Patents Represented by Attorney, Agent or Law Firm Lainie E. Parker
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Patent number: 7445848Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, an alkoxysilyl-functional acrylic polymer, and a curing catalyst. The invention further relates to the preparation of an alkoxysilyl-functional acrylic polymer.Type: GrantFiled: April 25, 2005Date of Patent: November 4, 2008Assignee: Akzo Nobel Coatings Internationals B.V.Inventor: Steve Alister Nixon
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Patent number: 7189776Abstract: The present invention relates to an aqueous composition comprising anionic organic polymeric particles and colloidal anionic silica-based particles. The anionic organic polymeric particles are obtainable by polymerising one or more ethylenically unsaturated monomers together with one or more polyfunctional branching agents and/or polyfunctional crosslinking agents. The anionic organic polymeric particles and the colloidal anionic silica-based particles in the aqueous composition are present in an amount of at least 0.01% by weight based on the total weight of the aqueous composition. The present invention further relates to a method for the preparation of the aqueous composition, uses of the aqueous composition and a process for the production or paper, in which the aqueous composition is added to a cellulosic suspension.Type: GrantFiled: June 11, 2002Date of Patent: March 13, 2007Assignee: Akzo Nobel N.V.Inventors: Duncan Carr, Michael Sigman
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Patent number: 7169261Abstract: An aqueous sol containing silica-based particles which has an S-value within the range of from 10 to 45%, a viscosity within the range of from 5 to 40 cP, and a molar ratio of SiO2 to M2O, where M is alkali metal or ammonium, within the range of from 10:1 to 40:1, or a silica content of at least 10% by weight. The invention further relates to a process for the production of silica-based particles comprising the steps of: (a) acidifying an aqueous silicate solution to a pH of from 1 to 4 to form an acid sol; (b) alkalising the acid sol at an SiO2 content within the range of from 4.5 to 8% by weight to; (c) allowing particle growth of the alkalised sol for at least 10 minutes, or heat-treating the alkalised sol at a temperature of a least 30° C.; and then (d) alkalising the obtained sol to a pH of at least 10.0.Type: GrantFiled: November 5, 2001Date of Patent: January 30, 2007Assignee: Akzo Nobel N.V.Inventors: Michael Persson, Marek Tokarz, Maj-Lis Dahlgren
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Patent number: 7166328Abstract: A process for primer coating of steel which is intended to be fabricated and overcoated, in which process the steel is primer coated with a primer coating comprising a silica or silicate binder, wherein the binder comprises an aqueous silica sol or alkali metal silicate having a SiO2/M2O mole ratio, where M represents total alkali metal and ammonium ions, of at least 6:1, and that after the primer coating has dried to the extent that it is touch dry it is treated with a solution which increases the film strength of the primer coating.Type: GrantFiled: March 17, 2000Date of Patent: January 23, 2007Assignee: International Coatings Ltd.Inventors: Gerard Howard Davies, Paul Anthony Jackson, Peter Joseph McCormack, Fiachra Banim
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Patent number: 7026400Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: ?wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, a glycidyl-functional acrylic polymer, and a hardener. The composition can be used as a protective coating for large structures such as ships, bridges, buildings, industrial plants, or oil rigs.Type: GrantFiled: November 26, 2003Date of Patent: April 11, 2006Assignee: International Coatings LimitedInventors: Keith Yeats, Steve Alister Nixon
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Patent number: 6989419Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, an alkoxysilyl-functional acrylic polymer, and a curing catalyst. The invention further relates to the preparation of an alkoxysilyl-functional acrylic polymer.Type: GrantFiled: December 12, 2002Date of Patent: January 24, 2006Assignee: International Coatings LimitedInventor: Steve Alister Nixon
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Patent number: 6933020Abstract: A coating composition that can be used in a process for coating a substrate where in a first step a radiation curable coating composition is applied to the substrate and/or a radiation permeable film. Next, the substrate and the film are pressed together in such a way that the coating composition is sandwiched between them. Thereafter, the coating composition is cured by irradiation through the film to obtain a coated substrate. In a subsequent step, the film is removed from the coated substrate. The coating composition applied to the film and/or the substrate is a hot melt composition comprising 20 to 100 wt. % of a radiation curable resin or mixture of radiation curable resins having a viscosity in the range of from 15 to 10,000 mPa.s in the temperature range of from 40 to 150° C.Type: GrantFiled: March 6, 2003Date of Patent: August 23, 2005Assignee: Akzo Nobel N.V.Inventors: Clive Nicholas Dove, John Sutcliffe, Ann Kerstin Birgitta Kjelqvist Lindell
