Abstract: An exhaust system which has a catalysed soot filter (CSF), a control unit, and a catalyzed sensor. The exhaust system, controllable by the control unit, can increase hydrocarbon (HC) and/or carbon monoxide (CO) content in an exhaust gas flowing into the CSF resulting in combustion of the HC and/or CO in the CSF, a temperature increase of the CSF, and combustion of particulate matter collected on the CSF. The catalyzed sensor is disposed between an engine manifold and the CSF, and combusts CO and/or HC in the exhaust gas and inputs the control unit with a datum correlating with an enthalpy of combustion of HC and/or CO in the exhaust gas, thereby controlling the content of the combustible HC and/or CO in the exhaust gas flowing into the CSF. The catalysed sensor is the only catalysed component in the exhaust system disposed between the engine and the CSF.

Abstract: Material withdrawal apparatus, methods, and systems of regulating material inventory in one or more units are provided. A material withdrawal apparatus includes a heat exchanger and transport medium junction configured to provide transport medium to transport the withdrawn material from the unit to the heat exchanger. Another material withdrawal apparatus includes a heat exchanger and shock coolant junction configured to provide shock coolant to the material withdrawn from the unit. Another material withdrawal apparatus includes a heat exchanger, shock coolant junction, and transport medium junction. Another embodiment of a material withdrawal apparatus includes a vessel and shock coolant junction. Another material withdrawal apparatus includes a vessel and transport medium junction. The vessel includes a wall, liner with heat insulating refractory material, fill port, and a discharge port.

Abstract: An exhaust system for an internal combustion engine, which system comprises a monolith substrate (10) coated with a catalyst, which monolith substrate comprising a plurality of substantially parallel channels, each channel having a length extending from an upstream end to a downstream end; and a first sensor disposed in a hole (16) defined in part by an external wall of the monolith substrate, wherein the monolith substrate comprises a portion (12) of the plurality of channels wherein the catalyst composition in at least a part of the length of channels extending from the upstream end has an increased activity for a reaction for which the catalyst composition is intended relative to catalyst composition in a remainder (14) of the monolith substrate, the arrangement being such that the sensor is contacted substantially only with exhaust gas that has first contacted the catalyst composition having an increased activity.

Abstract: The present invention is directed to catalytic cracking additives comprising a metals trapping material; and a high activity catalyst. The present invention is directed to processes for the catalytic cracking of feedstock comprising contacting said feedstock under catalytic cracking conditions with a composition comprising a bulk catalyst and a catalytic cracking additive, wherein the catalytic cracking additive comprises a metals trapping material; and a high activity catalyst. The invention is also directed to processes for increasing the performance of a bulk catalyst in the presence of at least one metal comprising contacting a feedstock with a catalytic cracking additive comprising a metals trapping material; and a high activity catalyst.

Abstract: A method of decomposing nitrogen dioxide to nitrogen monoxide in an exhaust gas of a lean-burn internal combustion engine, such as a diesel engine, comprises adjusting the C1 hydrocarbon:nitrogen oxides (C1 HC:NOx) ratio of the exhaust gas to from 0.1 to 2 and contacting this exhaust gas mixture with a particulate acidic refractory oxide selected from the group consisting of zeolites, tungsten-doped titania, silica-titania, zirconia-titania, gamma-alumina, amorphous silica-alumina and mixtures of any two or more thereof and passing the effluent gas to atmosphere.

Abstract: Catalyst withdrawal apparatuses and methods for regulating catalyst inventory in one or more units are provided. In one embodiment, a catalyst withdrawal apparatus for removing catalyst from a FCC unit includes a vessel coupled to a flow control circuit. Another embodiment of a catalyst withdrawal apparatus includes a vessel, a delivery line, and control valve. The control valve is configured to control the amount of gas to the delivery line and entrained with the catalyst. Another embodiment of catalyst withdrawal apparatus includes a vessel coupled to a heat exchanger. The heat exchanger includes a first conduit; a housing confining a coolant volume around a portion of the first conduit; and a sliding seal sealing the housing to the first conduit in manner that allows longitudinal expansion. A fluid catalyst cracking system coupled to a catalyst withdrawal apparatus and method for withdrawing catalyst from a unit are also disclosed.

