Abstract: The present invention relates to an aqueous coating composition having low volatile organic compounds (VOC) and producing a coating having excellent durability and resistance properties. The coating composition contains acetoacetate functional polymer and divalent metal ions. Coating compositions of the present invention are particularly useful in ink, polish and coating compositions where a tough, resistant coating is required. The coating composition can be used on various substrates such as floors, walls wood, metal, plastic, stone, paper, leather and concrete.

Abstract: Aqueous coating compositions containing at least 2 polymer components which provide adhesion and improved durability as measured by improved gloss retention or dirt pick up resistance in dried coatings made from the coating composition are disclosed.

Abstract: A formaldehyde-free curable aqueous composition comprising:(a) a polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts of the polyacid thereof;(b) an active hydrogen compound containing at least two active hydrogen groups selected from the group consisting of hydroxyl, primary amino, secondary amino, and mixtures thereof; and(c) a fluoroborate accelerator; wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said hydroxyl groups is from 1/0.01 to about 1/3, and wherein said carboxylic acid groups, anhydride groups, or salts thereof are neutralized to an extent of less than 35% with a fixed base is disclosed. A method for curing formaldehyde-free polyacids and a method for bonding glass fiber heat-resistant nonwovens with a formaldehyde-free binder are further disclosed.

Abstract: A formaldehyde-free curable composition useful for binding nonwovens comprises(a) a polyacid comprising at least two carboxylic acid groups, anhydride groups, or salts of the polyacid thereof;(b) an active hydrogen compound containing at least two active hydrogen groups selected from the group consisting of hydroxyl, primary amino, secondary amino, and mixtures thereof; and(c) one or more compounds selected from the group consisting of cyanamide, dicyandiamide, 1,2-mono- or di-(C.sub.1 -C.sub.6 alkyl) substituted-3-cyanoguanidines such as ethyl-3-cyanoguanidine, 1,2-diethyl-3-cyanoguanidine, and 1,2-diisopropyl-3-cyanoguanidine, and 1,2-mono- or di-(C.sub.6 -C.sub.12 aryl) substituted-3-cyanoguanidines, such as phenyl-dicyandiamide; and, optionally(d) an accelerator;wherein the ratio of the number of equivalents of said carboxylic acid groups, anhydride groups, or salts thereof to the number of equivalents of said active hydrogen groups is from 1/0.

Abstract: Gift free coating with improved tannin stain blocking, nicotine stain blocking, efflorescencee resistance, and water spot resistance are disclosed. Pre-treated ion exchange resins are incorporated into the coating compositions to achieve the improvements.

Abstract: A water dispersible powder composition is provided. The powder composition contains at least one film-forming polymer having at least one functional group and at least one reactive component that reacts to form a non-ionic bond with the polymer functional group following dispersion of the powder composition in water. The reaction between the polymer particles in the admixture and the reactive component renders the resulting coating water-resistant. The powder composition of this invention is useful for producing water-resistant coatings.

Abstract: A zirconium catalyzed transesterification process for preparing synthetic wax monomers is disclosed. The monomers are useful in a wide range of polymers.

Abstract: An aqueous coating composition having low VOC is provided. The invention provides excellent hardness and resistance properties in films formed from binders having glass transition temperatures below ambient temperature. The improvement in film properties comes from the binding of functionalized polyvinyl alcohol to a complementary functionalized latex binder. The low VOC compositions of this invention are useful for a variety of coatings including paints, stains, varnishes, mastics and adhesives.

Abstract: Processes are provided for producing a pure grade of acrylic acid having residual aldehyde levels under 10 parts per million. The processes apply selected groups of amines sequentially and, preferably, continuously in selectively reducing, for example, acrolein and furfural, and may be advantageously conducted in the presence of maleic acid and maleic anhydride impurities.

Abstract: A continuous process for producing a pure grade of acrylic acid having residual aldehyde levels under 10 parts per million. The process applies two groups of amines sequentially and continuously in selectively reducing acrolein and furfural and may be advantageously conducted in the presence of maleic acid and maleic anhydride impurities.