Patents Represented by Attorney M. B. Kapustij
  • Patent number: 5259978
    Abstract: A traction fluid comprising:(i) a diesteric compound or its derivative represented by the formula ##STR1## wherein A' is an ester linkage of --COO-- or --OOC--, n is a number having a value of from 1 to 10, R.sub.1 is independently selected from hydrogen and alkyl groups containing from 1 to 8 carbons, and R.sub.2 is independently selected from hydrogen and alkyl group containing from 1 to 3 carbons; and(ii) from 0.1 to 95% by weight of a branched poly-.alpha.-olefin .
    Type: Grant
    Filed: February 1, 1993
    Date of Patent: November 9, 1993
    Assignee: Toa Nenryo Kogyo, K.K.
    Inventors: Narihiko Yoshimura, Yasuji Komatsu, Hirotaka Tomizawa
  • Patent number: 5232614
    Abstract: Substituted para-phenylene diamines have been found to be effective antioxidants capable of protecting crankcase lubricating oils from thickening and sludge formation after prolonged exposure to oxygen at elevated temperature.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: August 3, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Terence Colclough, Andrew J. D. Ritchie
  • Patent number: 5167848
    Abstract: Oil soluble grafted ethylene-alpha-olefin copolymer useful as a viscosity modifier for oleaginous compositions comprising:(i) backbone copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crysallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.w /M.sub.w of less than 1.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: December 1, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski, John E. Johnston
  • Patent number: 5112510
    Abstract: A lubricating oil composition exhibiting improved flow properties, specifically low temperature flow properties, and viscometric properties, particularly low temperature viscometric properties comprising lubricating oil and(i) an amount effective to improve the low temperature flow properties of said lubricating oil composition of additive consisting essentially of at least one low molecular weight non-ethylene containing polymer or interpolymer containing pendent ester groups comprising repeating methylene units derived from mixture of aliphatic alcohols, said mixture containing at least about 25 weight percent C.sub.
    Type: Grant
    Filed: February 28, 1989
    Date of Patent: May 12, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Albert Rossi
  • Patent number: 5085792
    Abstract: A traction fluid comprising:(i) at least one diester or its derivative represented by the formula ##STR1## wherein A' is an ester linkage, n is an integer of 1 to 6, R.sub.1 is independently selected from hydrogen and alkyl groups containing from 1 to 8 carbon atoms, and R.sub.2 is independently selected from alkyl groups containing from 1 to 3 carbon atoms; and(ii) from 0.1 to 70 wt. % of at least one branched poly-alpha-olefin.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: February 4, 1992
    Assignee: Toa Nenryo Kogyo, K.K.
    Inventors: Yoshimura Narihiko, Hirotaka Tamizawa, Yasuji Komatsu
  • Patent number: 5085788
    Abstract: An oil soluble dispersant comprising the reaction products of:(1) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides, (ii) long chain hydrocarbon having a polyamine attached directly thereto, and (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyalkylene polyamine, said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least one polyepoxide.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: February 4, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Bundberg
  • Patent number: 5069804
    Abstract: Improved stability of overbased phenates, particularly when formulated with overbased sulphonates, as well as improved foaming tendency and viscosity is obtained by treating the overbased phenate, either during or subsequent to the overbasing process, with from 0.1 to 10 wt. %, preferably 2 to 6 wt. %, of a carboxylic acid with a C.sub.10 to C.sub.24 unbranched segment, e.g. behenic acid.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: December 3, 1991
    Assignee: Exxon Research & Engineering
    Inventors: John F. Marsh, Joseph M. Swietlik
  • Patent number: 5068047
    Abstract: Degraded molecular weight copolymers of ethylene alpha-olefin are provided. The ethylene alpha-olefin copolymers, before degradation, are characterized by having a narrow molecular weight distribution and are comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains. The degraded copolymers are useful as viscosity index improvers for oils.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: November 26, 1991
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: David Y. Chung, Mark J. Struglinski
  • Patent number: 5066598
    Abstract: A process for preparing a baseoil blend of predetermined coking tendency, and for measuring the effectiveness of additives for reducing coking tendency in baseoils, utilizing the relationship of the content of volatile fractions and low boiling fractions in baseoil to the onset and/or progression of asphaltene formation.
    Type: Grant
    Filed: October 23, 1989
    Date of Patent: November 19, 1991
    Assignee: Exxon Chemical Patents, Inc.
    Inventor: Ghazi B. Dickakian
  • Patent number: 5053151
    Abstract: The present invention is directed to a viscosity index improver for lubricating oil compositions comprising the reaction product of A a copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer grafted with ethylenically monoansaturataed carboxylic acid material and B amido-amine or thioamido-amine comprising the reaction product of a polyamine and alpha, beta-unsaturated compound of the formula ##STR1## wherein X is oxygen or sulfur, Y is OR.sup.4, --SR.sup.4 or ##STR2## and R.sup.1, R.sup.2, R.sup.3 R.sup.4 and R.sup.5 are independently selected from hydrogen, hydrocarbyl and substituted hydrocarbyl.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: October 1, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, John E. Johnston, Mark J. Struglinski, Robert D. Lundberg
  • Patent number: 5039437
    Abstract: Additives for improving the low temperature flow properties of hydrocarbon oils are disclosed, which comprise the condensation reaction product of alkylated phenol and aldehyde, wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole % of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole % of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be sulfurized, or produced in a branched backbone form in which monomer reactants are copolymerized with certain tri- or tetrafunctional comonomers.
