Abstract: A composition comprises nickel and a support material which comprises aluminum borate and zirconium borate. In one embodiment, this composition additionally comprises rhenium. Preferably, the catalyst support material is a coprecipitate of aluminum borate and zirconium borate.The above-described composition is employed as a catalyst for hydrogenating aromatic hydrocarbons to saturated hydrocarbons.
Abstract: A selective hydrogenation of an alkyne in an olefin-containing fluid is provided which comprises contacting the fluid and hydrogen gas with a catalyst in the presence of at least one sulfur compound, under reaction conditions effective to produce at least one alkene wherein the catalyst comprises at least one alkali metal, fluorine and an inorganic support material.
Type:
Grant
Filed:
July 23, 1996
Date of Patent:
December 16, 1997
Assignee:
Phillips Petroleum Company
Inventors:
Scott H. Brown, James B. Kimble, Stan A. Zisman
Abstract: A process for hydrodealkylating C.sub.9 -C.sub.12 alkyl-substituted benzenes (preferably trimethylbenzenes) to C.sub.6 -C.sub.8 aromatic hydrocarbons (in particular, toluene and xylenes) and C.sub.1 -C.sub.5 alkanes employs a catalyst containing zeolite Beta, nickel, molybdenum and sulfur (preferably as sulfides of nickel and of molybdenum).
Type:
Grant
Filed:
April 24, 1996
Date of Patent:
November 18, 1997
Assignee:
Phillips Petroleum Company
Inventors:
An-hsiang Wu, Charles A. Drake, Ralph J. Melton
Abstract: Cyclopentadiene is separated from dicyclopentadiene by means of a sorbent material which contains (i) alkali metal oxide(s) and/or hydroxide(s) and (ii) an inorganic support material. The more preferred sorbent material is Na.sub.2 O and/or NaOH on alumina.
Type:
Grant
Filed:
May 7, 1996
Date of Patent:
August 19, 1997
Assignee:
Phillips Petroleum Company
Inventors:
Tin-Tack Peter Cheung, Marvin M. Johnson
Abstract: A Group VIII metal-promoted zeolite (preferably Pt-promoted H-mordenite) is contacted with ammonium hexafluorosilicate and hydrogen gas at a temperature of about 100.degree.-450.degree. C. The obtained material is an effective catalyst for the transalkylation of aromatic hydrocarbons.
Abstract: C.sub.2 -C.sub.6 alkynes (preferably acetylene) contained in feeds which also contain sulfur impurities are hydrogenated to the corresponding alkenes in the presence of a supported palladium catalyst which has been promoted with alkali metal fluoride (preferably potassium fluoride). A specific cataylst consists essentially of a palladium component, at least one alkali metal fluoride (preferably KF) and an inorganic support material (preferably alumina).