Patents Represented by Attorney Lowell H. McCarter
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Method of casting in place an ion-sensitive membrane and ion-sensitive electrode using said membrane
Patent number: 4366038Abstract: A one-piece disposable electrode comprising a sealed chamber containing an electrolyte solution, silver-silver chloride conductor in the electrolyte solution in the chamber and a cast-in-place membrane essentially flush with an exterior wall of this chamber for exposure to a biological fluid whose ion content is to be measured.Type: GrantFiled: August 4, 1980Date of Patent: December 28, 1982Assignee: Instrumentation Laboratory Inc.Inventors: Susan D. Kearney, Gustav H. Dreier, Alan D. Cormier -
Patent number: 4247594Abstract: An electrically conductive resinous composition is prepared by cleaning the surface of copper flakes, mixing from about 25 to 75 percent by weight copper flakes with a resinous composition containing a curative selected from the group consisting of a dicyandiamide, a boron trifluoride releasing complex, a boron trichloride releasing complex or mixtures thereof, curing a layer of the resinous composition on an insulated substrate whereby a nonconductive layer is prepared and momentarily applying a voltage to the nonconductive resinous layer whereby the resinous layer becomes conductive. The one component resinous composition comprises from about 25 to about 70 percent by weight copper flakes with the balance of the compositions consisting of a resinous binder with from 1 to about 10 parts per hundred parts resinous binder of a curative selected from dicyandiamide, a boron trifluoride releasing complex, a boron trichloride complex and mixtures thereof.Type: GrantFiled: April 30, 1979Date of Patent: January 27, 1981Assignee: Marshall & Pike Enterprises Inc.Inventors: Madilyn R. Shea, Earl A. Pike
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Patent number: 4210567Abstract: Subject of this invention are plastisols based on selected plasticizers and on polymers of certain acrylic or methacrylic monomers, viz. mainly (i) t-butyl acrylate, a C.sub.1-4 alkyl, especially methyl, acrylate or cyclohexyl methacrylate, and optionally also (ii) one or more comonomers selected from methacrylates of aliphatic C.sub.2 to C.sub.10 alcohols, acrylates of aliphatic C.sub.1 to C.sub.10 alcohols, styrene and alpha-methyl styrene. The glass transition temperature of the polymer is above 35.degree. C., its average degree of polymerization more than 400 and its average particle size in the plastisol is 0.1 to 500 microns.Type: GrantFiled: February 27, 1978Date of Patent: July 1, 1980Assignee: Teroson G.m.b.H.Inventor: Bernhard Kosters
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Patent number: 4182649Abstract: Disclosed herein is a composite, self-supporting, polyurethane foam sheet prepared by forming an aqueous dispersion of hydrophilic polyurethane foam particles with fibers to serve as a binder therefor, wet-layering the dispersion onto a supporting screen to form a sheet, and removing water from the sheet. If desired, a porous web, woven or non-woven, e.g. paper, cloth, etc., can be positioned on the screen with the dispersion being layered out onto the web to form a laminar composite structure. Whether in sheet form or as a laminar structure the product of the invention is formed rapidly and possesses a desirable soft or cushioning feel.Type: GrantFiled: February 11, 1977Date of Patent: January 8, 1980Assignee: W. R. Grace & Co.Inventors: Irving E. Isgur, Andrew B. Holmstrem, Norman J. Hayes
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Patent number: 4160752Abstract: Water based polymeric dispersions, such as closure sealing compounds, which comprise a polymer latex, a resin component and a particulate nonplastic component such as fillers and pigments, can yield improved sealing, adhesion, preservative or decorative films when they are prepared by first suspending the inorganic particulate fillers and pigments in the molten resin components of the formulation, then emulsifying this suspension in water and finally combining the aqueous dispersion obtained with the rubber latex and the other ingredients of the final compound.Type: GrantFiled: November 8, 1976Date of Patent: July 10, 1979Assignee: W. R. Grace & Co.Inventors: Robert H. Akiyama, Leo B. Towle
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Patent number: 4139607Abstract: Certain fluorinated dimethyl ethers have been found to possess the stability, the compatibility and sufficient freedom from deleterious physiological effects to be used as aerosol propellants in cosmetic, hygienic, pharmaceutical and other personal products. Bis(difluoromethyl) ether is also free of the chlorine atoms believed responsible for some destruction of ozone in the upper atmosphere. Bis(difluoromethyl) ether and carbon dioxide provides a combined gaseous and liquefied propellant system having improved aerosol pattern and emptying characteristics and eliminates the compressed gas effect usually shown by use of carbon dioxide in propellant systems.Type: GrantFiled: August 5, 1977Date of Patent: February 13, 1979Assignee: W. R. Grace & Co.Inventors: Charles W. Simons, Gerald J. O'Neill, Joel A. Gribens