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Patent number: 6899955Abstract: A process for inhibiting the fouling of a substrate in a marine fouling environment, which comprises forming on the substrate, before exposure to the said environment, a coating comprising a curable fluorinated resin of the general formula: W-L-YFC—O—Rf—CFY-L-W wherein: W is a group of the general formula —Si(R1)?(OR2)3-?, wherein ?=0, 1, or 2, preferably ?=0, R1 and R2 independently have the meaning of linear of branched C1-C6 alkyl groups, optionally containing one or more ether groups, or C7-C12 aryl or alkyl groups, and preferably R1 and R2 are C1-C4 alkyl groups; L is an organic linking group; Y is F or CF3; and Rf is a group having an average molecular weight by number between 350 and 8000, preferably between 500 and 3000, and comprising repeating units having at least one of the following structures randomly distributed along the chain: —CFXO—, CF2CF2O—, CF2CF2CF2O—, CF2CF2CF2CF2O—, CR4R5CF2CF2O—, —(CF(CF3)CF2O)—, —CF2CF(CF3)O—, wherein X is F or CF3, R4 and R5 independently have the meaning of H, Cl,Type: GrantFiled: June 1, 2001Date of Patent: May 31, 2005Assignees: International Coatings Limited, Ausimont S.p.A.Inventors: Robert Lines, David Neil Williams, Stefano Turri
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Patent number: 6834679Abstract: A transfer line for the transfer of fluid or powder-like substances from one or more sources to an outlet characterized in that the transfer line comprises at least one movable section, optionally including associated equipment such as one or more pumps or filters. The movable line section to be cleaned is coupled to a cleaning station. Water for a first washing is transferred through the movable line section and preferably at least for a part recirculated a number of times. The used water is drained off. Fresh water for a second washing is transferred through the movable line section. After transferring the used water from the second wash tank into the first wash tank, water from a third wash tank is transferred through the movable line section to the first wash tank. The washings collected in the first wash tank can be reused as a first washing for a next movable line section to be cleaned.Type: GrantFiled: July 3, 2001Date of Patent: December 28, 2004Assignee: Akzo Nobel N.V.Inventor: Kevin Briggs
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Patent number: 6818100Abstract: A process for sizing paper comprising adding to an aqueous suspension containing cellulosic fibres, and optional fillers, a sizing dispersion comprising a polymer having an aromatic group, and a sizing promoter comprising a polymer having an aromatic group, wherein the sizing dispersion and the sizing promoter are added separately to the aqueous suspension.Type: GrantFiled: August 6, 2001Date of Patent: November 16, 2004Assignee: Akzo Nobel N.V.Inventors: Erik Lindgren, Sten Frölich, Michael Persson, Barbro Magnusson
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Patent number: 6812269Abstract: A process for preparing an aqueous powder coating dispersion comprising components A and B, wherein component A is a binder resin or a mixture of binder resins and component B is a crosslinker or a mixture of crosslinkers or component A is a crosslinker or a mixture of crosslinkers and component B is a binder resin or a mixture of binder resins, wherein the process comprises the steps of: a) dispersing a composition comprising component A by the addition of an aqueous medium in a phase inversion emulsification process, b) adding component B simultaneously with or after the addition of the aqueous medium, and c) optionally mixing the obtained composition to obtain a dispersion comprising components A and B. The process enables the preparation of stable powder coating slurries with particles in the range from 50 to 800 nm.Type: GrantFiled: November 13, 2002Date of Patent: November 2, 2004Assignee: Akzo Nobel N.V.Inventors: Martinus Adrianus Antonius Maria Koenraadt, Gerard Henk Beijers, Johan Eric Borgström, Kent Raabjerg Sörensen
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Patent number: 6793728Abstract: The present invention relates to a composition for coating a metal substrate which is intended to be fabricated and overcoated, and wherein the binder comprises an aqueous silica sol or alkali metal silicate having a SiO2/M2O mole ratio of at least 6:1, where M represents total alkali metal and ammonium ions, and wherein the silica particles have an average size equal to or smaller than 10 nm. Very good results are obtained if the dried coating is post-treated with a film-strengthening solution.Type: GrantFiled: December 21, 2001Date of Patent: September 21, 2004Assignee: International Coatings Ltd.Inventors: Gerard Howard Davies, Paul Anthony Jackson, Peter Joseph McCormack
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Patent number: 6787598Abstract: A pigment paste for tinting a coating composition, the pigment paste comprising at least one branched alkyd having a viscosity below 5 Pa.s, preferably below 3.5 Pa.s, at 23° C. and at a shear rate of 100 s−1, and pigment. The pigment paste can also include an aromate-free solvent. The number average molecular weight Mn of the alkyd is preferably between 2,000 and 2,400 g/mole. The degree of branching of the alkyd is preferably at least 0.35 and preferably below 0.42. The oil length is preferably between 76 and 84. The VOC is preferably below 250 g/l.Type: GrantFiled: May 21, 2002Date of Patent: September 7, 2004Assignee: Akzo Nobel N.V.Inventors: Robertus Jozef Franciscus Jans, Eugene Michael Arnoldus De Jong
