Abstract: A selective process for the preparation of 1-aminoanthraquinones from the corresponding 1-aminoanthraquinone-2-carboxylic acid by decarboxylation in basic solution in the presence of iron, tin or zinc as a catalyst.

Abstract: A selective process for the preparation of 1-aminoanthraquinones from the corresponding 1-aminoanthraquinone-2-carboxylic acid by decarboxylation in an acid solution in the presence of iron or zinc as a catalyst.

Abstract: A process for preparing molded polyurethane-polyurea elastomers comprising reacting an organic polyisocyanate and a reactive polyol composition, said reactive polyol composition comprising(a) a polyol having an equivalent weight of from 700 to 4,000 and a functionality from 2 to 6; and(b) a reactive aromatic diamine which is soluble in said polyol at use temperatures and concentrations, has a pK.sub.b value greater than 10, and has the following structural formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, and R.sub.4 individually are radicals selected from the group consisting of hydrogen and alkyl radicals of 1 to 4 carbon atoms, and at least one of the alkyl radicals in each ring is a non-linear alkyl radical selected from the group consisting of isopropyl, isobutyl, and tertiary butyl radicals, and wherein R.sub.5 and R.sub.6 are radicals individually selected from the group consisting of hydrogen and alkyl radicals of 1 to 4 carbon atoms.

Abstract: Liquid detergent compositions which are free of phosphate builders and nitrosamine-forming triethanolamines previously used with approximately 9 to 15 percent of N,N,N',N'-tetrakis(2-hydroxypropyl)ethylene diamine or its equivalent.

Abstract: The subject matter of this invention pertains to polyurethane sealant compositions which are flexible, strong, and resistant to shrinkage. The sealants are prepared by reacting a mixture of polyether polyol and inorganic filler with a polyisocyanate. The polyurethane sealants are useful for making castings, for patching, and as heat barriers.

Abstract: The subject matter of this invention relates to the preparation of polyurethanes. It is particularly concerned with the use of certain organo-zirconium and organo-mercury compounds as co-catalysts in the preparation of polyurethanes.

Abstract: This invention relates to a process for preparing cellular polymers having urethane groups, isocyanurate groups, or both. The cellular polymers are prepared by reacting an organic polyisocyanate with certain polymer dispersions in the presence of a blowing agent.The polymer dispersions comprise(a) as a continuous phase, a polyol having a functionality of 2 to 8 and a hydroxyl number of 150 to 700; and(b) as a dispersed phase, an organic compound having(a) at least one Zerewitinoff active hydrogen atom,(b) a melting point of 30.degree. C. to 260.degree. C., and(c) a molecular weight of 178 to 100,000.

Abstract: 2,2-Bis(4-allyloxy-3,5-dibromophenyl)-propane is used as a flame-retardant synergist for polystyrene.

Abstract: A yellow pigment capable of withstanding elevated temperatures such as 200.degree. C. is provided by the formation of a spinel of iron and other metal, such as Mg, Zn, and Sn. The pigment is made by a method which does not involve a step of calcining at high temperature, such as 600.degree. to 1100.degree. C., but rather involves precipitation from aqueous solution and subsequent exposure to elemental oxygen, as by aeration, to form submicron-sized particles of desired spinel.

Abstract: This invention pertains to a process for the preparation of an aromatic di- and/or polyisocyanate comprising the steps ofA. preparing an aromatic di- and/or polyurethane by1. reacting a primary aromatic di- and/or polyamine with an O-alkyl carbamate at temperatures greater than 100.degree. C.;2. separating the ammonia and other by-products from the aromatic di- and/or polyurethane;B. heating and the aromatic di- and/or polyurethane at temperatures of from 175.degree. C. to 600.degree. C.; andC. isolating the di- and/or polyisocyanate resulting from step B.

