Abstract: Substantial operating cost savings are realized in the recovery of acrylonitrile from an aqueous solution containing acrylonitrile by using the recovery column bottoms stream to provide heat to one or more distillation columns in the process.
Abstract: Improved amphora aggregates having a substantially spherical shape, a void center and two cavities 180.degree. apart in the external surface communicating to the void center are useful in diffusion-limited reactions and/or reactions in which heat transfer is critical. Especially preferred is use of the amphora aggregates in the hydrotreating of light hydrocarbon fractions, catalytic reforming, and fixed-bed alkylation processes.
Type:
Grant
Filed:
June 7, 1978
Date of Patent:
October 9, 1979
Assignee:
Standard Oil Company
Inventors:
Daniel R. Herrington, Albert P. Schwerko
Abstract: Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, bismuth, copper, oxygen, optionally a halogen selected from the group consisting of chlorine, bromine or iodine, and optionally, at least one element selected from the group consisting of Fe, Cr, Ni, Mn, Sb, Te, Rh, and Pd.