Patents Represented by Attorney L. S. Van Landingham, Jr.
  • Patent number: 4237101
    Abstract: Solid carbonaceous fossil fuels such as coal, lignite and peat are treated with an aqueous medium containing a novel catalyst to remove undesirable constituents and produce valuable products. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. In one variant, particles of a fossil fuel containing metal values are treated with an aqueous medium in the presence of the catalyst, and thereafter the treated particles are separated from the aqueous medium and extracted with an aqueous leach solution in which the metal values are soluble.
    Type: Grant
    Filed: April 14, 1978
    Date of Patent: December 2, 1980
    Assignee: CAW Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 4178256
    Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use.
    Type: Grant
    Filed: May 26, 1977
    Date of Patent: December 11, 1979
    Assignee: BASF Wyandotte Corporation
    Inventors: John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
  • Patent number: 4162547
    Abstract: An improved pocket cuspidor is provided which preferably includes a cooperating three component system. The first component is a mouthpiece provided with a disposable waterproof flexible bag releasably secured thereto. The first component is arranged within the second component which is a first waterproof container. The second component and the first component carried thereby, in turn, are arranged within the third component, which is a second waterproof container preferably conforming in size and shape to the pocket of a garment worn by the user of the cuspidor. A cover including a stopper for the mouthpiece opening, is provided which is hingedly attached to the first container and is releasably secured to the second container when the stopper is in liquid sealing engagement with the mouthpiece opening.
    Type: Grant
    Filed: October 12, 1978
    Date of Patent: July 31, 1979
    Inventor: Allen N. Jenkins
  • Patent number: 4163086
    Abstract: Liquid oxyalkylated polyol prepolymers are prepared by oxyalkylating a prepolymer prepared from a hydroxy aromatic compound, an aldehyde and furfuryl alcohol with an alkylene oxide containing about 2-4 carbon atoms. The oxyalkylated polyol prepolymers have a viscosity of 1,000-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde, about 3.1-15 moles of interpolymerized furfuryl alcohol, and about 1-10 moles of interpolymerized alkylene oxide for each mole of interpolymerized hydroxy aromatic compound. The resultant prepolymers are highly reactive and may be further polymerized with or without monomers such as polyisocyanate to produce flame retardant solid or cellular interpolymers. Flame retardant solid or cellular polyurethanes are prepared in one variant by interpolymerizing organic polyisocyanates with the oxyalkylated polyol prepolymers. In another variant, flame retardant closed cell cellular interpolymers are provided.
    Type: Grant
    Filed: March 31, 1978
    Date of Patent: July 31, 1979
    Assignee: BASF Wyandotte Corporation
    Inventors: Thirumurti Narayan, Moses Cenker
  • Patent number: 4126441
    Abstract: Cuttings to be rooted are intimately contacted with water containing a catalytically effective amount of a novel catalyst. The cuttings root faster and/or easier, and the new plants produced therefrom are more vigorous and resistant to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: November 21, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John W. Willard, Sr.
  • Patent number: 4125489
    Abstract: Liquid prepolymers are prepared by interpolymerizing monomers including a hydroxy aromatic compound, an aldehyde and furfuryl alcohol. The resultant liquid prepolymers have a viscosity of about 100-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde and about 3.1-15 moles of interpolymerized furfuryl alcohol for each mole of interpolymerized hydroxy aromatic compound. The prepolymers are highly reactive and may be polymerized with or without other monomers to produce flame retardant solid or cellular interpolymers. In one variant, flame retardant solid or cellular polymers are produced by interpolymerizing organic polyisocyanates with the prepolymers. In another variant, solid or cellular interpolymers are produced by polymerizing the prepolymers without monomers such as polyisocyanate in the presence of unreacted furfuryl alcohol. Processes are provided for preparing the aforementioned novel liquid prepolymers and solid or cellular interpolymers.
    Type: Grant
    Filed: March 31, 1978
    Date of Patent: November 14, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: Thirumurti Narayan, Moses Cenker
  • Patent number: 4120802
    Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use.
