Abstract: This invention relates to new compounds of the formula: ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 has zero to 10 C atoms, and no acetylenic unsaturation; each of R.sup.1, R.sup.2 and R.sup.3 is independently selected from H and hydrocarbyl; each of R.sup.4 and R.sup.
Type:
Grant
Filed:
May 19, 1988
Date of Patent:
September 19, 1989
Assignee:
The Standard Oil Company
Inventors:
Mark C. Cesa, James E. Rinz, Teodora T. Kopp
Abstract: Disclosed is the reaction of propane and isobutane with O.sub.2 and NH.sub.3 to make .alpha.,.beta.-unsaturated nitriles and olefins, using certain complex metal oxide catalyst compositions and an excess of the paraffin over both the O.sub.2 and the NH.sub.3. Also disclosed are suitable catalyst compositions for such reactions.
Type:
Grant
Filed:
September 29, 1988
Date of Patent:
September 12, 1989
Assignee:
The Standard Oil Company
Inventors:
James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
Abstract: Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.
Type:
Grant
Filed:
August 22, 1988
Date of Patent:
September 12, 1989
Assignee:
The Standard Oil Company
Inventors:
James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft
Abstract: Benzene is oxidized to produce the phenyl ester of a perfluoromonocarboxylic acid by reaction with H.sub.2 O.sub.2, a perfluoro acid or a combination of acetaldehyde and molecular oxygen, in the presence of (1) a cobalt salt of an organic acid catalyst and (2) a perfluoromonocarboxylic acid solvent.
Abstract: A mixture having emulsifying and emulsion stabilizing properties resulting from the polymerization of (1) a water soluble vinyl monomer selected from the group consisting of acrylamide and methacrylamide, (2) a water insoluble vinyl monomer having an alkyl chain containing about 6 to 30 carbon atoms selected from the group consisting of alkyl acrylate esters, alkyl methacrylate esters, N-alkyl acrylamides, N-alkyl methacrylamides and vinyl esters, and (3) a polymerizable vinyl monomer containing a basic group or salt thereof selected from the group consisting of ##STR1## where X is --O-- or ##STR2## A.sup.- is an inorganic anion,R" is a divalent saturated organic group containing one to six carbon atoms, andR'" is hydrogen or an alkyl group containing one to six carbon atoms.
Abstract: Disclosed is a process for making a 2-pyrrolidone and a succinimide by the vapor phase catalytic reaction of a maleimide with molecular hydrogen.
Abstract: A sea bed oil producing and processing complex has a template with three bays housing pairs of modules, viz, well, gas and oil production modules. The complex includes a separator for separating oil and gas and a pump for the produced oil, and bars having pipework to carry fluids between the pairs of modules and to despatch separated gas and oil. Saddles may carry fluids across between individual modules of a pair and the complex may have facilities for artificial lift, water injection, chemical fluid injection and for test fluids. Multiples of the three bays and pairs of modules may be within a single template and a number of modules may surround a central piping template. The complex can be services and maintained in a diverless mode using a monohull vessel and an ROV.
Abstract: A process for making a diamide of the formula ##STR1## by reacting a monoamide compound of the formula ##STR2## with CO and an amine or ammonia of the formula R.sub.7 R.sub.8 NH in the liquid phase under essentially anhydrous conditions at a temperature in the range from 120.degree. to 210.degree. C., where each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 is selected independently from H and a C.sub.1 to C.sub.12 hydrocarbyl containing no ethylenic or acetylenic unsaturation.
Type:
Grant
Filed:
May 3, 1985
Date of Patent:
July 11, 1989
Assignee:
The Standard Oil Company
Inventors:
Mark C. Cesa, Robert A. Dubbert, James D. Burrington
Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononitrile. Catalyst compositions useful in the process are also disclosed.
Type:
Grant
Filed:
May 16, 1988
Date of Patent:
June 27, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr.
Abstract: An improvement in the conversion of high boiling liquid organic materials to low boiling materials, and more particularly, in the process of converting heavy hydrocarbon oil feedstocks to fuel range liquids is described. In its broadest aspects, the invention comprises a process for converting high boiling hydrocarbons to lower boiling materials characterized by an increase in aromatic content and a lower pour point which comprises contacting said high boiling hydrocarbons with water at a temperature of from about 600.degree. F. to about 875.degree. F. at a pressure of at least about 2000 psi in the absence of any externally supplied catalysts, and wherein the weight ratio of water to high boiling hydrocarbons is from about 0.5:1 to about 1:1, and the water and high boiling hydrocarbon form a substantially single phase system under the elevated temperature and pressure conditions utilized.
Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononotrile. Catalyst compositions useful in the process are also disclosed.
Type:
Grant
Filed:
June 9, 1988
Date of Patent:
June 6, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
Abstract: Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkano:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst composition, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.
Type:
Grant
Filed:
May 15, 1987
Date of Patent:
June 6, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particular catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated mononitrile. Catalyst compositions useful in the process are also disclosed.
Type:
Grant
Filed:
May 31, 1988
Date of Patent:
May 30, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
Abstract: Disclosed are compositions which are blends of vinylidene chloride-vinyl chloride copolymers with certain indene or 3-methylindene containing polymers.
Type:
Grant
Filed:
June 22, 1987
Date of Patent:
May 2, 1989
Assignee:
The Standard Oil Company
Inventors:
George S. Li, J. Peter Hottois, Muyen M. Wu, Elmer J. DeWitt
Abstract: Disclosed is the hydrogenation of maleic acid in the presence of a solid iron-containing ruthenium catalyst containing the elements and the ratios indicated by the empirical formula,RuFe.sub.a M.sub.b O.sub.xwhereM is one or more of Pd and Rh,a is 0.1-5,b is zero-3, andx is a number sufficient to satisfy the valency requirements of the cations present in the catalyst,said process being effected by contacting in a reaction zone an excess of hydrogen with an aqueous solution of maleic acid in admixture with said catalyst.
Abstract: High surface area open microporous, partially crystalline, partially amorphous, solid ceramic materials containing silicon carbide with or without silica with or without carbon may be prepared by controlled pyrolysis of (RSiO.sub.1.5).sub.n gels in an inert atmosphere. The silica and carbon content, surface area, and pore size and distribution may be altered by optional subsequent processing steps to selectively remove carbon and/or silica.
Abstract: Disclosed is making a particular inorganic crystalline vanadium III oxidic compound from a pentavalent vanadium compound and at least one other or more metal cations, which process comprises (1) reducing a pentavalent vanadium oxidic compound to the V.sup.III state by heating at 100.degree. C. or less an aqueous medium slurry or solution of said pentavalent compound containing a reducing agent selected from hydrazine and hydrocarbylhydrazine, (2) providing in said aqueous medium, either before, during or after said reducing step, said other metal cation(s) in solution in the ratio called for by said particular crystalline compound, (3) removing the liquid aqueous medium, and (4) calcining the resulting dry solid at a temperature in the range from 400.degree. to 800.degree. C. in an inert atmosphere.Also disclosed is the vapor phase catalytic dehydrogenation of paraffins using certain spinels and perovskites as catalysts.
Type:
Grant
Filed:
October 29, 1987
Date of Patent:
March 28, 1989
Assignee:
The Standard Oil Company
Inventors:
Andrew T. Guttmann, James F. Brazdil, Robert K. Grasselli
Abstract: Disclosed is ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst comosition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalyst compositions useful in the process are also disclosed.
Type:
Grant
Filed:
March 28, 1988
Date of Patent:
March 21, 1989
Assignee:
The Standard Oil Company
Inventors:
Linda C. Glaeser, James F. Brazdil, Jr., Mark A. Toft
Abstract: A continuous process for the preparation of tetrahydrofuran comprises, in a single-stage process, catalytically hydrogenating the solution which results when at least one of maleic anhydride or succinic anhydride is dissolved in a monohydric aliphatic alcohol in the presence of hydrogen and a catalyst comprising the mixed oxides of copper, zinc and aluminum.
Abstract: Ammoxidation of C.sub.3 to C.sub.5 acyclic alkanes with NH.sub.3 and O.sub.2 using (1) a mole ratio of alkane:NH.sub.3 in the range from 2 to 16 and a mole ratio of alkane:O.sub.2 in the range 1 to 10 and (2) a mixture of particulate catalyst compositions, the first being especially effective to promote formation of an unsaturated nitrile and an olefin from the paraffin, and the second catalyst composition being especially effective to promote the conversion of the olefin to the unsaturated nitrile. Catalytic compositions useful in the process are disclosed.
Type:
Grant
Filed:
October 22, 1987
Date of Patent:
January 31, 1989
Assignee:
The Standard Oil Company
Inventors:
James F. Brazdil, Jr., Linda C. Glaeser, Mark A. Toft