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Patent number: 4127124Abstract: Bioimplant three dimensional latice of hydrophilic polyurethane having a backbone of polyetherol or polyesterol, end-capped with aliphatic or aromatic diisocyanate, chain branched with polyol and bound into a latice by chain extension alkyl diols. The method of producing such a latice. An extension would be the use of the latice for other medical and veterinary purposes.Type: GrantFiled: May 12, 1977Date of Patent: November 28, 1978Assignee: W. R. Grace & Co.Inventors: Donald C. Clagett, Michael J. Svetly, Peter H. Scott
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Patent number: 4127613Abstract: Methyl trifluorovinyl ether can be stabilized with respect to liquid and vapor phase deflagration or explosive potential by the addition of certain fluorohaloalkanes to the methyl trifluorovinyl ether.Type: GrantFiled: October 20, 1977Date of Patent: November 28, 1978Assignee: W. R. Grace & Co.Inventor: Gerald J. O'Neill
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Patent number: 4123817Abstract: The present invention relates to a windshield cleaning system and more particularly to a windshield cleaning system which utilizes both an oscillating wiper blade and a washer fluid system for transporting the washer fluid through the blade to outlets in the upper portion of the blade to clean the outer surface of the windshield.The windshield wiper blade includes a hollow elongated elastic material body enveloping a flexible elongated spline member. The body and the spline member cooperatively form elongated liquid passageways in the body. A flexible contact member extends downwardly from the elastic body to contact the windshield.Type: GrantFiled: August 8, 1977Date of Patent: November 7, 1978Inventor: William J. Hartery
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Patent number: 4119746Abstract: Porous, fibrous materials such as non-woven polyester or polypropylene web materials, cotton web, paper and other materials are saturated with a storage stable one-package latex composition. The latex composition is modified with a temperature sensitive cross-linking agent and neutralizing agents. The latex composition is tailored such that a fibrous material may be impregnated and dried at controlled temperature whereby a thermoplastic resin saturant web intermediate stock material having thermoset properties is produced. The cross-linking system in the latex composition is later activated in a specific manufacturing process at heat forming and molding temperatures to obtain a specifically shaped manufacture of desired rigidity and flexibility.Type: GrantFiled: June 14, 1977Date of Patent: October 10, 1978Assignee: W. R. Grace & Co.Inventor: Merrill Bleyle
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Patent number: 4119602Abstract: Disclosed herein are aqueous dispersions of blocked hydrophilic polyether urethane prepolymers and codispersions thereof with synthetic polymer latices. Also disclosed are methods of preparing the dispersions as well as polyurethane coatings and films prepared therewith. The dispersion/codispersions are characterized by good mechanical stability and resistance to freeze - thaw cycles. Coatings, films and impregnated articles prepared therefrom possess good physical properties. Coatings and films prepared from codispersions containing acrylic latex possess physical properties, chemical solvent resistance, etc. comparable to solvent-based urethanes.Type: GrantFiled: April 7, 1977Date of Patent: October 10, 1978Assignee: W. R. Grace & Co.Inventors: Irving E. Isgur, Robert R. Alexander, Thomas P. Moy
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Patent number: 4110508Abstract: The invention disclosed is for a foam sheet fabric prepared using a hydrophilic crosslinked polyurethane component prepared by reacting an isocyanate capped polyoxyethylene polyol reactant with large amounts of an aqueous reactant. The resultant fabrics may be characterized with a broad spectrum of improved properties including improved comfort, moisture control, ease of processing and may contain selective additives such as fibers, fire retardants or the like.Type: GrantFiled: February 9, 1976Date of Patent: August 29, 1978Assignee: W. R. Grace & Co.Inventors: Irving E. Isgur, Andrew B. Holmstrem, Norman J. Hayes
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Patent number: 4109027Abstract: Disclosed is an electrostatic coating device and method employing highly charged particles that are charged remote from the articles to be coated and then delivered to an area where they are to be applied by conveying them in a moving air stream. The movement is stopped by closing off the air stream, suspending the particles in space. Thereafter the particles are applied to an article by electrostatics. Special components are a powder entraining device which uses air fed at the bottom to erode the powder, feeds additional air from above and removes entrained powder from below; a charging device using the reaction of two converging opposed vortexes to oscillate the powder turbulently through an isolated high voltage electrical zone; and a multiple valve that feeds the charged powder to a can and vents the can, then isolates the can, bypassing the powder.Type: GrantFiled: January 21, 1976Date of Patent: August 22, 1978Assignee: W. R. Grace & Co.Inventor: James R. Crose
