Patents Represented by Attorney, Agent or Law Firm Lucas K. Shay
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Patent number: 5686293Abstract: A bacterial culture which comprises a Campylobacter-like species is provided. The bacterial culture is capable of oxidizing a sulfide compound in a fluid such as, for example, a produced brine. Also provided is a process for substantially reducing sulfide content in a fluid wherein the process comprises contacting the fluid with a bacterial culture which comprises a Campylobacter-like species.Type: GrantFiled: July 7, 1995Date of Patent: November 11, 1997Assignee: Phillips Petroleum CompanyInventors: Gary E. Jenneman, Diane Gevertz
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Patent number: 5684075Abstract: A composition is provided which comprises an acrylamide-containing polymer comprising repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide. Also provided is a water-based composition which can be used as drilling fluid wherein the composition comprises calcium chloride, an acrylamide-containing polymer which has repeat units derived from at least two monomers, a polypropylene glycol, and optionally, a polysaccharide.Type: GrantFiled: February 21, 1995Date of Patent: November 4, 1997Assignee: Phillips Petroleum CompanyInventors: Bharat B. Patel, T. George Muller
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Patent number: 5659107Abstract: Cyclopentadiene is separated from dicyclopentadiene by means of a sorbent material which contains (i) alkali metal oxide(s) and/or hydroxide(s) and (ii) an inorganic support material. The more preferred sorbent material is Na.sub.2 O and/or NaOH on alumina.Type: GrantFiled: May 7, 1996Date of Patent: August 19, 1997Assignee: Phillips Petroleum CompanyInventors: Tin-Tack Peter Cheung, Marvin M. Johnson
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Patent number: 5659086Abstract: A process which can be used for producing an organic disulfide is provided. The process comprises the steps of: (1) contacting a base and a mercaptan under an effective condition for forming a brine phase comprising the base and a basic salt of a mercaptan; (2) contacting the brine phase with a mercaptan and hydrogen peroxide under a condition sufficient to effect the formation of an aqueous phase and an organic phase; (3) separating the aqueous phase from the organic phase; (4) recovering the organic phase; and optionally, (5) removing a portion of water from the aqueous phase and thereafter repeating the steps of (2) to (5).Type: GrantFiled: June 6, 1995Date of Patent: August 19, 1997Assignee: Phillips Petroleum CompanyInventors: Alex Pauwels, Dean E. Stinn
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Patent number: 5650633Abstract: A composition comprising a nitrogen-containing olefinic compound and a process for using the nitrogen-containing olefinic compound to produce a water-soluble polymer which has applications in a subterranean formation are provided. The nitrogen-containing olefinic compound can be made from an amine and an alkylating agent. The polymer produced can be used in drilling fluids, workover fluids, completion fluids, permeability corrections, water or gas coning prevention, fluid loss prevention, matrix acidizing, fracture acidizing, and combinations of any two or more thereof.Type: GrantFiled: December 20, 1995Date of Patent: July 22, 1997Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Ahmad Moradi-Araghi, Odd Ivar Eriksen
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Patent number: 5642783Abstract: A process for altering the permeability of a subterranean formation comprises injecting into the subterranean formation a gelling composition which comprises a carboxylate-containing polymer, a crosslinking agent, and a liquid such as a produced brine wherein the polymer forms a gel in the formation, in the presence of the crosslinking agent. The polymer can have a molecular weight of from about 10,000 to about 30,000,000, contain about 0.Type: GrantFiled: May 17, 1996Date of Patent: July 1, 1997Assignee: Phillips Petroleum CompanyInventors: Ahmad Moradi-Araghi, Iqbal Ahmed
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Patent number: 5622906Abstract: A composition, which can be used as catalyst for producing an olefin polymer having a multimodal molecular weight distribution, is provided that comprises a transition metal-containing catalyst, a metallocene, and a boron-containing organoaluminoxane, wherein each component of the composition is present in an effective amount so that an olefin polymer having a multimodal molecular weight distribution can be produced using the composition as catalyst, preferably in the presence of a cocatalyst. Also provided is a process for preparing the composition which comprises: (1) contacting a transition metal-containing catalyst with an organoaluminoxane dispersed in a solvent to form a slurry; (2) combining the slurry with a boroxine to prepare a combination of a transition metal-containing catalyst and boron-containing organoaluminoxane; and (3) contacting the combination with a metallocene. Further provided is a process for polymerizing an olefin to prepare an olefin polymer using the composition.Type: GrantFiled: September 16, 1994Date of Patent: April 22, 1997Assignee: Phillips Petroleum CompanyInventor: Ted M. Pettijohn