Abstract: A pigment capable of withstanding elevated temperatures such as 175.degree. C. is provided by the formation of a spinel of iron and other metal, such as Cu, Ca, Cd, Co, Ba, Sr, Mg, Mn, and Li. The pigment is made by a method which does not involve a step of calcining at high temperature, such as 600.degree. C. to 1100.degree. C., but rather involves precipitation from aqueous solution and subsequent exposure to elemental oxygen, as by aeration, to form submicron-sized particles of desired spinel. Colors other than yellow may be obtained, and the spinels of Fe-Ba and Fe-Sr have magnetic properties.

Abstract: HR or high resiliency polyurethane foams having improved processing stability are prepared from reactive urethane formation promoting active hydrogen-containing compositions which have been pre-treated with carbon dioxide or a weak acid. The pre-treated active hydrogen-containing composition is, then, reacted with an organic polyisocyante to form the foams hereof.

Abstract: Polyamines are prepared by first reacting a polyoxyalkylene polyol having one to eight active hydrogen sites with an epihalohydrin. The resulting polyether is, then, reacted with an amine to replace the chlorine atoms with amine functions. The polyamines hereof are useful as intermediates for preparing cationic polyelectrolytes, such as drainage aids and the like.

Abstract: A process for separating hydrophobic organic liquids from water comprising passing a mixture of water and hydrophobic organic liquids through a column-like vessel which is filled with a hydrophobic, preferably open-celled, polyurethane foam, said foam having a high absorption capacity, permits high flow-through velocities even as the foam becomes covered and saturated with the hydrophobic organic liquids, is reversibly deformable, and can be reused.

Abstract: A process for the preparation of an aryl-mono and/or polyurethane comprising the steps ofA. reacting a primary aromatic mono, di-, and/or polyamine with an O-alkyl carbamate in the presence of alcohol and catalysts, andB. separating the ammonia and other by-products from the aliphatic and/or cycloaliphatic di- and/or polyurethane.The reaction is preferably carried out in the presence of urea. The aryl mono-, di-, and/or polyurethanes produced are valuable end and intermediate products. They can be transferred into the corresponding isocyanates which can then be used for the preparation of polyurethanes.

Abstract: This invention relates to an urethane group containing polyisocyanurate foam produced from a polyisocyanate and a polyhydroxy compound, wherein the polyhydroxy compound is the reaction mixture of a hydroxyl group containing amine which is at least difunctional and is selected from the group consisting of a secondary amine, a tertiary amine, and a mixture thereof, and a naphthenic acid, or a mixture of said reaction mixture and a conventional polyol, the reaction conditions are a temperature between 0.degree. C. and 150.degree. C. and an amino equivalent to carboxylic equivalent of 0.3:1 to 50:1.

Abstract: High molecular weight polyglycerol derivatives, useful as thickening agents for water-based lubricants, are prepared by oxyalkylating a polyglycerol with ethylene oxide or a mixture of ethylene oxide and propylene oxide. The polyglycerol derivatives are characterized as having an average of more than five glycerol units, and in having more than 95% and preferably more than 99% alkylene oxide units. These compounds exhibit excellent shear strength and provide an improved hydrolube when incorporated therein.

Abstract: Polyoxyalkylene polyamines are prepared by first reacting a polyoxyalkylene polyol or a polyoxyalkylene glycol monoether with a halogen-containing compound. The resulting halogenated ether is then aminated by the reaction therewith of a mono- or polyamine. The resulting products are substantially monoamine or polyamine derivatives depending upon the amine reactants. The resulting amines hereof are useful as intermediates for preparing cationic surfactants, cationic polymers and as fuel detergent additives.

Abstract: A monomeric reactant is adsorbed on the surface of a pigment prior to its agglomeration. The subsequent addition of a polymerization initiator or second reactant produces a coated pigment of improved dispersibility, especially in chemically related polymer binder systems.

Abstract: A process for the manufacture of a thermally insulating light stucco or plaster mixture which consists of expanded polystyrene particles coated with an aqueous solution of methyl cellulose in addition to cement, wall binder and dispersion powders.