Patents Represented by Attorney, Agent or Law Firm Joseph P. Fischer
  • Patent number: 6540825
    Abstract: The present invention describes the reaction product of an alkanolamine and a hydrocarbyl succinic anhydride compound useful in assisting the dispersion of pigments in aqueous and/or non-aqueous media.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: April 1, 2003
    Assignee: The Lubrizol Corporation
    Inventors: Robert E. Quinn, James S. Magyar
  • Patent number: 6403725
    Abstract: Disclosed is a metal containing polymer composition comprising; a metal overbased imide or ester functionalized polymer prepared by reacting (A) a polymer comprising (A1) an acidic functionalized polymer or ester functionalized polymer; (A2) an acidic mixed ester-acid of a carboxy containing interpolymer; or (A3) an ester functionalized polymer comprising a lactone and (B) a metal overbased composition that contains a reactive basic functionality comprising (B1) a metal overbased amine wherein the reactive basic functionality is a primary or secondary amino group; (B2) a metal overbased hydroxy substituted carboxylic acid wherein the reactive basic functionality is a hydroxy group; or (B3) a metal overbased dispersant wherein the reactive basic functionality is a primary or secondary amino group.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: June 11, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Nai Z. Huang, Richard M. Lange
  • Patent number: 6369162
    Abstract: A process for preparing a radial polymer comprising at least 3 polymeric arms and a central core comprising a polymerized di- or polyfunctional monomer, said process comprising the steps, (a) polymerizing at an elevated temperature, a charge comprising at least one free radical-polymerizable monomer to prepare a stabilized active polymer block (A) using a free radical polymerization process, wherein a stable free radical agent is employed during the polymerization, thereby preserving the stabilized active polymerization site at the terminus of the polymer; optionally (b) adding at least one additional free radical-polymerizable monomer, at least one of which is different from the monomers making up the first charge of monomers, to the stabilized active polymer block (A); and further reacting the mixture using a free radical process to effect copolymerization of said monomers, thereby preparing an A-B block copolymer having a stabilized active polymerization site at the terminus of the polymer; then (c) ad
    Type: Grant
    Filed: June 21, 2000
    Date of Patent: April 9, 2002
    Assignee: The Lubrizol Corporation
    Inventors: Daniel C. Visger, Richard M. Lange
  • Patent number: 6365558
    Abstract: A composition is disclosed which comprises (A) At least one oil comprising a synthetic triglyceride, a natural oil or a derivative of a natural oil; (B) a hydrogenated block copolymer comprising a normal block copolymer or a random block copolymer, said normal block copolymer made from a vinyl substituted aromatic and an aliphatic conjugated diene, said normal block copolymer having from two to about five polymer blocks with at least one polymer block of said vinyl substituted aromatic and at least one polymer block of said aliphatic conjugated diene, said random block copolymer made from vinyl substituted aromatic and aliphatic conjugated diene monomers, the total amount of said vinyl substituted aromatic blocks in said block copolymer being in the range of from about 20 percent to about 70 percent by weight and the total amount of said diene blocks in said block copolymer being in the range of from about 30 percent to about 80 percent by weight; the number average molecular weight of said normal block cop
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 2, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Kasturi Lal
  • Patent number: 6362374
    Abstract: The present invention is directed to a composition that contains polysulfides and that has a reduced odor level and to a method for reducing the odor of polysulfides. The composition contains a polysulfide and an inhibitor that reduces the odor level. The polysulfides include sulfurized olefins prepared by reacting the olefin with sulfur and H2S in the presence of a catalyst. The inhibitors are selected from the group consisting of hydrocarbyl acrylates and hydrocarbyl methacrylates. The method for reducing the odor level of polysulfides involves contacting the polysulfide with an inhibitor selected from the group consisting of hydrocarbyl acrylates and hydrocarbyl methacrylates under conditions that reduce the odor level.
    Type: Grant
    Filed: May 1, 2000
    Date of Patent: March 26, 2002
    Assignee: The Lubrizol Corporation
    Inventors: David R. Forester, Roger L. Sowerby, Bharat B. Malik, Victor A. Gober
  • Patent number: 6348075
    Abstract: The present invention is directed to a composition containing A) at least one polyalkenene substituted amine; and B) at least one hydrocarbyl-terminated poly(oxypropylene) monool represented by the formula wherein in formula (B-I), R is an alkyl or an alkyl-substituted aromatic group of about 8 to about 20 carbon atoms; x is a number from about 13 to about 28; and wherein the weight ratio of component (A) to component (B) ranges from about 10:1 to about 1:10. The composition is useful as a fuel additive for reducing intake valve deposits or for improving the valve stick performance of an internal combustion engine. The invention also relates to concentrates and fuel compositions containing the foregoing fuel additive composition and to a method for reducing intake valve deposits or for improving the valve stick performance of an internal combustion engine.
