy functional anchoring group.Type: GrantFiled: February 15, 2007Date of Patent: March 23, 2010Assignee: Ciba Corporation TarrytownInventors: Arend Noordam, Lothar Alexander Engelbrecht, Marcelles Van Der Sluis, Wendy Gezina Hof
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Patent number: 7674568Abstract: The present invention relates to a new solvent composition useful in the process of manufacturing an optical recording medium. The invention provides a new liquid composition comprising from 0.1 to 20% by weight of a dye having a solid state absorption band maximum in the spectral region from 300 to 800 nm, from 0.5 to 99.9% by weight of a compound of formula (I), wherein R1 to R8 are H, CH3 or C2H5, with the proviso that the total number of carbon atoms in R1 to R8 is 0, 1 or 2, and optionally from 0 to 99.4% by weight of one or more further components, all based on the weight of the solution. The instant solvent composition enables to manufacture an optical recording medium of a single recording layer type capable of recording and playing a large volume of information using commercially available compact disc recorders and players and of superior performance in an amazing wide range of drive speeds.Type: GrantFiled: January 21, 2003Date of Patent: March 9, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Bruce Milner, Jitka Brynjolffssen, Timothy Parks, Wolfgang Freitag
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Patent number: 7659238Abstract: This invention relates to fabric softener compositions comprising a fabric softener component or a mixture of fabric softener components and at least one polymer formed from the polymerization of c) a water soluble ethylenically unsaturated monomer or blend of monomers comprising at least one cationic monomer and/or at least one non-ionic monomer, d) a cross-linking agent or a mixture of cross-linking agents in an amount of less than 5 ppm by the weight of component a), and c) optionally at least one chain transfer agent, with the proviso that (i) if the polymer is a cationic homopolymer then the amount of the crosslinking agent is always more than 0 ppm, as thickeners, as well as to new fabric softener compositions.Type: GrantFiled: November 19, 2003Date of Patent: February 9, 2010Assignee: Ciba Specialty Chemicals Corp.Inventors: Emmanuel Martin, Keith Graham, David Normington, Malcolm Skinner
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Patent number: 7649077Abstract: The present invention relates to polymers comprising diazine, especially pyrimidine, containing repeating units. Optical devices, comprising the polymers of the present invention, can show significant advantages in color purity, device efficiency and/or operational lifetime. In addition, the polymers can have good solubility characteristics and relatively high glass transition temperatures, which facilitates their fabrication into coatings and films that are relatively thin, thermally stable, and relatively free of defects.Type: GrantFiled: October 21, 2003Date of Patent: January 19, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Robert Craig, Jonathan Rogers, Thomas Schäfer