    Type: Grant
    Filed: October 8, 1987
    Date of Patent: August 13, 1991
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: David J. Martella, John J. Jaruzelski
  • Patent number: 5030369
    Abstract: An oil soluble dispersant comprising the reaction products of:(1)(i) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides; (ii) long chain hydrocarbon having a polyamine attached directly thereto; (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyamine; and (iv) Mannich condensation product formed by reacting long chain hydrocarbyl substituted mono or dicarboxylic acids or their anhydrides with an aminophenol, which may be optionally hydrocarbyl substituted, to form a long chain hydrocarbyl substituted amide or imide-containing phenol intermediate adduct, and condensing said long chain hydrocarbyl substituted amide or imide-containing phenol adduct with aldehyde and polyamine; said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least
    Type: Grant
    Filed: December 29, 1988
    Date of Patent: July 9, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Lundberg, Antonio Gutierrez
  • Patent number: 5026495
    Abstract: An oil soluble dispersant comprising the reaction products of:(1) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides; (ii) long chain hydrocarbon having a polyamine attached directly thereto; (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyalkylene polyamine; and (iv) Mannich condensation product formed by reacting long chain hydrocarbyl substituted mono or dicarboxylic acids or their anhydrides with an aminophenol, which may be optionally hydrocarbyl substituted, to form a long chain hydrocarbyl substituted amide or imide-containing phenol intermediate adduct, and condensing said long chain hydrocarbyl substituted amide or imide-containing phenol adduct with aldehyde and polyamine; said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2)
    Type: Grant
    Filed: December 29, 1988
    Date of Patent: June 25, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Lundberg, Antonio Gutierrez
  • Patent number: 4982045
    Abstract: This process is one in which a butene feed is passed through a fixed bed of granular aluminum trichloride catalyst, preferably in the presence of an added co-catalyst, to produce a polymerized butene product having number-average molecular weight of greater than about 250.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: January 1, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Frank J. Chen, Robert D. Lundberg
  • Patent number: 4966722
    Abstract: Oil compositions comprising a lubricating oil and oil-soluble ethylene-alpha-olefin copolymer viscosity index improvers are substantially haze-free when said compositions contain an anti-hazing effective amount of a hydrocarbyl substituted succinic acid. The ethylene-alpha-olefin copolymer comprises intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: October 30, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Marvin F. Smith, Jr.
  • Patent number: 4957645
    Abstract: An oil soluble dispersant comprising the reaction products of:(1) (i) oil soluble salts, amides, imides, oxazolines, esters, or mixtures thereof of long chain hydrocarbyl substituted mono- and dicarboxylic acids or their anhydrides, (ii) long chain hydrocarbon having a polyamine attached directly thereto, and (iii) Mannich condensation product formed by condensing a long chain hydrocarbyl substituted hydroxy aromatic compound with an aldehyde and a polyamine, said adduct containing at least one reactive group selected from reactive amino groups and reactive hydroxyl groups; and(2) at least one polythioepoxide. Also disclosed are oleaginous compositions, particularly lubricating oil compositions, containing said dispersant.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: September 18, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Jacob Emert, Robert D. Lundberg
  • Patent number: 4952739
    Abstract: Poly-n-butene is prepared from a mixed C.sub.4 hydrocarbon feedstream containing less than about 5 wt. % isobutylene using an organo-aluminum chloride-HCl catalyst system wherein the HCl is introduced separately into the feedstream to form organochloride in the feedstream. Polymer product having a very narrow molecular weight distribution is obtained over the M.sub.n range of 300 to 900. Detergents derived from this poly-n-butene exhibit substantially improved performance in lubricating oil compositions.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: August 28, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Frank J. Chen
  • Patent number: 4935576
    Abstract: Polybutene is prepared from a mixed C.sub.4 hydrocarbon feedstream using an organo-aluminum/HCl catalyst system wherein the HCl is introduced separately into the feedstream to form organochloride in the feedstream. Polybutene product having a very narrow molecular weight distribution is obtained over the M.sub.n range of 700 to 3,000. Dispersants derived from this polybutene exhibit substantially improved performance in lubricating oil compositions.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: June 19, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Frank J. Chen
  • Patent number: 4933099
    Abstract: A lubricating oil composition comprising a major amount of mineral oil of lubricating viscosity and at least a viscosity index improving amount of an oil-soluble, saturated, ethylene copolymer, preferably an oxidatively and mechanically degraded ethylene copolymer having an ethylene content of 26-79 wt. % (35-85 mole %), a C.sub.3 to C.sub.18 higher alpha-olefin and from 0.05 to 3.0, optimally 0,8 to 2.5 wt. % of 2,5-norbornadiene and preferably at least a pour point depressing amount of lubricaitng oil pour point depressant, e.g. an alkyl fumarate vinyl acetate copolymer, whereby superior low temperature viscometrics is provided to said lubricating oil composition, compared to the same formulation using an ethylene copolymer not containing 2,5-norbornadiene.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: June 12, 1990
    Assignee: Exxon Research and Engineering Company
    Inventor: Gary W. VerStrate
  • Patent number: 4908146
    Abstract: Oil compositions comprising a lubricating oil and oil-soluble hydrocarbon polymeric viscosity index improvers such as ethylene-propylene copolymers are substantially haze-free when said compositions contain an anti-hazing effective amount of a hydrocarbyl substituted succinic acid. The invention also relates to the process for preparing said compositions.
    Type: Grant
    Filed: November 16, 1988
    Date of Patent: March 13, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Marvin F. Smith, Jr.