Patents Represented by Attorney Kenneth A. Koch
  • Patent number: 5293924
    Abstract: A method is disclosed for improving the continuous casting process for making copper by using a probe and analyzer which measures the gases present in the molten copper and controls the process based on the analyzer results.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: March 15, 1994
    Assignee: ASARCO Incorporated
    Inventors: John R. Hugens, Jr., Stephen L. Ferrel, Gary L. Spence
  • Patent number: 5279644
    Abstract: A new environmentally safe fire refining precious metal assay method is provided wherein bismuth oxide is used with a special flux composition as the precious metal collector and the cupelling procedure is performed in a controlled temperature range.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: January 18, 1994
    Assignee: ASARCO Incorporated
    Inventor: David W. Francisco
  • Patent number: 5242571
    Abstract: A method and apparatus are disclosed for producing copper wire by electrolytically engrossing a copper starting wire. Basically the invention utilizes an electrolytic tank employing a pair or pairs of shafts positioned externally of the tank upon which a minimum of one but generally at least two starting wires are transported on each pair for transfer of the wires through the tank. Multiple tanks, e.g., 10 to 1000 or more, may be used in a single facility for refining or electrowinning processes depending on the quantity of copper wire desired to be produced.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: September 7, 1993
    Assignee: ASARCO Incorporated
    Inventors: Carlos E. R. Sein, William J. Borzick
  • Patent number: 5240494
    Abstract: A method is disclosed for melting copper without incorporating unwanted oxygen and/or hydrogen into the copper by effectively controlling the burners used to melt the copper within desired fuel/air ratio operating limits by employing a special fuel/air mixture sampling and control system.
    Type: Grant
    Filed: April 25, 1991
    Date of Patent: August 31, 1993
    Assignee: ASARCO Incorporated
    Inventors: Jim D. Williams, Darrell W. Breitling
  • Patent number: 5234492
    Abstract: An improved process for deleading debismuthized dross is provided wherein the upgraded dross is treated by cupellation to form a slag until the level of bismuth in the upgraded dross reaches about 45% by weight. After cupellation, the partially deleaded upgraded dross may be treated by conventional means such as halogenation to provide a substantially pure bismuth product.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: August 10, 1993
    Assignee: ASARCO Incorporated
    Inventors: Funsho K. Ojebuoboh, Stephen A. Blaskovich
  • Patent number: 5133948
    Abstract: Bismuth impurity is removed from copper electrolyte by contacting the electrolyte with an effective amount of finely divided lead oxide.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: July 28, 1992
    Assignee: ASARCO Incorporated
    Inventors: Michael G. King, Jonathan S. Jackson, Wing H. Heung
  • Patent number: 5110353
    Abstract: Fume generated by roasting speiss is contacted with an oxygen-containing gas at an elevated temperature for a sufficient time to product arsenic and antimony products which may be separated from each other by means such as condensation. Further, in the roasting of antimony-containing phases (such as speiss) the presence of arsenic can enhance the volatility of the antimony.
    Type: Grant
    Filed: January 29, 1991
    Date of Patent: May 5, 1992
    Assignee: ASARCO Incorporated
    Inventors: Taie Li, Thomas P. Clement, II, John P. Hager
  • Patent number: 5108786
    Abstract: A method for making printed circuit boards wherein the resistance of catalyzed nonconductive surfaces to solutions used in the processing stages, e.g., KOH used to remove an etch resist covering through-holes and the desired circuit lines, is enhanced by treating the catalyzed surface with an accelerator to activate the catalyst, treating the accelerated surface with a reducing agent, followed by baking.
    Type: Grant
    Filed: November 20, 1990
    Date of Patent: April 28, 1992
    Assignee: Enthone-OMI, Inc.
    Inventor: Martin Bayes
  • Patent number: 5108552
    Abstract: A process for electrodespositing a conductive material on a substrate is disclosed which comprises movably mounting the substrate in a first conductive liquid electroplating bath which contains the conductive material, maintaining substantially constant conditions of temperature and liquid circulation in the first bath, passing an electric current through the substrate and the first bath so as to deposit the conductive material on the substrate, periodically transferring the substrate to a second liquid bath, the second bath containing a liquid of the same composition or lower concentrations of dissolved ingredients as compared to the first bath, weighing the substrate when immersed in the second bath and calculating therefrom the weight in air of conductive material deposited, returning the substrate to the first bath, and continuing the plating in a series of stages of plating, weighing in liquid and plating until the desired deposit is built up.Apparatus for carrying on the method is also disclosed.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: April 28, 1992
    Assignee: Enthone-OMI, Inc.
    Inventor: Guy Desthomas
  • Patent number: 5103892
    Abstract: Continuous casting of discrete solid shapes from a molten material using modified continuous casting machines and processes are disclosed. In a conventional twin belt continuous caster, for example, forming means such as dividers are employed on the upper belt to define a mold cavity in the casting region of the machine. Different size and shape forming means may be used to provide a variety of cast products.
