Patents Represented by Attorney Karl Stauss
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Patent number: 7638561Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous vehicle, a self-dispersed pigment, a silicone-containing surfactant and an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C. Also provided is a method for printing an image on a hydrophobic substrate.Type: GrantFiled: June 8, 2005Date of Patent: December 29, 2009Assignee: Rohm and Haas CompanyInventors: Zhenwen Fu, Hailan Guo, Michael Hallden-Abberton, Himal H. Ray
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Patent number: 7338988Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C.; a pigment; and a water-soluble surface agent is provided. Also provided is a method for providing an image on a hydrophobic surface and the image so provided.Type: GrantFiled: November 3, 2003Date of Patent: March 4, 2008Assignee: Rohm and Haas CompanyInventors: Carl Michael Hesler, Eric Alvin Johnson
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Patent number: 7241834Abstract: An aqueous acrylic emulsion polymer including, as copolymerized units, 70 to 99.5% by weight, based on dry polymer weight, monoethylenically unsaturated nonionic (meth)acrylic monomer and from 0.3 to 10% by weight, based on dry polymer weight, monoethylenically unsaturated acid monomer, wherein at least 40% by weight, based on dry polymer weight, of the emulsion polymer is formed by redox polymerization in the presence of 0.001 to 0.05 moles chain transfer agent per kg dry polymer weight is provided. An aqueous coating composition including the acrylic emulsion polymer, a method for improving the scrub resistance of a dry coating, a method for improving the adhesion of a dry coating, and a method for improving the adhesion of a dry coating to an alkyd substrate are provided.Type: GrantFiled: March 31, 2005Date of Patent: July 10, 2007Assignee: Rohm and Haas CompanyInventor: Ralph Craig Even
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Patent number: 7074842Abstract: An inkjet ink binder composition including an emulsion polymer, the polymer including as polymerized units 1–10%, by weight based on dry polymer weight, of a monomer selected from the group consisting of methylol acrylamide, methylol methacrylamide, methyl acrylamidoglycolate methyl ether, acrylamidoglycolic acid, and mixtures thereof is provided. An inkjet ink composition including the emulsion polymer, a liquid medium, and a pigment and a method for improving the durability of inkjet ink printed on a substrate are also provided.Type: GrantFiled: January 23, 2003Date of Patent: July 11, 2006Assignee: Rohm and Haas CompanyInventors: Chao-Jen Chung, Maureen Joanne Finley, Zhenwen Fu
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Patent number: 7025820Abstract: A method for forming an aqueous carbon black dispersion including providing a reaction mixture including carbon black having a DBP uptake of greater than 90 cc/100 g of the carbon black, a monovalent ion persulfate, an aqueous medium, and, in some embodiments, a strong acid; subjecting the reaction mixture to a first temperature of from 40° C. to 90° C. for from 2 hours to 24 hours; neutralizing the reaction mixture to a pH greater than 7.0, and, in certain embodiments, subjecting the neutralized reaction mixture to a second temperature of from 20° C. to 40° C. higher than the first temperature for from 2 hours to 12 hours is provided. In an alternative aspect carbon black having a particle diameter less than 18 nanometers in diameter and a DBP uptake of less than 70 cc/100 g carbon black is provided. The aqueous carbon black dispersion so formed and an aqueous inkjet ink containing the aqueous carbon black dispersion are also provided.Type: GrantFiled: November 3, 2003Date of Patent: April 11, 2006Assignee: Rohm and Haas CompanyInventors: Tabb Robertson Champlin, Stephen Andrew Crescimanno, Eric Jon Langenmayr, Richard Shu-Hua Wu
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Patent number: 6986808Abstract: Ink compositions having increased stability and increased jettability with the addition of specific surfactants, including alkyl ether sulfates and ethoxylated mercaptans, are provided. The remainder of the ink composition comprises a suitable carrier vehicle, which typically contains water, alcohols, surfactants, humectants and optionally a resin component.Type: GrantFiled: December 9, 2003Date of Patent: January 17, 2006Assignee: Rohm and Haas CompanyInventors: Zhenwen Fu, Louis Christopher Graziano
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Patent number: 6896212Abstract: A method of using polymeric grinding media to produce fine solid particles or fine solid dispersions in liquid, such as pigment dispersions for inks, is provided. The method of the present invention limits packing and plugging problems associated with polymeric media to allow efficient milling operation.Type: GrantFiled: September 4, 2003Date of Patent: May 24, 2005Assignee: Rohm and Haas CompanyInventors: Vere Orland Archibald, Richard Shu-Hua Wu