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Patent number: 4081503Abstract: Container closures are given the customary sealing gasket of plastics material by a two stage deformation of a pellet of the plastics material. In a first stage the material is partly deformed and is heated by direct conduction from a heated deforming member, and in the second stage a relatively cool final moulding die effects further deformation to impart the desired finished configuration to the gasket. The pressure member, and possibly also a workpiece support on which the upturned closure rests, is heated by means of a radiant heat source directing radiant heat onto a blackened roughened surface of the pressure member, and the workpiece support where applicable. The pressure member has a low-adhesion surface of polytetrafluoroethylene.Type: GrantFiled: July 25, 1974Date of Patent: March 28, 1978Assignee: W. R. Grace & Co.Inventor: Keith Shotbolt
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Patent number: 4062703Abstract: Zinc ammonium chloride type fluxes can be made that have longer life and reduced smoke characteristics by incorporating 1 to 50% sand into conventional fluxes for use on metal container side seam soldering baths, as well as into galvanizing fluxes.Type: GrantFiled: November 17, 1975Date of Patent: December 13, 1977Assignee: W. R. Grace & Co.Inventor: Joseph Vastag
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Patent number: 4020143Abstract: A metal recovery process in which copper, nickel, cobalt and molybdenum are recovered by reducing comminuted raw manganese nodules and leaching the reduced nodules with an aqueous ammoniacal solution to obtain a leach solution containing these metal values. In order to recover copper from leach solutions by techniques such as ion exchange extraction, it is desirable to oxidize the copper to the cupric state.In another embodiment, oxidation is required to bring about the solution of reduced metallic metal values of copper, nickel and cobalt or to convert lower valence ions of these metals to a more highly oxidized state. The present invention is an improvement in the foregoing metal recovery processes. In the present invention manganese nodules are used as the oxidizing agent to oxidize slurries containing pre-reduced manganese nodules which have lower valence ions of metals such as copper or the metal itself.Type: GrantFiled: August 26, 1974Date of Patent: April 26, 1977Assignee: Kennecott Copper CorporationInventors: Robert E. Lueders, Roger N. Kust, Lester J. Szabo
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Patent number: 4018866Abstract: A process in which copper, nickel, cobalt and molybdenum are recovered by direct leaching of comminuted raw manganese nodules after the nodules are reduced in a reduction circuit with an aqueous ammoniacal leach solution containing cuprous ions. An improvement is disclosed which results from recycling a portion of the metal values recovered back to the reduction circuit as a solid basic metal carbonate. The metal carbonate recycle enables the size of the reactors in the reduction circuit to be reduced. The recycle also increases the efficiency of the process by facilitating the solubilization of copper. Another aspect of the invention resides in the advantages of maintaining solubilized copper in amounts between 10 grams per liter and the solubility limit in the reduction circuit.Type: GrantFiled: November 3, 1975Date of Patent: April 19, 1977Assignee: Kennecott Copper CorporationInventor: Lester J. Szabo
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Patent number: 4012482Abstract: A process for scrubbing extracted ammonia from oximes. The process is particularly adaptable as a secondary scrub, prior to acid stripping, in a process in which metals are recovered from ammoniacal leach liquors by solvent extraction. The present process eliminates the pH rise of the aqueous scrub liquor associated with acid scrubbing of ammonia from oximes into which ammonia has been extracted. Extractable metal sulfates are utilized in an aqueous scrub solution at a pH <7. The net result is an exchange of ammonia on the oxime for copper or nickel in the scrub solution with resulting loading of copper or nickel by the oxime and the formation of ammonium sulfate in the aqueous scrub solution with no change in the pH of the aqueous scrub solution.Type: GrantFiled: July 21, 1975Date of Patent: March 15, 1977Assignee: Kennecott Copper CorporationInventors: David L. Natwig, Roald R. Skarbo
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Patent number: 4005173Abstract: Organic acids are added to ammoniacal leach liquors containing base metals such as copper, nickel and cobalt. Ammonia and carbon dioxide are then stripped from the leach liquor by heating the leach liquor sufficiently to drive off the ammonia and carbon dioxide. The resulting loss of ammonia and carbon dioxide causes the pH of the leach liquor to drop and enables the metal values to load onto the organic acid. Metal values are selectively stripped from the loaded organic acid.Type: GrantFiled: March 3, 1975Date of Patent: January 25, 1977Assignee: Kennecott Copper CorporationInventors: J. Paul Pemsler, John K. Litchfield
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Patent number: D274653Type: GrantFiled: January 18, 1982Date of Patent: July 10, 1984Inventor: Clement C. Peiren