    Type: Grant
    Filed: May 26, 1977
    Date of Patent: October 17, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
  • Patent number: 4120799
    Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use.
    Type: Grant
    Filed: May 26, 1977
    Date of Patent: October 17, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
  • Patent number: 4116666
    Abstract: Seeds are intimately contacted with water containing a catalytically effective amount of a novel catalyst to achieve faster germination and/or a higher germination rate. The resultant plants are also more vigorous and resistent to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: November 8, 1976
    Date of Patent: September 26, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4115281
    Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene, a fatty amphoteric compound, or a fatty amide as described hereinafter as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide, a fatty amphoteric compound or a fatty amide as described hereinafter as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride.
    Type: Grant
    Filed: January 26, 1976
    Date of Patent: September 19, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
  • Patent number: 4108809
    Abstract: Liquid prepolymers are prepared by interpolymerizing monomers including a hydroxy aromatic compound, an aldehyde and furfuryl alcohol. The resultant liquid prepolymers have a viscosity of about 100-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde and about 3.1-15 moles of interpolymerized furfuryl alcohol for each mole of interpolymerized hydroxy aromatic compound. The prepolymers are highly reactive and may be polymerized with or without other monomers to produce flame retardant solid or cellular interpolymers. In one variant, flame retardant solid or cellular polymers are produced by interpolymerizing organic polyisocyanates with the prepolymers. In another variant, solid or cellular interpolymers are produced by polymerizing the prepolymers without monomers such as polyisocyanate in the presence of unreacted furfuryl alcohol. Processes are provided for preparing the aforementioned novel liquid prepolymers and solid or cellular interpolymers.
    Type: Grant
    Filed: November 29, 1976
    Date of Patent: August 22, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: Thirumurti Narayan, Moses Cenker
  • Patent number: 4108808
    Abstract: Liquid oxyalkylated polyol prepolymers are prepared by oxyalkylating a prepolymer prepared from a hydroxy aromatic compound, an aldehyde and furfuryl alcohol with an alkylene oxide containing about 2-4 carbon atoms. The oxyalkylated polyol prepolymers have a viscosity of 1000-500,000 centipoises at 25.degree. C. and contain about 1.1-6 moles of interpolymerized aldehyde, about 3.1-15 moles of interpolymerized furfuryl alcohol, and about 1-10 moles of interpolymerized alkylene oxide for each mole of interpolymerized hydroxy aromatic compound. The resultant prepolymers are highly reactive and may be further polymerized with or without monomers such as polyisocyanate to produce flame retardant solid or cellular interpolymers. Flame retardant solid or cellular polyurethanes are prepared in one variant by interpolymerizing organic polyisocyanates with the oxyalkylated polyol prepolymers. In another variant, flame retardant closed cell cellular interpolymers are provided.
    Type: Grant
    Filed: November 26, 1976
    Date of Patent: August 22, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: Thirumurti Narayan, Moses Cenker
  • Patent number: 4092145
    Abstract: Cut flowers are intimately contacted with water containing a catalytically effective amount of a novel catalyst to prolong their life or beauty. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter.
    Type: Grant
    Filed: December 14, 1976
    Date of Patent: May 30, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4089786
    Abstract: Liquid and solid compositions are provided for souring and imparting softness to freshly laundered textile materials. When in the form of a stable homogeneous liquid, the composition may contain (a) a quaternized fatty amide, an aqueous emulsion of partially oxidized polyethylene or a fatty amphoteric compound as the softening agent, (b) hydrofluorosilicic acid, ammonium silicofluoride, zinc silicofluoride, ammonium acid fluoride, potassium acid fluoride, or orthophosphoric acid as the souring agent, and (c) water. When in the form of a stable dry solid, the composition may contain (a) a quaternized fatty amide or fatty amphoteric compound as the softening agent, and (b) ammonium silicofluoride, potassium silicofluoride, sodium silicofluoride, zinc silicofluoride, ammonium acid fluoride, sodium acid fluoride or potassium acid fluoride. A method of preparing the liquid composition is provided which insures that it remains stable and homogeneous while awaiting use.
