Abstract: The invention provides new magenta-dye-forming couplers, new magenta dyes formed therefrom, and new photographic elements containing the new couplers. The new couplers have the structure (I):Q--G--Q.sub.(I)wherein --G-- has the structure (II):--L--NH--SO.sub.2 --R--SO.sub.2 -NH--L--.sub.(II)wherein --R-- is substituted or unsubstituted alkylene, alkoxylene, arylene, or aryloxylene, andeach --L-- is independently substituted or unsubstituted alkylene, alkoxylene, arylene, aryloxylene, or aryloxyalkylene, andQ-- has the structure (III ): ##STR1## wherein: each R.sup.1 -- is independently H-- or a substituent; each X-- is independently H-- or a coupling-off group; andeach of D, E, and Z is independently a substituted or unsubstituted methine group, .dbd.
Type:
Grant
Filed:
December 17, 1993
Date of Patent:
October 25, 1994
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Terrence C. Mungal, Philip T. S. Lau, Stanley W. Cowan
Abstract: The invention provides new yellow-dye-forming couplers, new yellow dyes formed therefrom, and new photographic elements containing the new couplers. The new couplers have the structure (I): ##STR1## wherein ##STR2## has the structure (II) ##STR3## wherein each --R-- is independently a substituted or unsubstituted alkylene, alkoxylene, arylene, or aryloxylene group, and Q-- has the structure (III): ##STR4## wherein: each R.sup.1 -- is independently t-butyl or a substituted aryl group;each Z-- is independently H--, halo, or a substituted or unsubstituted alkyl, aryl, alkoxy, or aryloxy group; andeach X-- is independently H-- or a coupling-off group.
Type:
Grant
Filed:
December 17, 1993
Date of Patent:
October 25, 1994
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Philip T. S. Lau, Stanley W. Cowan
Abstract: The invention provides new yellow-dye-forming couplers, new yellow dyes formed therefrom, and new photographic elements containing the new couplers. The new couplers have the structure (I): ##STR1## wherein ##STR2## has the structure (II) ##STR3## wherein each --R-- is independently a substituted or unsubstituted alkylene, alkoxylene, arylene, or aryloxylene group, and Q-- has the structure (III): ##STR4## wherein: each R.sup.1 -- is independently t-butyl or a substituted aryl group;each Z-- is independently H--, halo, or a substituted or unsubstituted alkyl, aryl, alkoxy, or aryloxy group;each M-- is independently H-- or a substituent; and each R.sup.2 -- is independently H-- or a substituent.
Type:
Grant
Filed:
December 17, 1993
Date of Patent:
October 25, 1994
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Philip T. S. Lau, Stanley W. Cowan
Abstract: The invention provides new magenta-dye-forming couplers, new magenta dyes formed therefrom, and new photographic elements containing the new couplers. The new couplers have the structure (I): ##STR1## wherein ##STR2## has the structure (II) ##STR3## wherein each --R-- is independently a substituted or unsubstituted alkylene, alkoxylene, arylene, or aryloxylene group, andeach --L-- is independently a substituted or unsubstituted alkylene, alkoxylene, arylene, aryloxylene, or aryloxyalkylene group, and Q-- has the structure (III): ##STR4## wherein: each R.sup.1 -- is independently H-- or a substituent; each X-- is independently H-- or a coupling-off group; andeach of D, E, and Z is independently a substituted or unsubstituted methine group, .dbd.
Type:
Grant
Filed:
December 17, 1993
Date of Patent:
October 25, 1994
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Philip T. S. Lau, Stanley W. Cowan
Abstract: Dye-forming couplers provided by the invention are tris coupler compounds, each comprising three coupling moieties bonded to a phosphorous-containing tris linking group represented by ##STR1## has the structure (I): ##STR2## wherein each --R-- is independently a substituted or unsubstituted alkylene, alkoxylene, arylene, or aryloxylene group. Dyes of the invention are the dyes that are formed by coupling reaction of an oxidized photographic color developing agent and the new tris couplers of the invention. Photographic elements of the invention each comprise a support having thereon a photographic silver halide emulsion layer and one or more of the new tris couplers of the invention.
