Abstract: The invention relates to an electroconductive composition comprising a polysiloxane matrix, electroconductive particles dispersed therein and an amount of a nucleophilic chemical species capable of impeding an increase in the resistivity of the composition, the nucleophilic chemical species being substantially unreactive with the particles and the matrix, and not causing any substantial impairment of the tear strength and tensile strength properties of said matrix; electroconductive composite comprising the electroconductive composition; and methods for making the electroconductive composition.