Patents Represented by Attorney Lisa M. Golke
  • Patent number: 5827903
    Abstract: In a catalytic process for converting synthesis gas including hydrogen and carbon monoxide to hydrocarbons and oxygenates by a slurry Fischer-Tropsch synthesis, the wax product along with dispersed catalyst is removed from the slurry and purified by removing substantially all of the catalyst prior to upgrading the wax and returning a portion to the Fischer-Tropsch reaction. Separation of the catalyst particles from the wax product is accomplished by dense gas and/or liquid extraction in which the organic compounds in the wax are dissolved and carried away from the insoluble inorganic catalyst particles that are primarily inorganic in nature. The purified catalyst free wax product can be subsequently upgraded by various methods such as hydrogenation, isomerization, hydrocracking, conversion to gasoline and other products over ZSM-5 aluminosilicate zeolite, etc.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: October 27, 1998
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: Curt M. White, Michael S. Quiring, Karen L. Jensen, Richard F. Hickey, Larry D. Gillham
  • Patent number: 5721186
    Abstract: A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.
    Type: Grant
    Filed: September 6, 1996
    Date of Patent: February 24, 1998
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Malvina Farcasiu, Frank Derbyshire, Phillip B. Kaufman, Marit Jagtoyen
  • Patent number: 5711019
    Abstract: A method of removing Li.sub.2 O present in an electrolyte predominantly of LiCl and KCl. The electrolyte is heated to a temperature not less than about 500.degree. C. and then Al is introduced into the electrolyte in an amount in excess of the stoichiometric amount needed to convert the Li.sub.2 O to a Li-Al alloy and lithium aluminate salt. The salt and aluminum are maintained in contact with agitation for a time sufficient to convert the Li.sub.2 O.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: January 20, 1998
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: Zygmunt Tomczuk, William E. Miller, Gerald K. Johnson, James L. Willit