Patents Represented by Attorney Karl D. Dreher
  • Patent number: 3954627
    Abstract: Compositions containing lamellar micelles and which exhibit retro-viscous property at noncryogenic temperatures are prepared by mixing 4-15 percent of a surfactant (preferably an alkaryl sulfonate having an average equivalent weight of 350-525), 30-70 percent of a liquid hydrocarbon, 15-66 percent of water and optionally up to 20 percent of a cosurfactant, preferably an alcohol containing 1-20 carbon atoms, and/or electrolyte (preferably inorganic salt). The micelles have an axial ratio of at least 3.5 and preferably the composition has a viscosity of at least 75 cp. at a shear rate of 10 sec.sup.- .sup.1 at 23.degree.C. The composition is substantially optically clear, phase stable, birefringent, and the flow properties are such that substantially large increases in flow rate, e.g. 20-fold, can be realized at very small increases in pressure drop, e.g. 5 percent. Uses for the compositions include stimulation of wells (e.g.
    Type: Grant
    Filed: November 7, 1973
    Date of Patent: May 4, 1976
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty
  • Patent number: 3950034
    Abstract: An improved method of pipelining solids is effected by suspending the solids in a liquid containing lamellar micelles and pumping the mixture at flow rates predetermined to produce retro-viscous behavior in the liquid at noncryogenic temperatures. The liquid is a composition containing 4-15% surfactant (preferably petroleum sulfonate having an average equivalent weight of 350-525), and at least two substantially immiscible liquids (e.g. 30-70% liquid hydrocarbon and 15-66% water) and optionally up to 20% cosurfactant (preferably an alcohol containing 1-20 carbon atoms) and/or electrolyte (preferably inorganic salt). The micelles have an axial ratio of at least 3.5. Preferably, the composition has a viscosity of at least 75 cp at a shear rate of 10.sup.-.sup.1 seconds at 23.degree.C. The composition is substantially optically clear, phase stable, birefringent, and the flow properties are such that substantially large increases in flow rates, e.g. 20-fold, can be realized at very small pressure increases, e.g.
    Type: Grant
    Filed: November 23, 1973
    Date of Patent: April 13, 1976
    Assignee: Marathon Oil Company
    Inventors: Karl D. Dreher, William B. Gogarty