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Patent number: 6756459Abstract: A binder composition for aqueous coatings that exhibit high gloss and superior corrosion resistance when applied to metal substrates comprising an aqueous emulsion copolymer, the copolymer including as polymerized units, at least one ethylenically unsaturated monomer and an ethylenically unsaturated strong acid monomer, such as phosphorus containing monomers, particularly phosphoethylmethacrylate; or salts thereof. Also provided is a method for achieving high gloss and superior corrosion resistance of metal substrates by coating a substrate with an aqueous coating composition comprising the binders of the present invention and drying, or allowing to dry, the aqueous composition.Type: GrantFiled: September 12, 2001Date of Patent: June 29, 2004Assignee: Rohm and Haas CompanyInventors: Gary Robert Larson, Leo Joseph Procopio, William Joseph Rosano, Otto C. Ziemann
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Patent number: 6756075Abstract: A method and composition are provided for applying a single aqueous coating composition to a composite substrate during an in-press molding operation to achieve (i) improved initial whiteness in a white pigmented composition, (ii) excellent color retention/stability and (iii) excellent press release properties. The aqueous coating composition incorporates an ion exchange resin and serves as a combined sealer and topcoat finish for press molded composite substrates.Type: GrantFiled: February 25, 2002Date of Patent: June 29, 2004Assignee: Rohm and Haas CompanyInventors: Anne Seton DeMasi, Rosemarie Palmer Lauer
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Patent number: 6716912Abstract: The present invention comprises a polymeric binder for water-resistant ink jet inks, wherein the binder has an acid component in the range from about 1 to about 10 wt. % of the polymer, a glass transition temperature in the range from about −20° C. to about 25° C., and an average particle diameter in the range from about 250 to about 400 nm and a particle size distribution such that essentially all the particles have a diameter in the range from 130 to 450 nm. The binder comprises monomers selected from the group consisting of acrylates, methacrylates, styrene, substituted styrene, fluoromethacrylates, vinyl acrylates, vinyl acetates, acrylamides, substituted acrylamides, methacrylamides, substituted methacrylamides, or combinations thereof.Type: GrantFiled: November 30, 2000Date of Patent: April 6, 2004Assignee: Rohm and Haas CompanyInventors: Michael Bennett Freeman, Eric Jon Langenmayr, Thomas Glenn Madle
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Patent number: 6548596Abstract: A polymer composition comprising an aqueous suspension or dispersion of a water insoluble polymer of ethylenically unsaturated monomers, said polymer having a Tg of at least 35° C. and 25% to 65% by weight units of iso-butyl methacrylate (IBMA) and n-butyl methacrylate (BMA), and 3% to 50% by weight units of at least one acidic monomer. Floor polish compositions comprising said polymer may have improved repeatable high speed burnish response.Type: GrantFiled: July 23, 1998Date of Patent: April 15, 2003Assignee: Rohm and Haas CompanyInventors: Alan Wayne Kohr, Karl John Hartman
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Patent number: 6547929Abstract: A paper having an improved print quality comprises a paper substrate having a surface with a surface roughness of less than 6 microns and a surface gloss of 5-80% which surface has been coated with a light-weight, low solids content, top coat. The top coat may comprise (i) a rheology modifier/binder component and at least one pigment or (ii) at least one binder coated pigment. The top coat provides a significant improvement to the delta gloss of the so-treated paper.Type: GrantFiled: April 4, 2001Date of Patent: April 15, 2003Assignee: Rohm and Haas CompanyInventors: Barrett Richard Bobsein, James Tinney Brown, Zhenwen Fu, Janet Drobits Windisch
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Patent number: 6528581Abstract: The quality of a mastic coating system for bituminous substrates is improved through the use of a topcoat composition and/or tiecoat composition comprising a water-insoluble latex polymer. The latex polymer has a Tg of from −25° C. to 20° C. and is prepared from a monomer mixture comprising: (a) at least 20% by weight of at least one hydrophobic monomer selected from the group consisting of (C8 to C24) alkyl (meth)acrylates; (b) 0 or up to 45% by weight of at least one vinyl aromatic monomer; wherein the weight of (a) and (b) together constitute at least 25% by weight of said monomer mix (c) 0 or up to 75% by weight of at least one monomer selected from the group consisting (C1 to C4) alkyl (meth)acrylates; and (d) 0 or up to 5% by weight of at least one monomer selected from acrylic or methacrylic acid; wherein when (b) is not present in the monomer mix the amount of (d) is in the range from 0 or up to less than 3% by weight.Type: GrantFiled: April 16, 1999Date of Patent: March 4, 2003Assignee: Rohm and Haas CompanyInventors: David Goodro Kelly, Huiling Yang, Donald Alfred Winey
