Abstract: A process involving the reaction of pentaerythritol with phosphorus oxychloride. A solvent is used in the process, but not catalyst or amine (as a hydrogen chloride acceptor) is required.
Abstract: Organic zerovalent nickel complexes wherein the organic portion is derived from an ester of pentaerythritol phosphite. The complexes are believed to have a tetrahedral structure; one nickel atom is complexed with four molecules of the pentaerythritol phosphite ester. The nickel complexes are useful as polymer additives, being effective to impart improved resistance to deterioration of olefin polymers upon exposure to ultraviolet light.
Type:
Grant
Filed:
August 9, 1982
Date of Patent:
May 22, 1984
Assignee:
Borg-Warner Chemicals, Inc.
Inventors:
Ingenuin Hechenbleikner, William P. Enlow, David C. Lankin
Abstract: An asbestos-free friction material characterized by good friction and wear properties. It comprises the combination of a binder resin, copper oxide, antimony sulfide and an aromatic polyamide resin. Barytes is also a valuable additive in the combination.
Type:
Grant
Filed:
March 21, 1983
Date of Patent:
May 1, 1984
Assignee:
Borg-Warner Corporation
Inventors:
Howard S. Okubo, Clarence E. Albertson, Roger K. Nibert
Abstract: A process for preparing 5,5-bis(halomethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinanes by hydrolysis of the corresponding phosphoryl chloride. The product is effective, in small proportions, to impart flame-retardant properties to polymer compositions, especially polypropylene and styrenic polymers.
Abstract: Aromatic, phenol-free polyphosphites containing at least two pentaerythritol residues and three bis-phenolic residues. They are effective polymer additives and are especially useful in enhancing the thermal stability of polypropylene.
Type:
Grant
Filed:
June 22, 1981
Date of Patent:
November 1, 1983
Assignee:
Borg-Warner Chemicals, Inc.
Inventors:
Leo L. Valdiserri, Ingenuin Hechenbleikner
Abstract: An olefin polymer composition having improved stability to deterioration resulting from exposure to ultraviolet radiation. The enhanced stability results from the effective presence of a combination of an organic phosphite ester and a hydroxybenzophenone.
Abstract: An olefin polymer composition containing an ultraviolet light stabilizer. The ultraviolet light stabilizer is a zerovalent nickel complex the organic portion of which is an ester of pentaerythritol phosphite.
Abstract: An asbestos-free friction material containing "soft" glass fibers. The friction material, in a clutch or brake apparatus, is characterized by unusually smooth, quiet, vibrationless operation.
Abstract: An ultraviolet stabilizer for olefin polymers. It is a combination of a 2-hydroxyphenylbenzotriazole, a bis-(dialkylphenyl)pentaerythritol diphosphite.
Abstract: Poly(alkylene terephthalate) compositions containing a stabilizing proportion of a pentaerythritol diphosphite ester. The compositions are relatively stable under usual processing conditions which include high temperatures. Color formation, molecular degradation and acetaldehyde contamination are inhibited significantly.
Abstract: Certain phosphite-isocyanurate oligomers and their use as thermal stabilizers in polymer compositions. The phosphite-isocyanurates may be prepared from a tris-hydroxyalkyl isocyanurate by reaction with an organic phosphite such as triphenyl phosphite or tributyl phosphite. Optionally, an alcohol such as decyl alcohol may be employed as a reactant.
Abstract: Polymer compositions containing minor proportions of polyvalent metal or amine salts of 5,5-bis-(bromomethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinane. Aluminum, calcium and melamine salts are preferred.
Abstract: Polymer compositions containing minor proportions of a 5,5-bis-(halomethyl)-2-hydroxy-2-oxo-1,3,2-dioxaphosphorinane. The halo atom may be either chlorine or bromine.
Abstract: A blend of polystyrene, a block copolymer of styrene and certain conjugated diolefins, and a graft copolymer of styrene, acrylonitrile, and butadiene. Methyl methacrylate may be substituted for all or a portion of the acrylonitrile. The blend retains the good qualities of the individual polymers and is characterized by a stable compatibility.
Abstract: A process for the preparation of mixed aromatic-aliphatic phosphites. The process involves the reaction of an alkylphenol with diphenyl-(or a lower dialkyl-) pentaerythritol diphosphite. The process is simple and inexpensive, and produces a relatively pure product.
Abstract: A lead-free, fiberizable glass composition. The glass is characterized by a relatively low hardness rating and is accordingly useful in preparing friction surfaces. Its composition includes, on a weight basis, from about 45% to about 75% of silicon dioxide, from about 15% to about 30% of potassium oxide and from about 2% to about 10% of magnesium oxide.
Abstract: An olefin polymer composition containing a cyclic, hindered amine in combination with an organic phosphite ester. The composition is relatively stable in the presence of ultraviolet light.
Abstract: An improved polymer additive characterized by excellent stability to hydrolysis. Dialkyl pentaerythritol diphosphites are encapsulated in a petroleum or ester wax and thereby rendered relatively immune to decomposition under ordinary conditions of storage. At the same time, the wax coating is sufficiently low melting as to present no problem during milling operations at elevated temperatures, for example, where the heat stabilizing qualities of the dialkyl pentaerythritol diphosphite are required.
Type:
Grant
Filed:
August 24, 1979
Date of Patent:
November 10, 1981
Assignee:
Borg-Warner Chemicals, Inc.
Inventors:
Ved K. Sahajpal, Jacques Delaere, Zigmunt K. Kromolicki, Mattheus R. Settels