    Type: Grant
    Filed: May 26, 1977
    Date of Patent: May 16, 1978
    Assignee: BASF Wyandotte Corporation
    Inventors: John D. Ciko, John J. Cramer, Geoffrey A. Jamieson
  • Patent number: 4084938
    Abstract: Solid carbonaceous fossil fuels such as coal, lignite and peat are treated with an aqueous medium containing a novel catalyst to remove undesirable constituents and produce valuable products. The catalyst is prepared by steps including admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of dissolved water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle-forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. In one variant, combustible sulfur and nitrogen compounds and alkali metal ash are removed, and the resulting treated fuel may be used in urban areas where strict air pollution regulations must be met.
    Type: Grant
    Filed: July 7, 1975
    Date of Patent: April 18, 1978
    Assignee: Caw Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067712
    Abstract: Plants are grown in soil which has been intimately contacted with water containing a catalytically effective amount of a novel catalyst to improve the fertility thereof. In a preferred variant, the water which is intimately contacted with the soil may also contain catalyst treated lignite. Plants grown in the treated soil are more vigorous and resistant to disease or adverse environmental conditions. The yields are higher in instances where the plants are grown commercially for food or fiber, and the plants have a more pleasing appearance in instances where they are grown for decorative purposes.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067715
    Abstract: The roots of plants being transplanted are intimately contacted with water containing a catalytically effective amount of a novel catalyst. In a preferred variant, the water may also contain water soluble catalyst treated lignite. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles. The preparation of the novel catalyst and the water soluble catalyst treated lignite is described in detail hereinafter. The transplanted plants grow more vigorously and are more resistant to disease and/or adverse environmental conditions.
    Type: Grant
    Filed: December 14, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067714
    Abstract: Plants are watered with water containing a catalytically effective amount of a novel catalyst to promote growth, yield and/or beauty. The watered plants are more vigorous and resistant to disease and/or adverse environmental conditions. In a preferred variant, the water may also contain water soluble catalyst treated lignite. Plant nutrients may be present in the water and fed to the plants at the time of watering. The catalyst is prepared by a process including the steps of admixing a water soluble alkali metal silicate with an aqueous medium containing carefully controlled amounts of water soluble substances which are sources of calcium ion and magnesium ion, reacting the same to produce an aqueous colloidal suspension of the reaction product, admixing a micelle forming surfactant with the aqueous medium, and agitating the aqueous medium containing the colloidal particles and surfactant to form catalyst-containing micelles.
    Type: Grant
    Filed: December 13, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4067713
    Abstract: Soil is intimately contacted with water containing a catalytically effective amount of a novel catalyst to improve the fertility thereof. In a preferred variant, the water which is intimately contacted with the soil may also contain catalyst treated lignite. Plants grown in the treated soil are more vigorous and resistant to disease or adverse environmental conditions. The yields are higher in instances where the plants are grown commercially for food or fiber, and the plants have a more pleasing appearance in instances where they are grown for decorative purposes.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: January 10, 1978
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard, Sr.
  • Patent number: 4061734
    Abstract: Tissue in warm blooded animals which is damaged and/or infected is treated by administering a therapeutically effective amount of a composition containing a novel catalyst and water soluble catalyst treated lignite. The treatment is also effective in relieving stress and/or shock. In a further variant, warm blooded animals having damaged and/or infected tissue are treated with a composition containing therapeutically effective amounts of at least one antibiotic, the novel catalyst, and the catalyst treated lignite. Novel compositions are provided which contain therapeutic amounts of at least one antibiotic, the catalyst, and the catalyst treated lignite. The novel catalyst and the catalyst treated lignite are prepared by processes described in detail hereinafter.
    Type: Grant
    Filed: October 18, 1976
    Date of Patent: December 6, 1977
    Assignee: CAW Industries, Inc.
    Inventor: John Wesley Willard