Abstract: The invention is a process to produce allyl alcohol from propylene oxide. The process comprises isomerizing propylene oxide in the presence of a lithium phosphate catalyst which contains boron and from 2000 to 4000 ppm sodium. The propylene oxide conversion is 37 percent or lower.

Abstract: A catalyst, useful for the hydroformylation of allyl alcohol, is described. The catalyst comprises a rhodium complex and a 6-bis(3,5-dialkylphenyl)phosphino-N-pivaloyl-2-aminopyridine or a 3-bis(3,5-dialkylphenyl)phosphino-2H-isoquinolin-1-one. The invention also includes a process for the production of 4-hydroxybutyraldehyde comprising reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and the catalyst. The process gives a high ratio of the linear product 4-hydroxybutyraldehyde to the branched co-product 3-hydroxy-2-methylpropionaldehyde.

Abstract: A supported catalyst and a catalyst mixture, useful for the direct epoxidation of olefins, are disclosed. The supported catalyst comprises a noble metal, lead, and a carrier that has been treated by contacting with nitric acid. The catalyst mixture comprises a titanium or vanadium zeolite and the supported catalyst. The invention also includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst mixture. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.

Abstract: Product propylene oxide in a reaction mixture resulting from the reaction of propylene, oxygen and hydrogen or from the reaction of propylene and hydrogen peroxide is separated from propylene and/or propane by extractive distillation using methanol and/or water extractive distillation solvent.

Abstract: A process is provided for the production of alkylene oxide by catalytic reaction of olefin, hydrogen and oxygen in the presence of promoting buffer salts, the improvement wherein the buffer salts are recovered by electrodialysis and/or crystallization and recycled to the catalytic reaction.

Abstract: The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of a catalyst mixture containing a titanium or vanadium zeolite and a supported catalyst comprising palladium, gold, and an inorganic oxide carrier. Prior to its use in the epoxidation process, the supported catalyst is calcined in the presence of oxygen at a temperature from 450 to 800° C. and reduced in the presence of hydrogen at a temperature greater than 20° C. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.

Abstract: The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of a catalyst mixture containing a titanium or vanadium zeolite and a supported catalyst comprising palladium, rhenium and a carrier. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.

Abstract: A direct hydrocarbonylation process for the production of 1,4-butanediol is described. The process comprises reacting allyl alcohol with carbon monoxide and hydrogen in an alcohol solvent in the presence of a catalyst system comprising a rhodium complex, a trialkyl phosphine, and a diphosphine. The process gives a high yield of 1,4-butanediol in a one-step reaction.

Abstract: A unique reactor configuration especially suitable for interphase mass transfer and mixing of multiple phases, i.e. gas(es), liquid(s), and solid(s) where reaction is catalyzed by a solid catalyst comprises a draught tube reactor wherein the solid catalyst particles are maintained in an annular space between the draught tube of the reactor and an annulus-defining wall by means of filter elements positioned downstream and optionally also upstream from the catalyst bed.

Abstract: A process for the production of 4-hydroxybutyraldehyde is described. The process comprises reacting allyl alcohol with a mixture of carbon monoxide and hydrogen in the presence of a solvent and a catalyst system comprising a rhodium complex and a substituted or unsubstituted 4,5-bis(di-n-alkylphosphino)xanthene. The process gives high yield of 4-hydroxybutyraldehyde compared to 3-hydroxy-2-methylpropionaldehyde.

Abstract: A process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of a catalyst comprising a titanium or vanadium zeolite, palladium, and lead. The process results in significantly reduced alkane by-product formed by the hydrogenation of olefin.

Abstract: Catalysts useful for the direct epoxidation of olefins are disclosed. The catalysts comprise a noble metal, lead, bismuth, and a titanium or vanadium zeolite. The noble metal, lead, and bismuth may be supported on the titanium or vanadium zeolite. The catalyst may also be a mixture comprising the titanium or vanadium zeolite and a supported catalyst comprising the noble metal, lead, bismuth, and a carrier. The invention includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.

Abstract: Catalyst mixtures useful for the direct epoxidation of olefins are disclosed. The catalyst mixture comprises a titanium or vanadium zeolite and a supported catalyst comprising a noble metal, bismuth, and a carrier. The invention includes a process for producing an epoxide comprising reacting an olefin, hydrogen and oxygen in the presence of the catalyst mixture. The process results in significantly reduced alkane byproduct formed by the hydrogenation of olefin.