    Type: Grant
    Filed: April 14, 1998
    Date of Patent: February 19, 2002
    Assignee: The Lubrizol Corporation
    Inventor: Mitchell M. Jackson
  • Patent number: 6331603
    Abstract: A process for preparing nitrogen-containing copolymers useful as dispersant-viscosity improvers for lubricating oil compositions, additive concentrates and lubricating oil compositions are described.
    Type: Grant
    Filed: July 16, 1998
    Date of Patent: December 18, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Matthew R. Sivik, Charles P. Bryant
  • Patent number: 6299655
    Abstract: Diesel fuel oil compositions comprising high molecular weight, high total base number nitrogen containing dispersants provide exceptional diesel fuel injector cleanliness.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: October 9, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Thomas F. Steckel, Daniel T. Daly
  • Patent number: 6294628
    Abstract: A polyacrylate ester, and more particularly a polymethacrylate ester based dispersant-viscosity improver for lubricating oil compositions. Specifically, the dispersant viscosity improvers of this invention are nitrogen-containing copolymers comprising units derived from (A) from about 5% to about 75% by weight of alkyl acrylate ester monomers containing from 1 to 11 carbon atoms in the alkyl group; (B) from about 25% to about 95% by weight of alkyl acrylate ester monomers containing from 12 to about 24 carbon atoms in the alkyl group; and (C) from about 0.1% to about 20% by weight of at least one nitrogen containing monomer selected from the group consisting of vinyl substituted nitrogen heterocyclic monomers, N,N-dialkylaminoalkyl acrylate monomers, N,N-dialkylaminoalkyl acrylamide monomers and tertiary-alkyl acrylamides, provided that the total equals 100%. Processes for preparing the compositions, additive concentrates and lubricating oil compositions are described.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: September 25, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Charles P. Bryant, Bryan A. Grisso, Robert Cantiani
  • Patent number: 6288013
    Abstract: A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently selected from members of the group consisting of: groups of the formula wherein R3 is H or hydrocarbyl, R4 is a divalent hydrocarbylene group, n=0 or 1, and each of R9 and R10 is independently H, alkoxyhydrocarbyl, hydroxyhydrocarbyl, hydrocarbyl, aminohydrocarbyl, N-alkoxyalkyl- or hydroxyalkyl-substituted aminohydrocarbyl, or a group of the formula &Parenopenst;Y&Parenclosest;cR11—M, wherein each Y is independently a group of the formula each R11 is a divalent hydrocarbyl group, R12 is as defined above for R9 and R10, and M is H, hydrocarbyl, amino, an amide group, an amide-containing group, an acylamino group, an imide group, or an imide-conta
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: September 11, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Matthew R. Sivik, Richard M. Lange, Paul E. Adams, Daniel M. Vargo
  • Patent number: 6271184
    Abstract: A copolymer comprising units derived from (a) methaciylic acid esters containing from about 9 to about 25 carbon atoms in the ester group and (b) methacrylic acid esters containing from 7 to about 12 carbon atoms in the ester group, said ester groups having 2-(C1-4 alkyl)-substituents, and optionally (c) at least one monomer selected from the group consisting of methacrylic acid esters containing from 2 to about 8 carbon atoms in the ester group atoms and which are different from methacrylic acid esters (a) and (b), vinyl aromatic compounds, and nitrogen-containing vinyl monomers with the proviso that no more than 60% by weight of the esters contain not more than 11 carbon atoms in the ester group. Also described are additive concentrates and lubricating oil compositions containing the copolymers and processes for preparing copolymers.
