Patents Represented by Attorney Karl Stauss
  • Patent number: 7638561
    Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous vehicle, a self-dispersed pigment, a silicone-containing surfactant and an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C. Also provided is a method for printing an image on a hydrophobic substrate.
    Type: Grant
    Filed: June 8, 2005
    Date of Patent: December 29, 2009
    Assignee: Rohm and Haas Company
    Inventors: Zhenwen Fu, Hailan Guo, Michael Hallden-Abberton, Himal H. Ray
  • Patent number: 7338988
    Abstract: An aqueous inkjet ink composition suitable for printing on a hydrophobic surface such as a vinyl surface including an aqueous emulsion polymer having a glass transition temperature (Tg) of from ?40° C. to 150° C.; a pigment; and a water-soluble surface agent is provided. Also provided is a method for providing an image on a hydrophobic surface and the image so provided.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: March 4, 2008
    Assignee: Rohm and Haas Company
    Inventors: Carl Michael Hesler, Eric Alvin Johnson
  • Patent number: 7241834
    Abstract: An aqueous acrylic emulsion polymer including, as copolymerized units, 70 to 99.5% by weight, based on dry polymer weight, monoethylenically unsaturated nonionic (meth)acrylic monomer and from 0.3 to 10% by weight, based on dry polymer weight, monoethylenically unsaturated acid monomer, wherein at least 40% by weight, based on dry polymer weight, of the emulsion polymer is formed by redox polymerization in the presence of 0.001 to 0.05 moles chain transfer agent per kg dry polymer weight is provided. An aqueous coating composition including the acrylic emulsion polymer, a method for improving the scrub resistance of a dry coating, a method for improving the adhesion of a dry coating, and a method for improving the adhesion of a dry coating to an alkyd substrate are provided.
    Type: Grant
    Filed: March 31, 2005
    Date of Patent: July 10, 2007
    Assignee: Rohm and Haas Company
    Inventor: Ralph Craig Even
  • Patent number: 7074842
    Abstract: An inkjet ink binder composition including an emulsion polymer, the polymer including as polymerized units 1–10%, by weight based on dry polymer weight, of a monomer selected from the group consisting of methylol acrylamide, methylol methacrylamide, methyl acrylamidoglycolate methyl ether, acrylamidoglycolic acid, and mixtures thereof is provided. An inkjet ink composition including the emulsion polymer, a liquid medium, and a pigment and a method for improving the durability of inkjet ink printed on a substrate are also provided.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: July 11, 2006
    Assignee: Rohm and Haas Company
    Inventors: Chao-Jen Chung, Maureen Joanne Finley, Zhenwen Fu
  • Patent number: 7025820
    Abstract: A method for forming an aqueous carbon black dispersion including providing a reaction mixture including carbon black having a DBP uptake of greater than 90 cc/100 g of the carbon black, a monovalent ion persulfate, an aqueous medium, and, in some embodiments, a strong acid; subjecting the reaction mixture to a first temperature of from 40° C. to 90° C. for from 2 hours to 24 hours; neutralizing the reaction mixture to a pH greater than 7.0, and, in certain embodiments, subjecting the neutralized reaction mixture to a second temperature of from 20° C. to 40° C. higher than the first temperature for from 2 hours to 12 hours is provided. In an alternative aspect carbon black having a particle diameter less than 18 nanometers in diameter and a DBP uptake of less than 70 cc/100 g carbon black is provided. The aqueous carbon black dispersion so formed and an aqueous inkjet ink containing the aqueous carbon black dispersion are also provided.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: April 11, 2006
    Assignee: Rohm and Haas Company
    Inventors: Tabb Robertson Champlin, Stephen Andrew Crescimanno, Eric Jon Langenmayr, Richard Shu-Hua Wu
  • Patent number: 6986808
    Abstract: Ink compositions having increased stability and increased jettability with the addition of specific surfactants, including alkyl ether sulfates and ethoxylated mercaptans, are provided. The remainder of the ink composition comprises a suitable carrier vehicle, which typically contains water, alcohols, surfactants, humectants and optionally a resin component.
    Type: Grant
    Filed: December 9, 2003
    Date of Patent: January 17, 2006
    Assignee: Rohm and Haas Company
    Inventors: Zhenwen Fu, Louis Christopher Graziano
  • Patent number: 6896212
    Abstract: A method of using polymeric grinding media to produce fine solid particles or fine solid dispersions in liquid, such as pigment dispersions for inks, is provided. The method of the present invention limits packing and plugging problems associated with polymeric media to allow efficient milling operation.