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Patent number: 6451378Abstract: Adhesion between a coating and an EPDM rubber membrane may be improved by pre-treating the surface of the EPDM rubber membrane with an aqueous detergent composition having a pH above 8 and comprising from 1 to 10% by weight phosphate and from 1 to 10% by weight silicate, before application of the mastic.Type: GrantFiled: September 11, 2000Date of Patent: September 17, 2002Assignee: Rohm and Haas CompanyInventor: Thomas James Ennis
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Patent number: 6423382Abstract: A high gloss coating on a mineral substrate, such as a roof tile or floor tile, can be achieved by a method comprising: i) applying a first coating consisting of an aqueous composition comprising a film forming polymeric binder to a surface of the uncured substrate; ii) exposing said first coating to hot air or infrared, ultraviolet or microwave radiation, for sufficient time for at least the surface of said coating remote from the substrate body to form a film of polymeric binder, and iii) applying a second coating consisting of an aqueous composition comprising a film forming polymeric binder on top of the first coating. After application of the second coating, the substrate and coatings are dried and cured, for example in an oven or autoclave.Type: GrantFiled: November 24, 1999Date of Patent: July 23, 2002Assignee: Rohm and Haas CompanyInventors: Michael Damian Bowe, John Maxfield
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Patent number: 6349961Abstract: Products of and methods for producing complex shapes of composite molded articles, including snowboards, that meet or exceed the aesthetic, cost and performance requirements expected of similar non-molded composite articles. The injection molded or co-injection molded snowboard comprises a top surface and a bottom surface shaped to provide a center portion, at least one tip or tail portion and edges along the sides of the center portion, wherein the bottom surface is a substantially smooth continuous surface, the center portion is cambered away from the top surface and contains metal edges along the sides of the bottom surface center portion, the tip or tail portions are curved away from the bottom surface of the snowboard and the top surface contains binding mounts or screw threads flush mounted to secure bindings.Type: GrantFiled: June 15, 1999Date of Patent: February 26, 2002Assignee: Jumbo Snowboards, LLPInventors: David Colley, Joseph McRoskey, Olaf Mjelde
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Use of co-injection molding to produce composite parts including a molded snowboard with metal edges
Patent number: 6309586Abstract: The present invention comprises products of and methods for producing complex shapes of composite molded articles, including snowboards, that meet or exceed the aesthetic, cost and performance requirements expected of similar non-molded composite articles. The injection molded or co-injection molded snowboard comprises a top surface and a bottom surface shaped to provide a center portion, at least one tip or tail portion and edges along the sides of the center portion, wherein the bottom surface is a substantially smooth continuous surface, the center portion is cambered away from the top surface and contains metal edges along the sides of the bottom surface center portion, the tip or tail portions are curved away from the bottom surface of the snowboard and the top surface contains binding mounts or screw threads flush mounted to secure bindings.Type: GrantFiled: June 15, 1999Date of Patent: October 30, 2001Assignee: Jumbo Snowboards, LLCInventors: David Colley, Joseph McRoskey, Olaf Mjelde -
Patent number: 6299944Abstract: The present invention provides a method of curing a waterborne coating composition comprising the steps of: a) applying the waterborne coating composition, which comprises polymer solids of which at least 5% by weight thereof is UV curable, to a substrate; b) irradiating the coated substrate with microwave radiation; and c) irradiating the coated substrate with UV radiation.Type: GrantFiled: November 6, 1997Date of Patent: October 9, 2001Assignee: Rohm and Haas CompanyInventor: Andrew Paul Trapani
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Patent number: 6071602Abstract: Articles for controlling the porosity and permeation of a web are provided using a curable thixotropic shear thinnable polymer composition that preferably encapsulates a plurality of fibers of the web and/or forms an internal layer within the web. Webs suitable for several different uses are featured, for example medical garments resistant to permeation by a virus or bacteria. The effective pore size of the web is controlled by regulating various factors such as the thickness of the polymer composition encapsulating the fibers and the thickness and placement of the internal polymer layer. Other factors include the polymer density, structure, and crosslinking orientation, as well as the diffusion, permeation and sorption of the polymer.Type: GrantFiled: January 27, 1998Date of Patent: June 6, 2000Assignee: Nextec Applications, Inc.Inventor: James M. Caldwell
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Patent number: D504458Type: GrantFiled: December 17, 2002Date of Patent: April 26, 2005Inventor: Jon Edwards