    Type: Grant
    Filed: July 17, 1991
    Date of Patent: April 14, 1992
    Assignee: ASARCO Incorporated
    Inventor: John R. Hugens, Jr.
  • Patent number: 4985216
    Abstract: A process is provided for the reduction roasting of ores using a C.sub.2 to C.sub.8 hydrocarbon. The process is particularly applicable to manganese dioxide containing ores and provides enhanced reduction of the manganese to lower oxidation states at low operating temperatures for manganese dioxide ores and provides increased silver recoveries from refractory manganese-silver ores.
    Type: Grant
    Filed: July 20, 1988
    Date of Patent: January 15, 1991
    Assignee: ASARCO Incorporated
    Inventors: Mamdouh M. El Tawil, Adrian E. Albrethsen
  • Patent number: 4956097
    Abstract: A method for waste treating metal containing solutions comprising decomposing the metal from the solution in the substantial absence of air and separating the decomposed (precipitated) metal from the solution.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: September 11, 1990
    Assignee: Enthone, Incorporated
    Inventor: Constantine I. Courduvelis
  • Patent number: 4936127
    Abstract: The method of making copper rod by rolling is significantly improved by effectively controlling the water-soluble oil emulsion used to lubricate the rolls by employing a conductivity probe to maintain the conductivity of the emulsion within desired operating limits.
    Type: Grant
    Filed: May 25, 1989
    Date of Patent: June 26, 1990
    Assignee: Asarco Incorporated
    Inventor: Darrel W. Breitling
  • Patent number: 4902191
    Abstract: A mobile truck for moving containers and other articles comprising a base, supporting standards at opposite sides of the base, a handle pivotally attached at the upper ends of the standards, a lift supporting member pivotally attached to the handle and to a suitable lifter arm, the lifter arm having attached at one end a lifting device and the other end of the lifter arm being pivotally attached to a connecting bar, with the other end of the connecting bar being pivotally attached to the truck base.
    Type: Grant
    Filed: December 9, 1985
    Date of Patent: February 20, 1990
    Assignee: Asarco Incorporated
    Inventors: Joseph B. Cumbest, Johnnie L. Briggs, Francis R. Jones
  • Patent number: 4891061
    Abstract: Arsenic and antimony are separated from speiss by a roasting operation employing pyrite and coke and the arsenic is separated from the resultant product by a water pressure leaching operation.
    Type: Grant
    Filed: April 21, 1986
    Date of Patent: January 2, 1990
    Assignee: ASARCO Incorporated
    Inventors: Thomas P. Clement, II, John R. Wettlaufer, Jack A. Scott
  • Patent number: 4863696
    Abstract: An orifice assembly for use in connection with diffusion cells for the percutaneous absorption of fluids which is composed of a pair of resiliant and mating members having structure for securely retaining a flexible membrane therebetween in a predetermined and fluid tight relationship with each other and the diffusion cells.
    Type: Grant
    Filed: September 12, 1988
    Date of Patent: September 5, 1989
    Assignee: Crown Glass Company, Inc.
    Inventors: Michael E. Saydek, Gordon Flynn, Karlis Vizulis, Charles Von Reis
  • Patent number: 4859300
    Abstract: The permanganate process for treating plastics, e.g., printed circuit boards, to enhance the adhesion of metal plating to the plastic is improved by employing electrolysis to either maintain a certain permanganate level in the operating bath or to regenerate a spent or used bath.
    Type: Grant
    Filed: January 9, 1989
    Date of Patent: August 22, 1989
    Assignee: Enthone, Incorporated
    Inventors: Thomas E. Sullivan, Juan Haydu
  • Patent number: 4840820
    Abstract: A process is provided for improving the electroless nickel plating of aluminum which has been pretreated with a barrier coating such as zinc by employing multiple plating baths under controlled operating conditions.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: June 20, 1989
    Assignee: Enthone, Incorporated
    Inventors: Paul B. Schultz, Eugene F. Yarkosky
  • Patent number: 4808221
    Abstract: Fume generated by roasting speiss is contacted with an oxygen-containing gas at an elevated temperature for a sufficient time to produce arsenic and antimony products which may be separated from each other by means such as condensation. Further, in the roasting of antimony-containing phases (such as speiss) the presence of arsenic can enhance the volatility of the antimony.
    Type: Grant
    Filed: August 25, 1987
    Date of Patent: February 28, 1989
    Assignee: Asarco Incorporated
    Inventors: Thomas P. Clement, II, Taie Li, John P. Hager
  • Patent number: RE34664
    Abstract: The invention relates to a method and apparatus for electrolytic refining of copper and the production of copper wires for electrical purposes on a continual basis which produces round copper wires directly from impure copper anodes and to treat such wires in order to impart the desired characteristics as electrical conductors. The apparatus handles copper anodes of customary size refining them at normal current densities of less than 55 amps/foot.sup.2 onto starting wires of adequate tensile strength which is done continuously, the wire being provided to an electrolytic bath and, after withdrawal from the bath, the wires are finished by drawing and annealing.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: July 19, 1994
    Assignee: ASARCO Incorporated
    Inventor: Carlos E. Roggero Sein