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Patent number: 6776928Abstract: The invention relates to an electrically conductive powder coating composition having anti-static properties comprising metallic fibers. Further, the coating composition shows effective EMF shielding. Very good results are found when the metallic fibers have an L/D ratio in the range between 5 and 75, wherein L is the length of the fiber and D is the diameter of the fiber. In a preferred embodiment stainless steel fibers are incorporated in the powder coating composition.Type: GrantFiled: January 29, 2002Date of Patent: August 17, 2004Assignee: Akzo Nobel N.V.Inventors: Tullio Rossini, Franco Folcio, Corrado Dotti
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Patent number: 6755971Abstract: A process for the removal of undesirable bromine salts from fluid streams, especially waste and/or drinking water, comprising the step of exposing the fluid stream to a micro-organism which biochemically aids the reduction of the undesirable bromine salts, characterized in that the microorganisms belong to the group of pure and/or enrichment strains of bacteria grown on one or more of the following: perchlorate, chlorate, and bromate, or belong to bromate respiring bacteria.Type: GrantFiled: March 28, 2003Date of Patent: June 29, 2004Assignee: AKZO Nobel N.V.Inventors: Alexander Gerardus Maria Kroon, Cornelis Gijsbertus Van Ginkel
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Patent number: 6752904Abstract: The present invention relates to a process for the removal of lignin from lignocellulose containing material comprising treating the lignocellulose containing material prior to a high-yield pulping process with a delignifying gas comprising gaseous compounds comprising at least one oxygen atom such as chlorine dioxide containing gas.Type: GrantFiled: March 2, 2001Date of Patent: June 22, 2004Assignee: Akzo Nobel N.V.Inventors: Patrick S. Bryant, John C. Sokol, Dwane S. Hutto
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Patent number: 6750300Abstract: Hot melt coating composition, particularly suitable for low viscosity requiring application techniques, the composition having a Tg below 5° C., preferably below −20° C., and a viscosity below 2,000 mPa.s, preferably below 600 mPa.s, measured at 70° C. at a shear rate of 10 s−1. The composition includes at least one amorphous binder having a Tg below 5° C., preferably below −20° C., and/or at least one crystalline or semi-crystalline binder having a melting point or melting range below 150° C. The composition can be a one component system comprising an epoxy-functional resin, a polyamine having cyanamide groups, preferably dicyandiamide, and a blocked catalyst which is unblocked at an elevated temperature below the curing temperature. Alternatively, the composition may be one component of a two-component system based on isocyanate/polyol crosslinking.Type: GrantFiled: October 16, 2001Date of Patent: June 15, 2004Assignee: Akzo Nobel N.V.Inventors: Philip Mahieu, Faridoon Qazi, Didier Vanderveken, Kent Raabjerg Sörensen, Martinus Adrianus Anthonius Maria Koenraadt
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Patent number: 6743854Abstract: Ambient temperature curing coating composition comprising a polysiloxane having the formula: wherein each R1 is selected from the group consisting of alkyl, aryl, and alkoxy groups having up to six carbon atoms, reactive glycidoxy groups, and OSi(OR3)3 groups, wherein each R3 independently has the same meaning as R1, each R2 is selected from the group consisting of hydrogen and alkyl and aryl groups having up to six carbon atoms, and wherein n is selected so that the molecular weight of the polysiloxanes is in the range of from 500 to about 2,000, a glycidyl-functional acrylic polymer, and a hardener. The composition can be used as a protective coating for large structures such as ships, bridges, buildings, industrial plants, or oil rigs.Type: GrantFiled: January 12, 2001Date of Patent: June 1, 2004Assignee: International Coatings LimitedInventors: Keith Yeats, Steve Alister Nixon
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Patent number: 6733639Abstract: The invention relates to a gas diffusion electrode (1) comprising a hydrophobic gas diffusion layer (3b), a reaction layer (3a), and a hydrophilic layer (5) arranged in the mentioned order wherein the reaction layer (3a) is arranged to a barrier layer (4), which barrier layer (4), on its opposite side, is arranged to the hydrophilic layer (5). The invention also relates to a method for manufacturing such a gas diffusion electrode (1), and to an electrolytic cell, and use thereof.Type: GrantFiled: November 9, 2001Date of Patent: May 11, 2004Assignee: Akzo Nobel N.V.Inventors: Bernd Busse, Lars-Erik Bergman
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Patent number: 6723376Abstract: A process for inhibiting the fouling of a substrate in a fouling environment, which comprises forming on the substrate, before exposure to the environment, a coating comprising a film-forming polymer (A) carrying unreacted curable silicon-containing functional groups providing latent reactivity, and thereafter applying a layer comprising a curable polymeric fouling-inhibiting material (B), more especially a curable polysiloxane or a curable flourine-containing polymer, and bonding the applied layer to the coating by a condensation curing reaction involving the unreacted functional groups thereon. The initial coating can be applied over a range of worn or damaged anti-fouling coatings. The sequential application of layers is a simpler, more flexible and more controllable procedure than is offered by complex systems designed to produce outer siloxane-rich regions. Relatively long periods are achievable.Type: GrantFiled: June 22, 2000Date of Patent: April 20, 2004Assignee: International Coatings LimitedInventors: Trevor Hamilton, Gergina Elizabth Green, David Neil Williams