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Patent number: 5618981Abstract: A process which can be used to produce an aromatic sulfide compound having the formula of (R.sub.4-n)(X.sub.n)(W)Ar--S--R' is provided. The process comprises contacting, in the presence of a surfactant, a halo-substituted aromatic compound in an aqueous solution with a salt of a mercaptan under conditions sufficient to produce the aromatic sulfide in which the halo-substituted aromatic compound and salt of mercaptan are each present in an amount effective to synthesize the aromatic sulfide wherein R is hydrogen or a hydrocarbyl radical, X is a hlogen, n is a number from 0 to 3, W is a substituent, Ar is an aromatic ring, and R' is a hydrocarbyl radical.Type: GrantFiled: May 19, 1995Date of Patent: April 8, 1997Assignee: Phillips Petroleum CompanyInventor: James E. Shaw
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Patent number: 5585334Abstract: A process which can be used to dissolve sulfur deposits or sulfur plugs in gas wells, oil wells, vessels, or conduits for transporting a fluid containing sulfur is provided. The process comprises contacting the sulfur deposits or sulfur plugs under conditions sufficient to dissolve sulfur wherein the composition comprises an organic sulfide, a base, a surfactant, and optionally, a mercaptan and is present in an amount effective to dissolve sulfur.Type: GrantFiled: April 21, 1995Date of Patent: December 17, 1996Assignee: Phillips Petroleum CompanyInventor: James E. Shaw
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Patent number: 5576271Abstract: A composition useful for viscosifying a water-based fluid is provided which comprises a polymer such as guar gum, a metal compound such as an aluminum compound. The composition can also contain a polymer such as guar gum, a magnesium compound such as magnesium oxide, a metal aluminate such as sodium aluminate or a metal compound such as an aluminum compound, and optionally a fatty acid or salts thereof. The water-based fluid can also contain a clay such as bentonite. A process for viscosifying a water-based fluid and for substantially retaining the viscosity of the water-based fluid is also provided which comprises contacting the fluid with the composition described herein. Also disclosed is a process for controlling water loss of a water-based drilling fluid wherein the process comprises contacting the fluid with the composition described herein.Type: GrantFiled: August 31, 1994Date of Patent: November 19, 1996Assignee: Phillips Petroleum CompayInventor: Bharat B. Patel
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Patent number: 5565602Abstract: A process which can be used for producing thiolcarbamates is provided wherein the process comprises contacting a reaction mixture with a hydrocarbyl chloride such as, for example, benzyl chloride under a condition which is sufficient to produce a product mixture wherein the reaction mixture comprises carbonyl sulfide, an amine such as, for example, a secondary amine, a solvent; the solvent comprises a tertiary amine; and the reaction mixture, hydrocarbyl halide, and solvent are each present in an amount sufficient to effect the production of a thiolcarbamate. Optionally, the reaction mixture can also comprise a metal hydroxide. Further optionally, the product mixture can be contacted with a metal hydroxide if the reaction mixture does not comprise a metal hydroxide.Type: GrantFiled: March 13, 1995Date of Patent: October 15, 1996Assignee: Phillips Petroleum CompanyInventors: Michael S. Matson, Dean E. Stinn, Michael D. Mitchell
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Patent number: 5565517Abstract: A process for preparing an organic polysulfide polymer, such as polyethylene trisulfide, is provided which comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a basic catalyst wherein the dimercaptan, elemental sulfur, and basic catalyst are each present in an effective amount to effect the preparation of the organic polysulfide polymer. A process for controlling the molecular weight of an organic polysulfide polymer is also provided which comprises contacting a mercaptan with a dimercaptan and sulfur, in the presence of a basic catalyst, under conditions sufficient to prepare an organic polysulfide polymer.Type: GrantFiled: November 16, 1994Date of Patent: October 15, 1996Assignee: Phillips Petroleum CompanyInventors: Howard F. Efner, James E. Shaw
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Patent number: 5559271Abstract: A composition which comprises a major amount of an organic polysulfide and an odor-masking amount of an odor-masking compound selected from the group consisting of wintergreen, cinnamons, vanillins, terpenes, sesquiterpenes, and combinations of any two or more thereof is provided wherein the composition has a more pleasant odor than the organic polysulfide.Type: GrantFiled: July 26, 1995Date of Patent: September 24, 1996Assignee: Phillips Petroleum CompanyInventors: James E. Shaw, Howard F. Efner
