Abstract: A thermal printing head for printing alphanumeric characters on a thermally-responsive medium, the head being faced with a pattern of heat generating "dot" elements electrically insulated from one another and having conductive leads, with means for connecting the leads selectively to a source of electric current. The heat generating elements are formed of a film of boron phosphide. Preferably the leads are also formed of boron phosphide, integral with the elements, but "doped" to secure a high degree of conductivity.