    Type: Grant
    Filed: June 30, 2000
    Date of Patent: August 7, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Joseph G. Seebauer, Charles P. Bryant
  • Patent number: 6268318
    Abstract: A.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: July 31, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Allen J. Rolfes, Scot Eric Jaynes
  • Patent number: 6265358
    Abstract: A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula —Q—Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k≧2, groups —K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarb
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: July 24, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Carmen V. Luciani, Richard M. Lange, Daniel M. Vargo
  • Patent number: 6258761
    Abstract: A composition prepared by reacting (A) an esterified carboxy-containing interpolymer, said interpolymer being derived from at least two monomers, (i) one of said monomers being at least one vinyl aromatic monomer and (ii) the other of said monomers being at least one alpha, beta-unsaturated acylating agent, and having, before esterification, {overscore (M)}n determined by gel permeation chromatography ranging from about 8,000 to about 350,000, wherein from about 80% to about 99% of the carboxylic groups of said interpolymer are esterified, wherein from about 80 to about 100% of the ester groups contain from 8 to about 23 carbon atoms and from 0 to about 20% of the ester groups contain from 2 to 7 carbon atoms, with (B) a hydrocarbyl substituted carboxylic acid or functional derivative thereof wherein the hydrocarbyl group comprises from about 10 to about 400 carbon atoms, and (C) an amine having an average of more than 1 condensable N—H group, in any order or simultaneously, or with the preformed reac
    Type: Grant
    Filed: June 10, 1999
    Date of Patent: July 10, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Richard M. Lange, James R. Shanklin, Jr., Jeffry G. Dietz, Richard Yodice, Naresh C. Mathur
  • Patent number: 6235068
    Abstract: A fuel composition, comprising: a marine diesel fuel; and a liner lacquering reducing amount of a hydrocarbyl-substituted sulphonic acid. This invention also relates to a process for reducing liner lacquering in a marine diesel engine, comprising operating the diesel engine using the foregoing fuel composition.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: May 22, 2001
    Assignee: The Lubrizol Corporation
    Inventor: David John Moreton
  • Patent number: 6211122
    Abstract: A carboxylic composition comprising hydrocarbon substituted carboxylic acylating agents prepared by reacting a polyolefin and a terpolymer, simultaneously or individually in any order, with at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5 (IV) wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof, derivatives of the foregoing carboxylic compositions, with one or more of (1) an amine characterized by the presence within its structure of at least one HN<group; (2) an alcohol; (3) a reactive metal or a reactive metal compound; and (4) a mixture of two or more of (1) through (3); the components of (4) being reacted with the mixture of carboxylic acylating agents simultaneously or sequentially, in any order, and additive concentrates and lubricating oil and fuel compositions containing these compositions.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: April 3, 2001
    Assignee: The Lubrizol Corporation
    Inventors: John K. Pudelski, Jeffry G. Dietz, Matthew R. Sivik
  • Patent number: 6207839
    Abstract: A process for reacting olefinic compounds, certain carboxylic reactants, and aldehydes or ketones and products prepared by the process. The compositions of the process are useful as intermediates for the preparation of additives for lubricants and fuels.
    Type: Grant
    Filed: August 5, 1998
    Date of Patent: March 27, 2001
    Assignee: The Lubrizol Corporation
    Inventor: Mark R. Baker
  • Patent number: 6200398
    Abstract: Water in oil emulsion explosive compositions comprises a discontinuous aqueous phase comprising at least one oxygen-supplying component, a continuous organic phase, an emulsifying amount of an emulsifier composition comprising: the reaction product of an amine (C) characterized by the presence within its structure of at least one H—N group and an intermediate formed in the reaction of (A) at least one olefinic compound containing at least one group of the formula  and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5  (III)  wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of (D) at least one aldehyde or ketone; and optionally a sensitizer.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: March 13, 2001
    Assignee: The Lubrizol Corporation
    Inventor: James H. Bush
  • Patent number: 6176893
    Abstract: Non-explosive water in oil emulsion fertilizer compositions comprise a discontinuous aqueous phase comprising at least one fertilizer component, a continuous organic phase, an emulsifying amount of an emulsifier composition comprising: the reaction product of an amine (C) characterized by the presence within its structure of at least one H—N group and an intermediate formed in the reaction of (A) at least one olefinic compound containing at least one group of the formula and (B) at least one carboxylic reactant selected from the group consisting of compounds of the formula R3C(O)(R4)nC(O)OR5   (III) wherein each of R3 and R5 is independently H or a hydrocarbyl group, R4 is a divalent hydrocarbylene group, and n is 0 or 1, and reactive sources thereof and optionally, from about 0.5 to about 2 moles, per mole of (B), of (D) at least one aldehyde or ketone. The fertilizer compositions provide for controlled release of the fertilizer components.
    Type: Grant
    Filed: December 30, 1998
    Date of Patent: January 23, 2001
    Assignee: The Lubrizol Corporation
    Inventor: James H. Bush
  • Patent number: 6172122
    Abstract: A stable emulsion composition is disclosed which comprises: (A) a metal overbased gelled composition, prepared by forming a mixture of (i) a carbonated overbased material in an oleophilic medium, which material contains a metal salt of at least one organic acid material containing at least 8 carbon atoms, and (ii) an alcohol or an alcohol-water mixture; (B) a surfactant; and (C) an aqueous liquid. The stable emulsion composition may further comprise at least one of a solute, a suspended solid or an oxidation inhibitor.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: January 9, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Saurabh S. Lawate, William R. Sweet