    Type: Grant
    Filed: September 4, 2003
    Date of Patent: May 24, 2005
    Assignee: Rohm and Haas Company
    Inventors: Vere Orland Archibald, Richard Shu-Hua Wu
  • Patent number: 6756459
    Abstract: A binder composition for aqueous coatings that exhibit high gloss and superior corrosion resistance when applied to metal substrates comprising an aqueous emulsion copolymer, the copolymer including as polymerized units, at least one ethylenically unsaturated monomer and an ethylenically unsaturated strong acid monomer, such as phosphorus containing monomers, particularly phosphoethylmethacrylate; or salts thereof. Also provided is a method for achieving high gloss and superior corrosion resistance of metal substrates by coating a substrate with an aqueous coating composition comprising the binders of the present invention and drying, or allowing to dry, the aqueous composition.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: June 29, 2004
    Assignee: Rohm and Haas Company
    Inventors: Gary Robert Larson, Leo Joseph Procopio, William Joseph Rosano, Otto C. Ziemann
  • Patent number: 6756075
    Abstract: A method and composition are provided for applying a single aqueous coating composition to a composite substrate during an in-press molding operation to achieve (i) improved initial whiteness in a white pigmented composition, (ii) excellent color retention/stability and (iii) excellent press release properties. The aqueous coating composition incorporates an ion exchange resin and serves as a combined sealer and topcoat finish for press molded composite substrates.
    Type: Grant
    Filed: February 25, 2002
    Date of Patent: June 29, 2004
    Assignee: Rohm and Haas Company
    Inventors: Anne Seton DeMasi, Rosemarie Palmer Lauer
  • Patent number: 6716912
    Abstract: The present invention comprises a polymeric binder for water-resistant ink jet inks, wherein the binder has an acid component in the range from about 1 to about 10 wt. % of the polymer, a glass transition temperature in the range from about −20° C. to about 25° C., and an average particle diameter in the range from about 250 to about 400 nm and a particle size distribution such that essentially all the particles have a diameter in the range from 130 to 450 nm. The binder comprises monomers selected from the group consisting of acrylates, methacrylates, styrene, substituted styrene, fluoromethacrylates, vinyl acrylates, vinyl acetates, acrylamides, substituted acrylamides, methacrylamides, substituted methacrylamides, or combinations thereof.
    Type: Grant
    Filed: November 30, 2000
    Date of Patent: April 6, 2004
    Assignee: Rohm and Haas Company
    Inventors: Michael Bennett Freeman, Eric Jon Langenmayr, Thomas Glenn Madle
  • Patent number: 6548596
    Abstract: A polymer composition comprising an aqueous suspension or dispersion of a water insoluble polymer of ethylenically unsaturated monomers, said polymer having a Tg of at least 35° C. and 25% to 65% by weight units of iso-butyl methacrylate (IBMA) and n-butyl methacrylate (BMA), and 3% to 50% by weight units of at least one acidic monomer. Floor polish compositions comprising said polymer may have improved repeatable high speed burnish response.
    Type: Grant
    Filed: July 23, 1998
    Date of Patent: April 15, 2003
    Assignee: Rohm and Haas Company
    Inventors: Alan Wayne Kohr, Karl John Hartman
  • Patent number: 6547929
    Abstract: A paper having an improved print quality comprises a paper substrate having a surface with a surface roughness of less than 6 microns and a surface gloss of 5-80% which surface has been coated with a light-weight, low solids content, top coat. The top coat may comprise (i) a rheology modifier/binder component and at least one pigment or (ii) at least one binder coated pigment. The top coat provides a significant improvement to the delta gloss of the so-treated paper.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: April 15, 2003
    Assignee: Rohm and Haas Company
    Inventors: Barrett Richard Bobsein, James Tinney Brown, Zhenwen Fu, Janet Drobits Windisch
  • Patent number: 6528581
    Abstract: The quality of a mastic coating system for bituminous substrates is improved through the use of a topcoat composition and/or tiecoat composition comprising a water-insoluble latex polymer. The latex polymer has a Tg of from −25° C. to 20° C. and is prepared from a monomer mixture comprising: (a) at least 20% by weight of at least one hydrophobic monomer selected from the group consisting of (C8 to C24) alkyl (meth)acrylates; (b) 0 or up to 45% by weight of at least one vinyl aromatic monomer; wherein the weight of (a) and (b) together constitute at least 25% by weight of said monomer mix (c) 0 or up to 75% by weight of at least one monomer selected from the group consisting (C1 to C4) alkyl (meth)acrylates; and (d) 0 or up to 5% by weight of at least one monomer selected from acrylic or methacrylic acid; wherein when (b) is not present in the monomer mix the amount of (d) is in the range from 0 or up to less than 3% by weight.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: March 4, 2003
    Assignee: Rohm and Haas Company