Type:
Grant
Filed:
December 17, 1993
Date of Patent:
August 23, 1994
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Philip T. S. Lau, Stanley W. Cowan
Abstract: A color negative photographic recording material is described in which low emulsion coverage tabular grain silver halide emulsion imaging units are employed. The silver halide emulsion in at least one of the units comprises grains having a tabularity of between about 50 and 25,000. The imaging unit thickness is less than about 4.0 .mu.m, using a total of no more than 2.0 parts by weight of silver per part of coupler. The imaging unit yields a density of at least 2.0 when exposed and processed.
Type:
Grant
Filed:
January 19, 1993
Date of Patent:
June 21, 1994
Assignee:
Eastman Kodak Company
Inventors:
Allan F. Sowinski, George F. Wu, Thomas B. Brust, James T. Kofron, Gary L. House
Abstract: There are described a method for retouching photographic images, compositions adapted for such retouching, and photographic elements containing dye-forming couplers that yield dye images that particularly lend themselves to retouching by this method. The method comprises contacting a photographic element containing a dye image with a defined retouching composition to solubilize and remove selected areas or amounts of dye. The composition comprises an aqueous basic solution of a dinucleophile and a water-soluble organic co-solvent. The preferred photographic element for application of this retouching method comprises a dye image formed from a pyrazoloazole magenta dye forming coupler having a cleavable ballast group joined to the remainder of the molecule by one or two electrophilic cleavage groups. The retouching composition cleaves the ballast from the dye and solubilizes the dye, allowing it to be washed from the element.
Type:
Grant
Filed:
April 23, 1992
Date of Patent:
March 22, 1994
Assignee:
Eastman Kodak Company
Inventors:
J. Ramon Vargas, John W. Harder, Phillip D. Knight, Paul A. Burns, Lynda D. Weber
Abstract: There are described color photographic elements containing novel release compounds which rapidly release a photographically useful group, such as a development inhibitor, from a timing group.
Abstract: The critical dimensions of product samples made during a standard certification procedure for an injection molding process are measured and a loss factor value is computed for each such dimension. Using statistical techniques, the largest loss factor value is partitioned into percentages of loss contributed by a predetermined set of loss elements. The loss element contributing the largest percentage is corrected so as to improve the quality of the process and the product. The method provides a way of determining what kinds of process corrections will most effectively improve product and process quality.
Type:
Grant
Filed:
April 7, 1992
Date of Patent:
September 21, 1993
Assignee:
Eastman Kodak Company
Inventors:
James J. Wenskus, Jr., Michael W. Dupin
Abstract: Room light handleable direct reversal silver bromide emulsions, with up to 70 mole percent chloride, have a broad Dmin window when from 1.times.10.sup.-6 to 1.times.10.sup.-4 mole per silver mole of a polybromo coordination complex of iridium is incorporated in the silver halide grains. The emulsions are stabilized against deterioration on keeping with mercapto compounds.
Type:
Grant
Filed:
September 10, 1990
Date of Patent:
August 31, 1993
Assignee:
Eastman Kodak Company
Inventors:
Gaile A. Janusonis, Francis R. Hilton, Jr., Richard D. Lucitte, Woodrow G. McDugle, Roger Lok, David Erdtmann
Abstract: An injection molding machine control device where mold element separation distance is measured and integrated as a function of time while moldable material is being introduced in the mold cavity between the mold elements. When the integral value reaches a preselected value, the mold injection pressure is changed and the moldable material is allowed to cure within the cavity.
Abstract: Photographic elements are described containing a polymeric dye-forming coupler that has been formed by emulsion polymerization of ethylenically unsaturated monomers in the presence of a high-boiling organic coupler solvent. Couplers of high activity are obtained.
Type:
Grant
Filed:
March 2, 1990
Date of Patent:
August 17, 1993
Assignee:
Eastman Kodak Company
Inventors:
Ping-Wah Tang, Philip T. S. Lau, Stanley W. Cowan
Abstract: Certain development inhibitor releasing compounds when incorporated in a photographic element at low levels provide development acceleration. The compounds release silver halide binding groups that are substituted with a group containing an ether oxygen atom and/or an imino nitrogen atom. They are especially useful in high speed color photographic materials.
Type:
Grant
Filed:
December 13, 1990
Date of Patent:
June 22, 1993
Assignee:
Eastman Kodak Company
Inventors:
Richard P. Szajewski, Jerrold N. Poslusny
Abstract: A color negative photographic recording material is described in which low emulsion coverage tabular grain silver halide emulsion imaging units are employed. The silver halide emulsion in at least one of the units comprises grains having a tabularity of between about 50 and 25,000. The imaging unit thickness is less than about 4.0 .mu.m, using a total of no more than 2.0 parts by weight of silver per part of coupler. The imaging unit yields a density of at least 2.0 when exposed and processed.
