Abstract: The present invention relates to a fully formulated lubicants comprising poly ?-olefins (PAOs), prepared from a mixed ?-olefin feed, which exhibit superior Noack volatility at low pour points, and methods for preparing the fully formulated lubricants. The fully formulated lubricants include PAOs that include mixtures of 1-decene and 1-dodecene. The PAOs may be prepared by polymerization/oligomerization using an alcohol promoted BF3 in conjunction with a combination of co-catalysts.
Type:
Grant
Filed:
August 16, 2002
Date of Patent:
March 22, 2005
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Douglas E. Deckman, Mark D. Winemiller, William L. Maxwell, David J. Baillargeon, Norman Yang, Maria Caridad B. Goze
Abstract: The invention relates to a process for uniformly dispersing a transition metal metallocene complex on a carrier comprising (1) providing silica which is porous and has a particle size of 1 to 250 microns, having pores which have an average diameter of 50 to 500 Angstroms and having a pore volume of 0.5 to 5.0 cc/g; (2) slurrying the silica in an aliphatic solvent having a boiling point less than 110° C.
Type:
Grant
Filed:
September 16, 2002
Date of Patent:
February 15, 2005
Assignee:
ExxonMobil Oil Corporation
Inventors:
Yury V. Kissin, Robert I. Mink, Thomas E. Nowlin, Pradeep P. Shirodkar, Sandra D. Schregenberger, Grace O. Tsien
Abstract: The present invention relates to poly &agr;-olefins (PAO's) which exhibit superior Noack volatility at low pour points. Mixtures of 1-decene and 1-dodecene are polymerized using an alcohol promoted BF3 in conjunction with a combination of cocatalysts. The reaction mixture is distilled to remove the unreacted monomeric and dimeric species. The resulting product is then hydrogenated to saturate the oliogomers to provide a hydrogenated product which has a viscosity of 5 cSt. This product is distilled to provide PAO's of varying viscosity grades. The 4 cSt PAO is comprised mostly of trimers and tetramers while the 6 cSt product is comprised of trimers, tetramers, and pentamers.
Abstract: An integrated process for the production of a dialkyl carbonate and a diol from an alkylene oxide, carbon dioxide and an aliphatic monohydric alcohol is described in which an alkylene oxide is first reacted with carbon dioxide in the presence of a halogen-free carbonation catalyst to provide a corresponding cyclic carbonate and the cyclic carbonate is then reacted with an aliphatic monohydric alcohol in the presence of the carbonation catalyst and/or a transesterification catalyst and recycling the carbonation catalyst to provide a corresponding dialkyl carbonate and diol, wherein the dialkyl carbonate product exhibits a halogen concentration of about 5 ppm or less.
Type:
Grant
Filed:
March 25, 2002
Date of Patent:
August 10, 2004
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Richard H. Schlosberg, J. Scott Buchanan, Jose Guadalupe Santiesteban, Zhaozhong Jiang, William A. Weber
Abstract: This invention relates to a lubricating composition comprising a major amount of an oil of lubricating viscosity, at least one organic polysulfide comprising less than about 88% dihydrocarbyl trisulfide, from up to about 5% dihydrocarbyl disulfide, and more than about 7 wt. % dihydrocarbyl higher polysulfides, and at least one phosphorus or boron compound, or mixtures of two or more thereof. The invention also relates to concentrates and greases containing the above combination. The invention also relates to methods of making the organic polysulfide.
Type:
Grant
Filed:
March 5, 2002
Date of Patent:
February 10, 2004
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
William T. Sullivan, Percy Rohinton Kanga, Thomas Smith Coolbaugh
Abstract: The present invention relates to methods for production of arylsulfides wherein an aromatic compound is reacted with elemental sulfur in the presence of solid acid catalyst. The solid acid catalyst can be a zeolite. The methods are useful for producing alkylated diphenylsulfides from aromatic compounds and elemental sulfur.
Type:
Grant
Filed:
October 9, 2001
Date of Patent:
April 15, 2003
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Margaret M. Wu, Philip Trotto, Shifang Luo, Jose G. Santiesteban, Hye Kyung C. Timken, Sandeep S. Dhingra, Simon C. Weston, Richard T. Spissell
Abstract: A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate-based foam; (b) a polyol-based foam; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate-based foam and the polyol-based foam; and (d) a blowing agent which comprises a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.
Type:
Grant
Filed:
July 24, 2001
Date of Patent:
January 14, 2003
Assignee:
Exxon Mobil Chemical Patents Inc
Inventors:
Robert H. Blanpied, James Darryl Thornsberry, Steven E. Silverberg, James R. Lattner, C. Harry McMullen, Leonel E. Sanchez, Tronze-I Dennis Wu
Abstract: A continuous process for the manufacture of alkylated diphenyl compounds such as diphenyl ether and diphenyl sulfides by alkylating a diphenyl compound such as diphenyl ether with an olefinic alkylating agent by passing a continuous flow of the diphenyl compound and the olefin over a solid particulate catalyst which comprises a molecular sieve of the MCM-22 family. The process is flexible. By adjusting feed compositions, products of different compositions and wide range of properties are produced.
Type:
Grant
Filed:
December 29, 1999
Date of Patent:
June 18, 2002
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Margaret M. Wu, Rene B. Lapierre, Gilbert R. Jersey, Andrew Gene Horodysky
Abstract: A method is provided for co-producing dialkyl carbonate and alkanediol by reacting alkylene carbonate with alkanol in the presence of an amorphous aluminosilicate catalyst containing alkali metal, alkaline earth metal, or a combination thereof.
Type:
Grant
Filed:
February 4, 2000
Date of Patent:
January 29, 2002
Assignee:
ExxonMobil Chemical Patents Inc.
Inventors:
Clarence D. Chang, Larry E. Hoglen, Zhaozhong Jiang, Rene B. LaPierre
Abstract: A process for the carbonylation of alkyl aromatic compounds uses acidic ionic liquids. In one embodiment, the ionic liquid is intrinsically acidic, having an anion mole fraction of greater than 0.5. The ionic liquids include those comprised of a quaternary nitrogen-containing cation and a metal halide anion. The process provides for good conversion and selectivity in the production of the corresponding aromatic aldehyde compound.
Abstract: A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate-based foam; (b) a polyol-based foam; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate-based foam and the polyol-based foam; and (d) a blowing agent which comprises a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.
Type:
Grant
Filed:
October 25, 1999
Date of Patent:
October 23, 2001
Assignee:
ExxonMobil Chemical Patents, Inc.
Inventors:
Robert H. Blanpied, James Darryl Thornsberry, Steven E. Silverberg, James R. Lattner, C. Harry McMullen, Leonel E. Sanchez, Tronze-I Dennis Wu