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Patent number: 5547025Abstract: A process for altering the permeability of a subterranean formation comprises injecting into the subterranean formation a gelling composition which comprises a carboxylate-containing polymer, a crosslinking agent, and a liquid such as a produced brine wherein the polymer forms a gel in the formation, in the presence of the crosslinking agent. The polymer can have a molecular weight of from about 10,000 to about 1,000,000, contain about 0.01 to about 5 mole % of a carboxylate group, and be present in the gelling composition in the range of from about 100 to about 100,000 mg per liter of the composition.Type: GrantFiled: April 14, 1995Date of Patent: August 20, 1996Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Ahmad Moradi-Araghi
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Patent number: 5547281Abstract: An apparatus for fluid flow communication is disclosed which comprises a substantially tubular member having first and second opposite end portions; a first end wall secured to and closing the first end portion of said substantially tubular member wherein the first end wall has at least one first aperture extending therethrough; a second end wall secured to and closing the second end portion of the substantially tubular member wherein the second end wall has at least one second aperture extending therethrough; an intermediate wall disposed within the substantially tubular member intermediate the first and second end walls and having a circumferential outer edge; and support means disposed within the substantially tubular member for fixedly securing the intermediate wall relative to the inner surface of the substantially tubular member whereby the circumferential outer edge of the intermediate wall and the inner surface of the substantially tubular member define a substantially annular passage.Type: GrantFiled: October 11, 1994Date of Patent: August 20, 1996Assignee: Phillips Petroleum CompanyInventor: John R. Brooks
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Patent number: 5545714Abstract: A process for preparing an organic disulfide polymer such as polyethylene disulfide which is used in batteries comprises contacting a dimercaptan such as 1,2-ethanedithiol with elemental sulfur using a mixture of a basic compound such as NaOH and an ethoxylated alcohol such as Union Carbide's TERGITOL.RTM. 15-S-7 having the formula of R.sup.2 O(CH.sub.2 CH.sub.2 O).sub.7 H as catalyst wherein the dimercaptan is present in excess amount to effect the preparation of the disulfide polymer.Type: GrantFiled: May 25, 1995Date of Patent: August 13, 1996Assignee: Phillips Petroleum CompanyInventors: James E. Shaw, William E. Sattich, Howard F. Efner
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Patent number: 5536706Abstract: A process for inhibiting the deposition or precipitation of wax in a hydrocarbon fluid such as, for example, a crude oil, and for operating a pipeline is disclosed. The process comprises combining an effective amount of a polymer with the hydrocarbon fluid wherein the polymer comprises random repeat unit of butadiene. Also provided is a composition which comprises a hydrocarbon fluid and a random copolymer which comprises repeat units of styrene and butadiene.Type: GrantFiled: September 2, 1994Date of Patent: July 16, 1996Assignee: Phillips Petroleum CompanyInventors: Lyle R. Kallenbach, Marvin M. Johnson, Howard F. Efner
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Patent number: 5532212Abstract: A composition useful for viscosifying a water-based fluid is provided which comprises a metal aluminate such as sodium aluminate, or a blend of a viscosity promoter such as sodium aluminate and a magnesium compound such as magnesium oxide, or a clay such as bentonite and the blend. The water-based fluid can also contain a clay such as bentonite. A process for viscosifying a water-based fluid is also provided which comprises contacting the fluid with the composition described herein. Also disclosed is a process for controlling water loss of a water-based drilling fluid wherein the process comprises contacting the fluid with the composition described herein.Type: GrantFiled: September 27, 1995Date of Patent: July 2, 1996Assignee: Phillips Petroleum CompanyInventor: Bharat B. Patel
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Patent number: 5530163Abstract: A process which can be used to produce organic polysulfide compounds is provided. The process comprises contacting, in the presence of a catalyst, a mercaptan with sulfur under conditions sufficient to produce an organic polysulfide and thereafter, the resulting reaction medium is contacted with an acid to produce an acid-treated organic polysulfide wherein the mercaptan, sulfur, and catalyst are each present in an amount effective to produce an organic polysulfide. The acid-treated organic polysulfide can be purified and recovered.Type: GrantFiled: January 23, 1995Date of Patent: June 25, 1996Assignee: Phillips Petroleum CompanyInventor: James E. Shaw
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Patent number: 5523367Abstract: A composition which comprises a water-polymer and a process for using the polymer to absorb a fluid are disclosed. The water-insoluble polymer comprises repeate units derived from: (a) an ampholytic monomer which is a polymerizable vinylic amine-containing monomer and an acid having an ethylenic moiety; (b) at least one olefinic comonomer; and optionally, (c) one crosslinking agent which has at least two polymerizable olefinic functionalities wherein the olefinic functionalities are suitable for crosslinking.Type: GrantFiled: January 23, 1995Date of Patent: June 4, 1996Assignee: Phillips Petroleum CompanyInventor: Iqbal Ahmed