Type:
Grant
Filed:
January 30, 1992
Date of Patent:
June 15, 1993
Assignee:
Eastman Kodak Company
Inventors:
Allan F. Sowinski, George F. Wu, Thomas B. Brust, James T. Kofron, Gary L. House
Abstract: In a curtain coating apparatus for the coating of photographic film and paper webs and the like, the line of impingement of the curtain on the moving web is controlled by providing a pressure controlled zone on one side of the flowing curtain. Small changes in the static air pressure in the zone cause the position of the curtain to move without disturbing the quality of the curtain. Wetted side walls of the pressure controlled zone can serve as edge guides for the curtain.
Type:
Grant
Filed:
January 10, 1992
Date of Patent:
April 27, 1993
Assignee:
Eastman Kodak Company
Inventors:
Douglas S. Finnicum, Kenneth J. Ruschak, Steven J. Weinstein
Abstract: A method and an apparatus for monitoring the process stability of an injection molding machine having a reciprocating screw engaged in the plasticating of a moldable material in preparation to its being introduced into the mold cavity. The invention involves the measurement of the duration of the operation of the screw engaged in the plasticating of the moldable material and includes the analysis of this duration over a period of time thus providing the supervisor with the necessary information to determine whether the machine/process is meeting or deviating from the desired operating requirements.
Abstract: A method and apparatus for continuously liquefying a gelled photographic material for coating on a substrate is disclosed. The material is advanced throughout the liquefaction apparatus and on to the substrate coating system as a substantially undisrupted mass. The technique is particularly useful for liquefying small amounts of material at a time, because system hold-up volume and waste is minimized.
Type:
Grant
Filed:
November 14, 1990
Date of Patent:
March 9, 1993
Assignee:
Eastman Kodak Company
Inventors:
Donald E. Eaton, James K. Toner, Daniel J. Wooster
Abstract: An apparatus for degassing a continuously flowing liquid stream comprising an air-tight housing, in which is mounted for rotation a centrifuge bowl of circular cross-section and having an inner surface for spreading centrifugally impelled liquid to be degassed and an annular peripheral trough for retaining centrifugally impelled degassed liquid. The liquid stream is fed into the bowl and the degassed liquid is withdrawn through a tube extending from an exit line outside the housing to an open end of elongate cross-section which is positioned within the trough of the bowl and is immersible in the degassed liquid. The apparatus further provides for measuring the pressure of the exiting degassed liquid, the pressure measurement being used to regulate the flow of liquid into the bowl so as to maintain a substantially constant level of liquid therein.
Type:
Grant
Filed:
January 13, 1992
Date of Patent:
March 2, 1993
Assignee:
Eastman Kodak Company
Inventors:
Donald E. Eaton, Errol S. Francis, Eric L. Dillenbeck, Lawrence D. Meston, Walter Johannes
Abstract: There is described a system and method for reproducing an original record using a narrow band filter, such as a dichroic filter, to modify the contrast of the reproduction without modifying the color balance or the wavelength peak of sub-reocrds. The system is particularly useful in reproducing motion picture records where a multiplicity of additive lamp houses can be employed. The system reduces variations in contrast and color reproduction among different additive lamp houses.
Type:
Grant
Filed:
February 13, 1992
Date of Patent:
February 2, 1993
Assignee:
Eastman Kodak Company
Inventors:
Mary L. Schmoeger, Charles P. Hagmaier, Jr., Mitchell J. Bogdanowicz, Christopher L. DuMont, Richard C. Sehlin
Abstract: A new film cassette assembly comprises a thrust type cassette and a roll of a photographic film having particular properties. One such property is a low coefficient of friction between the emulsion side and back side of the film. In preferred embodiments the film has a stiffness sufficient to avoid buckling of the film when the film spool is rotated in the unwinding direction and is very thin. Most preferably, it is formed from a hydrophilic copolyester having the desired stiffness.
Type:
Grant
Filed:
May 6, 1991
Date of Patent:
December 22, 1992
Assignee:
Eastman Kodak Company
Inventors:
David A. Dieterich, David B. Kemp, Christopher T. Mattson