    Inventors: David Goodro Kelly, Huiling Yang, Donald Alfred Winey
  • Patent number: 6451378
    Abstract: Adhesion between a coating and an EPDM rubber membrane may be improved by pre-treating the surface of the EPDM rubber membrane with an aqueous detergent composition having a pH above 8 and comprising from 1 to 10% by weight phosphate and from 1 to 10% by weight silicate, before application of the mastic.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: September 17, 2002
    Assignee: Rohm and Haas Company
    Inventor: Thomas James Ennis
  • Patent number: 6423382
    Abstract: A high gloss coating on a mineral substrate, such as a roof tile or floor tile, can be achieved by a method comprising: i) applying a first coating consisting of an aqueous composition comprising a film forming polymeric binder to a surface of the uncured substrate; ii) exposing said first coating to hot air or infrared, ultraviolet or microwave radiation, for sufficient time for at least the surface of said coating remote from the substrate body to form a film of polymeric binder, and iii) applying a second coating consisting of an aqueous composition comprising a film forming polymeric binder on top of the first coating. After application of the second coating, the substrate and coatings are dried and cured, for example in an oven or autoclave.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: July 23, 2002
    Assignee: Rohm and Haas Company
    Inventors: Michael Damian Bowe, John Maxfield
  • Patent number: 6349961
    Abstract: Products of and methods for producing complex shapes of composite molded articles, including snowboards, that meet or exceed the aesthetic, cost and performance requirements expected of similar non-molded composite articles. The injection molded or co-injection molded snowboard comprises a top surface and a bottom surface shaped to provide a center portion, at least one tip or tail portion and edges along the sides of the center portion, wherein the bottom surface is a substantially smooth continuous surface, the center portion is cambered away from the top surface and contains metal edges along the sides of the bottom surface center portion, the tip or tail portions are curved away from the bottom surface of the snowboard and the top surface contains binding mounts or screw threads flush mounted to secure bindings.
    Type: Grant
    Filed: June 15, 1999
    Date of Patent: February 26, 2002
    Assignee: Jumbo Snowboards, LLP
    Inventors: David Colley, Joseph McRoskey, Olaf Mjelde
  • Patent number: 6309586
    Abstract: The present invention comprises products of and methods for producing complex shapes of composite molded articles, including snowboards, that meet or exceed the aesthetic, cost and performance requirements expected of similar non-molded composite articles. The injection molded or co-injection molded snowboard comprises a top surface and a bottom surface shaped to provide a center portion, at least one tip or tail portion and edges along the sides of the center portion, wherein the bottom surface is a substantially smooth continuous surface, the center portion is cambered away from the top surface and contains metal edges along the sides of the bottom surface center portion, the tip or tail portions are curved away from the bottom surface of the snowboard and the top surface contains binding mounts or screw threads flush mounted to secure bindings.
    Type: Grant
    Filed: June 15, 1999
    Date of Patent: October 30, 2001
    Assignee: Jumbo Snowboards, LLC
    Inventors: David Colley, Joseph McRoskey, Olaf Mjelde
  • Patent number: 6299944
    Abstract: The present invention provides a method of curing a waterborne coating composition comprising the steps of: a) applying the waterborne coating composition, which comprises polymer solids of which at least 5% by weight thereof is UV curable, to a substrate; b) irradiating the coated substrate with microwave radiation; and c) irradiating the coated substrate with UV radiation.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: October 9, 2001
    Assignee: Rohm and Haas Company
    Inventor: Andrew Paul Trapani
  • Patent number: 6071602
    Abstract: Articles for controlling the porosity and permeation of a web are provided using a curable thixotropic shear thinnable polymer composition that preferably encapsulates a plurality of fibers of the web and/or forms an internal layer within the web. Webs suitable for several different uses are featured, for example medical garments resistant to permeation by a virus or bacteria. The effective pore size of the web is controlled by regulating various factors such as the thickness of the polymer composition encapsulating the fibers and the thickness and placement of the internal polymer layer. Other factors include the polymer density, structure, and crosslinking orientation, as well as the diffusion, permeation and sorption of the polymer.
    Type: Grant
    Filed: January 27, 1998
    Date of Patent: June 6, 2000
    Assignee: Nextec Applications, Inc.
    Inventor: James M. Caldwell
  • Patent number: D504458
    Type: Grant
    Filed: December 17, 2002
    Date of Patent: April 26, 2005
    Inventor: Jon Edwards